4-(3-phenylquinoxalin-2-yl)diphenylamine | 1159218-78-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: 4-(3-phenylquinoxalin-2-yl)diphenylamine
• 英文别名: N-phenyl-4-(3-phenylquinoxalin-2-yl)aniline
• CAS: 1159218-78-6
• 化学式: C₂₆H₁₉N₃
• 分子量: 373.457
• InChiKey: JLDPGUGTWBTYEM-UHFFFAOYSA-N

物化性质

• 沸点：
  537.2±50.0 °C(Predicted)
• 密度：
  1.218±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  29
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  37.8
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-(3-phenylquinoxalin-2-yl)diphenylamine 、 2-(4-溴苯基)-5-苯基-1,3,4-恶二唑 在 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 三叔丁基膦 、 sodium t-butanolate 作用下， 以 正己烷 、 甲苯 为溶剂， 反应 3.0h， 以88%的产率得到4-(5-phenyl-1,3,4-oxadiazol-2-yl)-4'(3-phenylquinoxalin-2-yl)triphenylamine
  参考文献：
  名称：

  Quinoxaline derivative, and light emitting element, light emitting device and electronic appliance using the same

  摘要：

  公开号：

  EP2067778B1
• 作为产物：
  描述：

  1-溴-4-(苯基乙炔基)苯 在 三叔丁基膦 、 碘 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 、 sodium t-butanolate 作用下， 以 5,5-dimethyl-1,3-cyclohexadiene 、 乙醇 、 正己烷 为溶剂， 反应 8.5h， 生成 4-(3-phenylquinoxalin-2-yl)diphenylamine
  参考文献：
  名称：

  퀴녹살린 유도체, 및 이를 사용한 발광 소자, 발광 장치 및전자 기기

  摘要：

  The purpose is to provide a new bipolar organic compound. Also, the aim is to provide an excellent carrier balance luminous component. Furthermore, the goal is to offer luminous components and devices with low driving voltage and low power consumption. Additionally, the objective is to provide electronic devices with low power consumption. The solution provides a chemical formula represented as Quinoxaline derivative. In the chemical formula 1, α1 and α2 independently represent an arylene group with up to 13 carbon atoms forming a ring, Ar represents an aryl group with up to 13 carbon atoms forming a ring, R1 and R6 independently represent a hydrogen atom, an alkyl group with 1 to 6 carbon atoms, or one of the aryl groups with up to 13 carbon atoms forming a ring, R2 to R5 and R7 to R10 independently represent a hydrogen atom, an alkyl group with 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, or a substituted or unsubstituted biphenyl group. Bipolar organic compound, Quinoxaline derivative, carrier balance, luminous component, luminous device, electronic device, driving voltage, power consumption.

  公开号：

  KR101564230B1

文献信息

• Quinoxaline Derivative, and Light-Emitting Element, Light-Emitting Device, and Electronic Device Using the Same
  申请人：Osaka Harue

  公开号：US20090140644A1

  公开（公告）日：2009-06-04

  The present invention provides a quinoxaline derivative rerpesented by a general formula (G1). In the formula, α 1 and α 2 each independently represent an arylene group which has 13 or less carbon atoms forming a ring; Ar represents an aryl group which has 13 or less carbon atoms forming a ring; R 1 and R 6 each independently represent any of a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, or an aryl group which has 13 or less carbon atoms forming a ring; and R 2 to R 5 and R 7 to R 10 each independently represent any of a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, or a substituted or unsubstituted biphenyl group.

  该发明提供了一种由通式（G1）表示的喹喔啉衍生物。在该式中，α1和α2分别表示一个芳基基团，该基团有13个或更少的碳原子形成一个环；Ar表示一个芳基基团，该基团有13个或更少的碳原子形成一个环；R1和R6各自独立地表示氢原子、具有1到6个碳原子的烷基基团，或者有13个或更少的碳原子形成一个环的芳基基团；R2到R5和R7到R10各自独立地表示氢原子、具有1到6个碳原子的烷基基团、取代或未取代的苯基团，或者取代或未取代的联苯基团。
• Quinoxaline Derivative, and Light Emitting Element, Light Emitting Device and Electronic Appliance Using the Same
  申请人：Kawakami Sachiko

  公开号：US20090153041A1

  公开（公告）日：2009-06-18

  A quinoxaline-based, new bipolar organic compound is provided, and a light emitting element using the quinoxaline-based compound is demonstrated. The quinoxaline derivative of the invention has a structure in which carbon at one or both of the 2-position and the 3-position of the quinoxaline unit are bonded, via an arylene group, with an amine unit which has a substituted or unsubstituted five-membered ring or a substituted or unsubstituted condensed ring containing a five-membered ring structure. The quinoxaline-based compound was proven to possess bipolar characteristics in view of carrier transportation, which allows the fabrication of a light emitting element and an electronic appliance with a low driving voltage and low power consumption.

  本发明提供了一种基于喹喔啉的新型双极有机化合物，并演示了使用该基于喹喔啉的化合物的发光元件。该发明的喹喔啉衍生物具有结构，在其中，喹喔啉单元的2位和/或3位的碳通过芳基烃基团与一种含有取代或未取代的五元环或含有五元环结构的取代或未取代的缩合环的胺单元键合。基于喹喔啉的化合物被证明具有双极特性，具有载流子传输的特性，这允许制造具有低驱动电压和低功耗的发光元件和电子设备。
• Quinoxaline derivative, and light emitting element, licht emitting device and electronic appliance using the same
  申请人：SEMICONDUCTOR ENERGY LABORATORY CO., LTD.

  公开号：EP2067778A1

  公开（公告）日：2009-06-10

  A quinoxaline-based, new bipolar organic compound is provided, and a light emitting element using the quinoxaline-based compound is demonstrated. The quinoxaline derivative of the invention has a structure in which carbon at one or both of the 2-position and the 3-position of the quinoxaline unit are bonded, via an arylene group, with an amine unit which has a substituted or unsubstituted five-membered ring or a substituted or unsubstituted condensed ring containing a five-membered ring structure. The quinoxaline-based compound was proven to possess bipolar characteristics in view of carrier transportation, which allows the fabrication of a light emitting element and an electronic appliance with a low driving voltage and low power consumption.

  本发明提供了一种基于喹喔啉的新型双极有机化合物，并展示了一种使用该基于喹喔啉的化合物的发光元件。本发明的喹喔啉衍生物具有这样的结构：喹喔啉单元 2 位和 3 位中的一个或两个位置上的碳通过芳烯基与具有取代或未取代五元环或含有五元环结构的取代或未取代缩合环的胺单元键合。这种基于喹喔啉的化合物被证明在载流子传输方面具有双极特性，因此可以制造低驱动电压和低功耗的发光元件和电子设备。
• US7993761B2
  申请人：——

  公开号：US7993761B2

  公开（公告）日：2011-08-09
• US8216696B2
  申请人：——

  公开号：US8216696B2

  公开（公告）日：2012-07-10