1-cyclohexene-1-ethanethioic acid | 112936-09-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 硫代酸
• 英文名称: 1-cyclohexene-1-ethanethioic acid
• 英文别名: (Cyclohex-1-en-1-yl)ethanethioic S-acid；2-(cyclohexen-1-yl)ethanethioic S-acid
• CAS: 112936-09-1
• 化学式: C₈H₁₂OS
• 分子量: 156.249
• InChiKey: ILLJLZAPZCSKTO-UHFFFAOYSA-N

物化性质

• 沸点：
  233.6±19.0 °C(Predicted)
• 密度：
  1.066±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  18.1
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  羰基硫 、 亚甲基环己烷 在 二甲基氯化铝 作用下， 以 二氯甲烷 、 甲苯 为溶剂， 反应 3.5h， 以42%的产率得到1-cyclohexene-1-ethanethioic acid
  参考文献：
  名称：

  Dunkerton, Lois V.; Sasa, Michiyuki, Synthetic Communications, 1987, vol. 17, # 10, p. 1217 - 1226

  摘要：

  DOI：

文献信息

• Process for providing monovalent and polyvalent metal, particularly antimony, mercaptocarboxylic acid ester salts; monovalent and polyvalent metal mercaptocarboxylic acid salts; polyol mercaptocarboxylic acid monoesters, and esters of such polyol mercaptocarboxylic acid esters with a mercaptocarboxylic acid; stabilizer compositions for polyvinyl chloride resins comprising such compounds; and polyvinyl chloride resin compositions comprising a stabilizing amount of such compounds
  申请人：Mack, Gerry

  公开号：EP0024919A2

  公开（公告）日：1981-03-11

  Antimony mercaptocarboxylic acid esters are provided having the formula: wherein: R is selected from the group consisting of hydrogen, alkyl having from one to about eighteen carbon atoms and alkylene linked with R2 in a ring having from three to about eight carbon atoms; R2 is selected from the group consisting of alkyl having from one to about eighteen carbon atoms, phenyl, and alkylene linked with R, in a ring having from three to about eight carbon atoms; R3 is selected from the group consisting of hydrogen and alkyl having from one to three carbon atoms; R4 is selected from the group consisting of alkyl, aryl, alkylaryl, alkoxycarbonyl-alkylene and acyloxyalkylene having from three to about twenty carbon atoms, the alkylene having from two to about six carbon atoms; R5 is selected from the group consisting of alkylene and cycloalkylene having from one to about eighteen carbon atoms, and such groups having from one to four hydroxyl groups; Z is a bivalent alkylene group having from one to five carbon atoms and carrying the sulfur in a position alpha or beta to -OOC-; and n is a number from 1 to 3. A process for preparing such antimony compounds is also provided, as well as predecessor intermediates, and stabilizer compositions for polyvinyl chloride resin compositions comprising such antimony compounds, if desired with other polyvinyl chloride resin stabilizers.

  巯基羧酸锑酯的化学式如下 其中 R 选自氢、具有 1 至约 18 个碳原子的烷基和与 R2 连接成具有 3 至约 8 个碳原子的环的亚烷基组成的组； R2 选自具有 1 至约 18 个碳原子的烷基、苯基和与 R2 连接在具有 3 至约 8 个碳原子的环中的亚烷基组成的组； R3 选自由氢和具有一至三个碳原子的烷基组成的组； R4 选自具有 3 至约 20 个碳原子的烷基、芳基、烷芳基、烷氧羰基亚烷基和酰氧基亚烷基组成的组，其中亚烷基具有 2 至约 6 个碳原子； R5 选自具有 1 至约 18 个碳原子的亚烷基和环亚烷基，以及具有 1 至 4 个羟基的此类基团； Z 是二价亚烷基，具有 1 至 5 个碳原子，并在 -OOC- 的α或β位上带有硫；以及 n 是 1 至 3 的数字。 本发明还提供了制备此类锑化合物的工艺以及前身中间体，并提供了包含此类锑化合物的聚氯乙烯树脂组合物的稳定剂组合物（如需要与其他聚氯乙烯树脂稳定剂一起使用）。
• DUNKERTON, L. V.;SASA, MICHIYUKI, SYNTH. COMMUN., 17,(1987) N 10, 1217-1225
  作者：DUNKERTON, L. V.、SASA, MICHIYUKI

  DOI：——

  日期：——
• US4269731A
  申请人：——

  公开号：US4269731A

  公开（公告）日：1981-05-26
• Dunkerton, Lois V.; Sasa, Michiyuki, Synthetic Communications, 1987, vol. 17, # 10, p. 1217 - 1226
  作者：Dunkerton, Lois V.、Sasa, Michiyuki

  DOI：——

  日期：——