3-prenyl-4-hydroxybenzoic acid senecioate methylester | 137553-26-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-prenyl-4-hydroxybenzoic acid senecioate methylester
• 英文别名: Methyl 4-(3-methylbut-2-enoyloxy)-3-(3-methylbut-2-enyl)benzoate
• CAS: 137553-26-5
• 化学式: C₁₈H₂₂O₄
• 分子量: 302.37
• InChiKey: SDFUQXLBTGUYEW-UHFFFAOYSA-N

物化性质

• 沸点：
  432.2±44.0 °C(Predicted)
• 密度：
  1.065±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  22
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3-prenyl-4-hydroxybenzoic acid senecioate methylester 在 氢氧化钾 作用下， 以 1,4-二氧六环 、 甲醇 为溶剂， 以30 mg的产率得到甲基4-羟基-3-(3-甲基丁-2-烯基)苯甲酸酯
  参考文献：
  名称：

  Kaurane succinates and prenylated aromatics from Odixia angusta and Ozothamnus obcordatus

  摘要：

  The aerial parts of Odixia angusta afforded five ent-kaurane succinates and a nor-derivative as well as diprenyl p-coumarate and a hemiacetal derived from the latter. Ozothamnus obcordatus gave five prenylated p-hydroxybenzoic acids probably formed by oxidative cleavage of the coumarates. The structures were elucidated by high field NMR techniques.

  DOI：

  10.1016/0031-9422(91)85127-l

文献信息

• Kaurane succinates and prenylated aromatics from Odixia angusta and Ozothamnus obcordatus
  作者：C. Zdero、F. Bohlmann、A. Anderberg

  DOI：10.1016/0031-9422(91)85127-l

  日期：1991.1

  The aerial parts of Odixia angusta afforded five ent-kaurane succinates and a nor-derivative as well as diprenyl p-coumarate and a hemiacetal derived from the latter. Ozothamnus obcordatus gave five prenylated p-hydroxybenzoic acids probably formed by oxidative cleavage of the coumarates. The structures were elucidated by high field NMR techniques.