9-(2-methoxyethoxy)anthracene | 112607-85-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 9-(2-methoxyethoxy)anthracene
• CAS: 112607-85-9
• 化学式: C₁₇H₁₆O₂
• 分子量: 252.313
• InChiKey: FMVIJEPYIULFMQ-UHFFFAOYSA-N

物化性质

• 熔点：
  106.9-108.1 °C
• 沸点：
  425.5±28.0 °C(Predicted)
• 密度：
  1.141±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  乙二醇甲醚 、 蒽 以58%的产率得到
  参考文献：
  名称：

  SUGIYAMA TAKASHI, CHEM. LETT.,(1987) N 6, 1013-1016

  摘要：

  DOI：

文献信息

• Synthesis of 9-Anthryl Ethers from trans-9,10-Dihydro-9,10-dimethoxy­anthracene by Acid-Catalyzed Transetherification
  作者：Dae Chi、Keun Jang、Hee Shin

  DOI：10.1055/s-0028-1088073

  日期：2009.5

  Ar) to anthracene, anthryl ethers at the C9-position of anthracene were obtained as the major products when trans-9,10-dihydro-9,10-dimethoxyanthracene was reacted (10 minutes at 75 ˚C) with various alcohols. 9-Anthryl ethers with primary, secondary, cyclic alcohols, and polyethylene glycol (PEG) were isolated in 47-73% yields under optimized conditions. It is hoped that the devised method offers a

  在对蒽的亲电芳族加成反应（Ad E Ar）的研究中，当反式-9,10-二氢-9,10-二甲氧基蒽反应（10分钟）时，蒽C9位的蒽醚是主要产物。在75℃下）与各种酒精混合。在优化的条件下，以47-73％的收率分离出带有伯，仲，环状醇和聚乙二醇（PEG）的9-蒽醚。希望所设计的方法为通过将反式-9，10-二氢-9，10-二甲氧基蒽与各种醇进行酸催化的反式醚化提供一种新的合成路线来制备蒽醚。 互醚化-蒽醚-反式-9,10-二氢-9,10-二甲氧基蒽
• Application of Lanthanoids to Organic Chemistry. Direct Alkoxylation of Anthracene
  作者：Takashi Sugiyama

  DOI：10.1246/cl.1987.1013

  日期：1987.6.5

  Direct alkoxylation of anthracene with some lower alcohols and ethylene glycol monoalkyl ethers, or monoacetate were carried out in the presence of cerium(IV)tetrakis(trifluoro acetate), and expected alkoxylated anthracene derivatives were obtained.

  蒽与一些低级醇和乙二醇单烷基醚或单乙酸酯在四（三氟乙酸）铈（IV）的存在下进行直接烷氧基化，并获得预期的烷氧基化蒽衍生物。
• RADICAL POLYMERIZATION CONTROL AGENT AND RADICAL POLYMERIZATION CONTROL METHOD
  申请人：Kawasaki Kasei Chemicals Ltd.

  公开号：US20210122692A1

  公开（公告）日：2021-04-29

  A conventional polymerization inhibitor is for example an agent to scavenge radicals generated during storage of a radical polymerizable compound and used to stably handle the radical polymerizable compound, but is unnecessary when the radical polymerizable compound is to be subjected to radical polymerization reaction, and is preferably removed at the time of the radical polymerization reaction. The object of the present invention is to obviate inconvenience of removing the polymerization inhibitor at the time of radical polymerization. The radical polymerization control agent contained in a radical polymerizable composition of the present invention functions as a radical polymerization inhibitor for example stored in a dark place, but loses its radical polymerization inhibiting effect when polymerization is initiated while being irradiated with light at a certain specific wavelength at the time of polymerization. Thus, radical polymerization of the radical polymerizable compound is easily initiated without increasing the amount of a radical polymerization initiator. That is, the radical polymerization control agent of the present invention is a radical polymerization control agent which is a corn pound having an effect to inhibit radical polymerization of a radical polymerizable compound and which loses the radical polymerization inhibiting effect under irradiation with light rays containing light within a wavelength range of from 300 nm to 500 nm.