1,6-diazabicyclo<4.4.3>tridecane | 79401-85-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,6-diazabicyclo<4.4.3>tridecane
• 英文别名: 1,6-Diazabicyclo[4.4.3]tridecane
• CAS: 79401-85-7
• 化学式: C₁₁H₂₂N₂
• 分子量: 182.309
• InChiKey: PNUZYSTXXHXMMC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.57
• 重原子数：
  13.0
• 可旋转键数：
  0.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  6.48
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  6-aza-1-azoniatricyclo<4.4.3.0^1,5>tridecane chloride 在 lithium aluminium tetrahydride 作用下， 以 乙二醇二甲醚 为溶剂， 反应 24.0h， 以72%的产率得到1,6-diazabicyclo<4.4.3>tridecane
  参考文献：
  名称：

  Synthesis of medium-ring bicyclic bridgehead diamines from monocyclic diamines via α-aminoammonium ions

  摘要：

  DOI：

  10.1016/s0040-4039(00)88382-3

文献信息

• [EN] DYE COMPOSITIONS, METHODS OF PREPARATION, CONJUGATES THEREOF, AND METHODS OF USE<br/>[FR] COMPOSITIONS DE COLORANT, PROCÉDÉS DE PRÉPARATION, CONJUGUÉS ASSOCIÉS, ET PROCÉDÉS D'UTILISATION
  申请人：UNIV CORNELL

  公开号：WO2013109859A1

  公开（公告）日：2013-07-25

  Dye compounds of the formula (1) wherein A is a protective agent group that has a characteristic of modifying the singlet-triplet occupancy of the shown cyanine moiety, and M is a reactive crosslinking group or a group that can be converted to a reactive crosslinking group. Methods for synthesizing the dye compounds and applications for their use are also described.

  化合物的染料的公式（1），其中A是一种保护剂基团，具有修改所示青菁基团的单三态占据特性，而M是一种反应性交联基团或可转化为反应性交联基团的基团。还描述了合成染料化合物的方法以及它们的用途。
• DYE COMPOSITIONS, METHODS OF PREPARATION, CONJUGATES THEREOF, AND METHODS OF USE
  申请人：CORNELL UNIVERSITY

  公开号：US20150011731A1

  公开（公告）日：2015-01-08

  Dye compounds of the formula (1) wherein A is a protective agent group that has a characteristic of modifying the singlet-triplet occupancy of the shown cyanine moiety, and M is a reactive crosslinking group or a group that can be converted to a reactive crosslinking group. Methods for synthesizing the dye compounds and applications for their use are also described.

  公式（1）中，A是一种保护剂基团，具有改变所示花菁基团的单重态-三重态占据特性，M是反应性交联基团或可转化为反应性交联基团的基团。还描述了合成染料化合物的方法以及它们的应用。
• Alder, Roger W.; Sessions, Richard B.; Bennet, Andrew J., Journal of the Chemical Society. Perkin transactions I, 1982, p. 603 - 610
  作者：Alder, Roger W.、Sessions, Richard B.、Bennet, Andrew J.、Moss, Richard E.

  DOI：——

  日期：——
• METHODS AND COMPOSITIONS FOR ALTERING PHOTOPHYSICAL PROPERITES OF FLUOROPHORES VIA PROXIMAL QUENCHING
  申请人：Blanchard Scott

  公开号：US20120027689A1

  公开（公告）日：2012-02-02

  The invention is directed to fluorophore-containing compositions and configurations wherein proximity between the fluorophore and one or more protective agents (PAs) modifies the lifetime of fluorescent and/or dark states, their frequency of occurrence, and the total lifetime of fluorescence in order to appropriately modify the photophysical characteristics of the fluorophore. The invention is also directed to methods that utilize these compositions and configurations.
• METHODS AND COMPOSITIONS FOR ALTERING PHOTOPHYSICAL PROPERTIES OF FLUOROPHORES VIA PROXIMAL QUENCHING
  申请人：Cornell University

  公开号：US20150328340A1

  公开（公告）日：2015-11-19

  The invention is directed to fluorophore-containing compositions and configurations wherein proximity between the fluorophore and one or more protective agents (PAs) modifies the lifetime of fluorescent and/or dark states, their frequency of occurrence, and the total lifetime of fluorescence in order to appropriately modify the photophysical characteristics of the fluorophore. The invention is also directed to methods that utilize these compositions and configurations.