N,O-diphenylcarbamoyl-2-hydroxyethylamine | 103791-67-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,O-diphenylcarbamoyl-2-hydroxyethylamine
• 英文别名: 1-phenylcarbamoyloxy-2-(N'-phenyl-ureido)-ethane；1-Phenylcarbamoyloxy-2-(N'-phenyl-ureido)-aethan；N-(β-Anilinoformyloxy-aethyl)-N'-phenyl-harnstoff；2-(3-Phenylureido)ethyl N-phenylcarbamate；2-(phenylcarbamoylamino)ethyl N-phenylcarbamate
• CAS: 103791-67-9
• 化学式: C₁₆H₁₇N₃O₃
• 分子量: 299.329
• InChiKey: SYKKXOQGUGBKQM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  22
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  79.5
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  C.I.酸性橙108 、 苯甲酰基叠氮化物 以 1,4-二氧六环 为溶剂， 反应 3.5h， 以75%的产率得到N,O-diphenylcarbamoyl-2-hydroxyethylamine
  参考文献：
  名称：

  Shepel', F. G.; Sorochinskaya, T. G., Journal of Organic Chemistry USSR (English Translation), 1986, p. 174 - 177

  摘要：

  DOI：

文献信息

• Ultrafast dynamics of myoglobin probed by time-resolved resonance Raman spectroscopy
  作者：Yasuhisa Mizutani、Teizo Kitagawa

  DOI：10.1002/tcr.1012

  日期：——

  in this laboratory on the ultrafast dynamics of myoglobin (Mb) is summarized with a stress on structural and vibrational energy relaxation. Studies on the structural relaxation of Mb following CO photolysis revealed that the structural change of heme itself, caused by CO photodissociation, is completed within the instrumental response time of the time-resolved resonance Raman apparatus used (approximately

  总结了在该实验室中对肌红蛋白（Mb）的超快动力学进行的最新实验工作，并着重强调了结构和振动能的松弛。对CO光解后Mb的结构弛豫的研究表明，由CO光解离引起的血红素本身的结构变化在所用时间分辨共振拉曼仪器的仪器响应时间内（约2 ps）完成。相反，发现反式配体解离时铁-组氨酸（Fe-His）拉伸模式的强度和频率的变化在皮秒状态下发生。Fe-His谱带不存在与CO结合的形式，并且与在血红素的振动模式中观察到的相反，其在光解离时的出现不是瞬时的。表明从血红素平面的Fe位移有明显的时间演化。Fe-His拉伸模式的条带位置以约100 ps的时间常数变化，这表明蛋白质的三级结构变化发生在100 ps的范围内。v4和v7波段的反斯托克斯拉曼强度的时间变化表明，受激种群的光解离和衰变会立即产生振动激发血红素，其时间常数分别为1.1 +/- 0.6和1.9 +/- 0.6 ps 。此外，还介绍了时间分辨共振拉
• CELLULOSE ACYLATE FILM, NOVEL COMPOUND, POLARIZING PLATE AND LIQUID CRYSTAL DISPLAY DEVICE
  申请人：FUJIFILM Corporation

  公开号：US20150361036A1

  公开（公告）日：2015-12-17

  A cellulose acylate film, which includes a compound denoted by general formula (I) below, the equivalent U of which, calculated as a value obtained by dividing the molecular weight of the compound by the number of divalent linking groups denoted by —O—C(═O)—NH— contained per molecule, is less than or equal to 515, wherein, in general formula (I), each of L 11 and L 21 independently denotes an optionally substituted alkylene group; each of L 12 and L 22 independently denotes a single bond, any one of or any combination of —O—, —NR 1 —, —S— and —C(═O)—; R 1 denotes a hydrogen atom or a substituent; each of n1 and n2 independently denotes an integer of 0 to 20, with at least either n1 or n2 being an integer of greater than or equal to 1. Q 1 -(L 12 -L 11 ) n1 -O—C(═O)—NH-(L 21 -L 22 ) n2 -Q 2 General formula (I)

  一种纤维素酰酸酯薄膜，包括下面的通用公式（I）表示的化合物，其当以将该化合物的分子量除以每分子中含有的二价连接基团—O—C(═O)—NH—的数量得到的值计算时等效U小于或等于515，其中，在通用公式（I）中，L11和L21中的每一个独立表示一个可选择取代的烷基基团；L12和L22中的每一个独立表示一个单键，任意一个或任意组合的—O—、—NR1—、—S—和—C(═O)—；R1表示氢原子或取代基；n1和n2中的每一个独立表示0到20的整数，其中n1或n2中至少有一个整数大于或等于1。Q1-(L12-L11)n1-O—C(═O)—NH-(L21-L22)n2-Q2通用公式（I）
• Cellulose acylate film, novel compound, polarizing plate and liquid crystal display device
  申请人：FUJIFILM Corporation

  公开号：US10040754B2

  公开（公告）日：2018-08-07

  A cellulose acylate film, which includes a compound denoted by general formula (I) below, the equivalent U of which, calculated as a value obtained by dividing the molecular weight of the compound by the number of divalent linking groups denoted by —O—C(═O)—NH— contained per molecule, is less than or equal to 515, wherein, in general formula (I), each of L11 and L21 independently denotes an optionally substituted alkylene group; each of L12 and L22 independently denotes a single bond, any one of or any combination of —O—, —NR1—, —S— and —C(═O)—; R1 denotes a hydrogen atom or a substituent; each of n1 and n2 independently denotes an integer of 0 to 20, with at least either n1 or n2 being an integer of greater than or equal to 1. Q1-(L12-L11)n1-O—C(═O)—NH-(L21-L22)n2-Q2  General formula (I)

  一种纤维素酰基化合物薄膜，它包括以下通式(I)表示的化合物，其当量U(通过将化合物的分子量除以每个分子所含的由-O-C(═O)-NH-表示的二价连接基团的数目而得到的值)小于或等于515，其中，在通式(I)中，L11和L21各自独立地表示任选取代的亚烷基；L12和L22各自独立地表示单键、-O-、-NR1-、-S-和-C(═O)-中的任意一个或任意组合； R1表示氢原子或取代基； n1和n2各自独立地表示0至20的整数，其中至少n1或n2之一是大于或等于1的整数。 Q1-(L12-L11)n1-O-C(═O)-NH-(L21-L22)n2-Q2 通式 (I)
• Cellulose ester film, polarizing plate, and liquid crystal display device
  申请人：FUJIFILM Corporation

  公开号：US10338290B2

  公开（公告）日：2019-07-02

  A cellulose ester film contains a compound having a structural unit denoted by —NR—(C═O)— in which R represents a hydrogen atom or a substituent, a surface having knoop hardness of greater than or equal to 210 N/mm2 is provided, and loss tangent tan δ at 25° C. is greater than or equal to 0.03.

  一种纤维素酯薄膜含有一种化合物，其结构单元用-NR-(C═O)-表示，其中R代表氢原子或取代基，表面硬度大于或等于210牛顿/平方毫米，25°C时的损耗正切tanδ大于或等于0.03。
• SHEPEL, F. G.;SOROCHINSKAYA, T. G., ZH. ORGAN. XIMII, 1986, 22, N 1, 197-200
  作者：SHEPEL, F. G.、SOROCHINSKAYA, T. G.

  DOI：——

  日期：——