2-Methacryloyloxyethyl phenyl phosphate | 64716-34-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-Methacryloyloxyethyl phenyl phosphate
• 英文别名: 2-[hydroxy(phenoxy)phosphoryl]oxyethyl 2-methylprop-2-enoate
• CAS: 64716-34-3
• 化学式: C₁₂H₁₅O₆P
• 分子量: 286.22
• InChiKey: LYRWNAXKUQELGU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  19
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  82.1
• 氢给体数：
  1
• 氢受体数：
  6

文献信息

• DENTAL POLYMERIZABLE MONOMER COMPOSITIONS
  申请人：MITSUI CHEMICALS, INC.

  公开号：US20170181932A1

  公开（公告）日：2017-06-29

  Provided are dental polymerizable monomer compositions that can give cured products having high toughness and high rigidity, and dental compositions containing such dental polymerizable monomer compositions and cured products thereof having high mechanical properties. The dental polymerizable monomer composition includes a urethane acrylate compound (A) and a polymerizable compound (B) having at least one polymerizable group selected from methacryloyl groups and acryloyl groups, the urethane acrylate compound (A) being obtained by reacting a specific hydroxyacrylate (a1) with a diisocyanate (a2) having two isocyanate groups bonded to a divalent C 6-9 aromatic hydrocarbon group or a divalent C 6-9 bridged cyclic hydrocarbon group via a methylene group optionally substituted with a hydrocarbon group in place of a hydrogen atom, the proportion of the number of acryloyl groups present in the urethane acrylate compound (A) being 10% to less than 90% relative to the total number of (meth)acryloyl groups in the monomer composition.

  提供了一种牙科可聚合单体组合物，可使固化产物具有高韧性和高刚度，并且含有这种牙科可聚合单体组合物和具有高机械性能的固化产物的牙科组合物。该牙科可聚合单体组合物包括一种脲基丙烯酸酯化合物（A）和一种具有至少一种可聚合基团，所述可聚合基团选自甲基丙烯酰基团和丙烯酰基团的可聚合化合物（B），脲基丙烯酸酯化合物（A）是通过将特定的羟基丙烯酸酯（a1）与具有两个异氰酸基团与一个二价C6-9芳香烃基或一个二价C6-9桥环烃基通过一个亚甲基团或者可选地替代氢原子的烃基的甲烷基团相结合的二异氰酸酯（a2）反应而得到的，相对于单体组合物中（甲）丙烯酰基团的总数，脲基丙烯酸酯化合物（A）中存在的丙烯酰基团的比例为10%至90%。
• DENTAL MATERIALS ON THE BASIS OF UREA GROUP-CONTAINING MONOMERS
  申请人：IVOCLAR VIVADENT AG

  公开号：US20160151249A1

  公开（公告）日：2016-06-02

  Dental material which contains a urea derivative according to general formula I, in which R 1 and R 2 are in each case independently of each other an aliphatic C 1 -C 15 radical which can be interrupted by —O—, —S—, —CO—O—; X is a radically polymerizable group; Y is a radically polymerizable group or an acid group; n, m are in each case independently of each other 1, 2, or 3.

  含有一种按照一般式I的脲衍生物的牙科材料，其中R1和R2分别为独立的脂肪族C1-C15基团，可以被—O—，—S—，—CO—O—打断；X是一个基团，可以被自由基聚合；Y是一个自由基聚合基团或酸基团；n，m分别独立地为1、2或3。
• ACIDIC HYBRID MONOMERS AND DENTAL MATERIALS BASED THEREON
  申请人：Ivoclar Vivadent AG

  公开号：US20170281475A1

  公开（公告）日：2017-10-05

  Acidic monomer according to Formula I: in which A is a linear or branched aliphatic C 1 -C 18 -hydrocarbon group, which can be interrupted by one or more —O—, —S—, —CO—O—, —O—CO—NH—, —HN—CO—NH— or —CO—NR 1 —; R 1 is H or a C 1 -C 6 alkyl group; X is absent or is a linear or branched aliphatic C 1 -C 10 hydrocarbon group, which can be interrupted by one or more —O—, —S—, —CO—O—, —O—CO—NH—, —HN—CO—NH— or —CO—NR 2 —; R 2 is H or a C 1 -C 6 alkyl group; PG is a radically polymerizable group, preferably vinyl, allyl, CH 2 ═CR 3 —CO—Y— or R 4 O—CO—C(═CH 2 )—CH 2 —Y—; Y═O or NR 5 or is absent; R 3 is H or CH 3 ; R 4 is H or a C 1 -C 7 alkyl group; R 5 is H or a C 1 -C 7 alkyl group; n is 1, 2, 3 or 4; m=1 or 2; p=1, 2 or 3; and q=1, 2 or 3. The monomers are particularly suitable as components of dental material.

  根据公式I，酸性单体包括以下成分：其中A是线性或支链脂肪族C1-C18烃基，可以被一个或多个-O-，-S-，-CO-O-，-O-CO-NH-，-HN-CO-NH-或-CO-NR1-所中断；R1为H或C1-C6烷基；X不存在或是线性或支链脂肪族C1-C10烃基，可以被一个或多个-O-，-S-，-CO-O-，-O-CO-NH-，-HN-CO-NH-或-CO-NR2-所中断；R2为H或C1-C6烷基；PG是一个自由基聚合基团，优选为乙烯基，烯丙基，CH2═CR3—CO—Y—或R4O—CO—C(═ )— —Y—；Y为O或NR5或不存在；R3为H或CH3；R4为H或C1-C7烷基；R5为H或C1-C7烷基；n为1、2、3或4；m为1或2；p为1、2或3；q为1、2或3。这些单体特别适用于牙科材料的成分。
• Photopolymerizable dental materials with bisacylphosphine oxides as initiators
  申请人：Moszner Norbert

  公开号：US20070027229A1

  公开（公告）日：2007-02-01

  Polymerizable dental material which contains at least one radically-polymerizable monomer and at least one bisacylphosphine oxide of the Formula I, in which R 1 is a linear or branched C 2 to C 14 alkyl residue, which can be interrupted by one or more O atoms, PG-Y-R 2 -X- or a substituted or unsubstituted, aromatic C 6 to C 14 radical; R 2 is absent or a linear or branched C 1 to C 20 alkylene radical, which can be interrupted by one or more O atoms; R 3 is H, a linear or branched C 1 to C 6 alkyl residue or PG-Y-R 2 -X-; R 4 is a linear or branched C 1 -C 6 alkyl or —O—C 1 -C 6 alkyl residue; R 5 is H or PG-Y-R 2 -X-; R 6 is H or PG-Y-R 2 -X-; PG is a polymerizable group; X is absent, O or S; Y is absent, O, S, an ester, amide or urethane group; the bisacylphosphine oxide having at least one PG-Y-R 2 -X group and X and/or Y being absent if R 2 is absent.

  这是一种聚合牙科材料，其中至少含有一种自由基聚合单体和至少一种公式I的双酰基氧化膦，其中R1是线性或支链的C2到C14烷基残基，可以被一个或多个O原子中断，也可以是PG-Y-R2-X-或取代或未取代的芳香族C6到C14基团；R2不存在或是线性或支链的C1到C20烷基残基，可以被一个或多个O原子中断；R3是H，线性或支链的C1到C6烷基残基或PG-Y-R2-X-；R4是线性或支链的C1-C6烷基或-O-C1-C6烷基残基；R5是H或PG-Y-R2-X-；R6是H或PG-Y-R2-X-；PG是可聚合的基团；X不存在、O或S；Y不存在、O、S、酯、酰胺或脲基团；如果R2不存在，则双酰基氧化膦至少具有一个PG-Y-R2-X基团，并且X和/或Y不存在。
• B-Ketophosphonic Acids And Dental Materials Based Thereon
  申请人：IVOCLAR VIVADENT AG

  公开号：US20160145277A1

  公开（公告）日：2016-05-26

  β-Ketophosphonic acid according to general formula I: in which A=an aliphatic C 1 -C 18 radical which can be interrupted by —O—, —S—, —CO—O— or —O—CO—C—; n=1, 2, 3 or 4; m=1 or 2; X=absent or a C 1 -C 10 radical which can be interrupted by —O—, —S—, —CO—C—, —O—CO—NH— or —CO—NR 1 —, wherein R 1 is H or C 1 -C 7 -alkyl; and PG=a group which can undergo free radical polymerization. The β-ketophosphonic acids are suitable in particular for the preparation of dental materials.

  β-酮磷酸根据一般式I：其中A=一种脂肪族C1-C18基团，可以被—O—、—S—、—CO—O—或—O—CO—C—中断；n=1、2、3或4；m=1或2；X=不存在或是一种C1-C10基团，可以被—O—、—S—、—CO—C—、—O—CO—NH—或—CO—NR1—中断，其中R1为H或C1-C7-烷基；PG=可以发生自由基聚合的基团。β-酮磷酸特别适用于制备牙科材料。