PhAs(S2N2) | 1215864-09-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: PhAs(S2N2)
• 英文别名: 5-Phenyl-1,3lambda4-dithia-2,4-diaza-5-arsacyclopenta-2,3-diene；5-phenyl-1,3λ4-dithia-2,4-diaza-5-arsacyclopenta-2,3-diene
• CAS: 1215864-09-7
• 化学式: C₆H₅AsN₂S₂
• 分子量: 244.173
• InChiKey: JVYNFIPRISZQCX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.49
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  51
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  二氯苯胂 在 [nBu₂Sn(S₂N₂)]2 作用下， 以 二氯甲烷 为溶剂， 反应 6.0h， 以51%的产率得到PhAs(S2N2)
  参考文献：
  名称：

  Five-Membered Arsenic−Sulfur−Nitrogen Heterocycles, RAs(S₂N₂) (R = Me, Et, ⁱPr, ^tBu, Ph, Mes)

  摘要：

  A series of 5-alkyl/aryl-1,3 lambda(4)delta(2),2,4,5-dithiadiazarsoles RAs(S2N2) (R = Me, Et, Pr-i, Bu-t, Ph, Mes) were prepared by a ligand exchange between [(Bu2Sn)-Bu-n(S2N2)](2) and the corresponding organodihalogenoarsines RAsX2 (X = Cl, I). All products were characterized by NMR, IR, and Raman spectroscopies and mass spectrometry. The crystal structures of the aryldithiadiazarsoles (R = Ph, Mes) were determined.

  DOI：

  10.1021/ic1000107

文献信息

• Five-Membered Arsenic−Sulfur−Nitrogen Heterocycles, RAs(S₂N₂) (R = Me, Et, ⁱPr, ^tBu, Ph, Mes)
  作者：Vit Matuska、Alexandra M. Z. Slawin、J. Derek Woollins

  DOI：10.1021/ic1000107

  日期：2010.3.15

  A series of 5-alkyl/aryl-1,3 lambda(4)delta(2),2,4,5-dithiadiazarsoles RAs(S2N2) (R = Me, Et, Pr-i, Bu-t, Ph, Mes) were prepared by a ligand exchange between [(Bu2Sn)-Bu-n(S2N2)](2) and the corresponding organodihalogenoarsines RAsX2 (X = Cl, I). All products were characterized by NMR, IR, and Raman spectroscopies and mass spectrometry. The crystal structures of the aryldithiadiazarsoles (R = Ph, Mes) were determined.