3-[([1,1'-Biphenyl]-4-yl)oxy]aniline | 887580-43-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-[([1,1'-Biphenyl]-4-yl)oxy]aniline
• 英文别名: 3-(4-phenylphenoxy)aniline
• CAS: 887580-43-0
• 化学式: C₁₈H₁₅NO
• 分子量: 261.3
• InChiKey: YJQRLTCXYNGNSE-UHFFFAOYSA-N

物化性质

• 沸点：
  428.8±28.0 °C(Predicted)
• 密度：
  1.148±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  35.2
• 氢给体数：
  1
• 氢受体数：
  2

文献信息

• POLYIMIDE RESIN COMPOSITION
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0267289A1

  公开（公告）日：1988-05-18

  A polyimide resin composition, which comprises 100 parts by weight of a polyimide having repeating units represented by general formula (I), (wherein Y represents a direct bond, a divalent hydrocarbyl group having 1 to 10 carbon atoms, a hexafluoroisopropylidene group, a carbonyl group, a thio group, a sulfinyl group, a sulfonyl group or an oxido group, and R represents a tetravalent aliphatic group having 2 or more carbon atoms, alicyclic group, monocylic aromatic group, fused polycyclic aromatic group or non-fused cyclic aromatic group wherein aromatic groups are linked to each other directly or via a linking member) and 5 to 100 parts by weight of fibrous reinforcing material such as glass fibers, carbon fibers, potassium titanate fibers, aromatic polymide fibers, etc. This resin composition has excellent heat resistance, dimensional stability, and mechanical strength and is a useful material for manufacturing electric or electronic components, precision machine parts, etc. The polyimide to be used can be prepared from an aromatic ether diamine and a tetracarboxylic acid dianhydride, using 4,4'-bis(3-amino- phenoxy)biphenyl, 2,2'-bis(4-(3-aminophenoxy)phenyl)-propane, bis(4-(3-aminophenoxy)phenyl) sulfide, etc. as the ether diamine and pyromellitic dianhydride, 3,3',4,4'-benzophenonetetracarboxylic acid dianhydride, etc. as the tetracarboxylic acid dianhydride.

  一种聚酰亚胺树脂组合物，它包括 100 重量份的具有通式(I)代表的重复单元的聚酰亚胺，（其中 Y 代表直接键、具有 1 至 10 个碳原子的二价烃基、六氟异亚丙基、羰基、硫基、亚磺酰基、磺酰基或氧化基、和 R 代表具有 2 个或 2 个以上碳原子的四价脂肪族基团、脂环族基团、单环芳香族基团、熔合多环芳香族基团或非熔合环芳香族基团，其中芳香族基团直接或通过连接构件相互连接）以及 5 至 100 重量份的纤维增强材料，如玻璃纤维、碳纤维、钛酸钾纤维、芳香族聚酰亚胺纤维等。这种树脂组合物具有优异的耐热性、尺寸稳定性和机械强度，是制造电气或电子元件、精密机械零件等的有用材料。使用的聚酰亚胺可以由芳香族醚二胺和四羧酸二酐制备，使用 4,4'-双（3-氨基苯氧基）联苯、2,2'-双（4-（3-氨基苯氧基）苯基）丙烷、双（4-（3-氨基苯氧基）苯基）硫醚等作为醚二胺和四羧酸二酐。作为醚二胺和吡咯二酸酐，3,3',4,4'-二苯甲酮四羧酸二酸酐等作为四羧酸二酸酐。
• Durch Einwirkung von Strahlung vernetzendes Gemisch und dessen Verwendung zur Herstellung hochtemperaturbeständiger Reliefstrukturen
  申请人：BASF Lacke + Farben Aktiengesellschaft

  公开号：EP0571899A1

  公开（公告）日：1993-12-01

  Die Erfindung betrifft durch Einwirkung von Strahlung vernetzende Gemische, im wesentlichen bestehend aus (I) mindestens einer in polaren organischen Lösungsmitteln löslichen carboxylgruppenhaltigen polymeren Vorstufe hochtemperaturbeständiger heterocyclischer Polymerer, (II) einem copolymerisierbaren ethylenisch ungesättigten ternären Sulfoniumsalz, (III) einem Photoinitiator oder Photoinitiatorsystem und (IV) mindetens einem polaren aprotischen organischen Lösungsmittel. Diese Gemische eignen sich zur Herstellung hochtemperaturbeständiger Reliefstrukturen.

  本发明涉及在辐射作用下交联的混合物，主要包括 (I) 至少一种可溶于极性有机溶剂的耐高温杂环聚合物的含羧基聚合物前体、 (II) 可共聚的乙烯不饱和三元锍盐 (III) 一种光引发剂或光引发剂体系，以及 (IV) 至少一种极性烷基有机溶剂。 这些混合物适用于生产耐高温浮雕结构。
• SOLUTION COMPOSITIONS OF BLOCK COPOLYIMIDES COMPRISING PYROMELLITIC DIANHYDRIDE AND PROCESS FOR PRODUCTION THEREOF
  申请人：PI R & D Co., Ltd.

  公开号：EP1561786A1

  公开（公告）日：2005-08-10

  Polyimides consisting of PMDA and an aromatic diamine are normally solvent-insoluble. According to the present invention, they are solubilized in solvents to prepare four-component or higher block copolymers containing BTDA. PMDA is reacted with a certain type of aromatic diamine in a molar ratio of 1:2-1.5 to produce a solvent-soluble oligomer. This is combined with an acid dianhydride and an aromatic diamine to produce a four-component or higher solvent-soluble block copolymer. The molar ratio of the aromatic diamine added with PMDA is 1:2-1.5. A number of solvent-soluble block copolymers containing PMDA can be prepared. Four-component or higher polyimide block copolymers containing PMDA, BTDA, and DAT are prepared by sequential reactions in the presence of a binary catalyst. This made it possible to prepare various polyimides from many inexpensively available materials. Polyimides containing PMDA-BTDA-DAT can be prepared at high performance, in mass and at low cost by using economical direct imidation, and therefore can be widely used in future.

  由 PMDA 和芳香族二胺组成的聚酰亚胺通常不溶于溶剂。根据本发明，可将它们溶解在溶剂中，制备含有 BTDA 的四组份或更高组份嵌段共聚物。PMDA 与某种芳香族二胺以 1:2-1.5 的摩尔比进行反应，生成可溶于溶剂的低聚物。低聚物与酸性二酐和芳香族二胺反应生成四组份或更高组份的可溶于溶剂的嵌段共聚物。 芳香族二胺与 PMDA 的摩尔比为 1:2-1.5。可以制备多种含有 PMDA 的溶剂可溶嵌段共聚物。 在二元催化剂存在下，通过连续反应可制备出含有 PMDA、BTDA 和 DAT 的四组份或更高组份的聚酰亚胺嵌段共聚物。这使得利用许多廉价材料制备各种聚酰亚胺成为可能。含有 PMDA-BTDA-DAT 的聚酰亚胺可通过经济的直接酰亚胺法制备出高性能、大规模和低成本的聚酰亚胺，因此可在未来得到广泛应用。
• Polyimide metal laminate
  申请人：Fukuda Kazuyuki

  公开号：US20050048297A1

  公开（公告）日：2005-03-03

  The polyimide metal laminate has at least one resin layer produced from a silica-dispersed polyimide composition obtained by reacting (A) alkoxysilane and/or its partial hydrolysis polycondensate with (B) an amino-containing compound having a functional group capable of forming a bond with silica, in the presence of water in a polyimide solution and/or a polyamic acid solution.

  聚酰亚胺金属层压板至少有一层树脂层，由二氧化硅分散聚酰亚胺组合物制成，该组合物是在聚酰亚胺溶液和/或聚酰胺酸溶液中，在有水的情况下，将(A)烷氧基硅烷和/或其部分水解缩聚物与(B)含氨基的化合物反应而成，该化合物具有能与二氧化硅形成键合的官能团。
• Solution compositions of block copolyimides comprising pyromellitic dianhydride and process for production thereof
  申请人：Itatani Hiroshi

  公开号：US20060004180A1

  公开（公告）日：2006-01-05

  Polyimides consisting of PMDA and an aromatic diamine are normally solvent-insoluble. According to the present invention, they are solubilized in solvents to prepare four-component or higher block copolymers containing BTDA. PMDA is reacted with a certain type of aromatic diamine in a molar ratio of 1:2-1.5 to produce a solvent-soluble oligomer. This is combined with an acid dianhydride and an aromatic diamine to produce a four-component or higher solvent-soluble block copolymer. The molar ratio of the aromatic diamine added with PMDA is 1:2-1.5. A number of solvent-soluble block copolymers containing PMDA can be prepared. Four-component or higher polyimide block copolymers containing PMDA, BTDA, and DAT are prepared by sequential reactions in the presence of a binary catalyst. This made it possible to prepare various polyimides from many inexpensively available materials. Polyimides containing PMDA-BTDA-DAT can be prepared at high performance, in mass and at low cost by using economical direct imidation, and therefore can be widely used in future.

  由 PMDA 和芳香族二胺组成的聚酰亚胺通常不溶于溶剂。根据本发明，可将它们溶解在溶剂中，制备含有 BTDA 的四组份或更高组份嵌段共聚物。PMDA 与某种芳香族二胺以 1:2-1.5 的摩尔比进行反应，生成可溶于溶剂的低聚物。低聚物与酸性二酐和芳香族二胺反应生成四组份或更高组份的可溶于溶剂的嵌段共聚物。芳香族二胺与 PMDA 的摩尔比为 1:2-1.5。可以制备多种含有 PMDA 的溶剂可溶嵌段共聚物。在二元催化剂存在下，通过连续反应可制备出含有 PMDA、BTDA 和 DAT 的四组份或更高组份的聚酰亚胺嵌段共聚物。这使得利用许多廉价材料制备各种聚酰亚胺成为可能。含有 PMDA-BTDA-DAT 的聚酰亚胺可通过经济的直接酰亚胺法制备，性能高、质量大、成本低，因此可在未来广泛应用。