2-Methyl-penten-(2)-thiosaeure-(5) | 98485-30-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 硫代酸
• 英文名称: 2-Methyl-penten-(2)-thiosaeure-(5)
• 英文别名: 4-methylpent-3-enethioic S-acid
• CAS: 98485-30-4
• 化学式: C₆H₁₀OS
• 分子量: 130.211
• InChiKey: OXMRGLHTZAIGBF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  8
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  18.1
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-甲基-3-戊烯酸 生成 2-Methyl-penten-(2)-thiosaeure-(5)
  参考文献：
  名称：

  Korte,F.; Christoph,H., Chemische Berichte, 1961, vol. 94, p. 1966 - 1976

  摘要：

  DOI：

文献信息

• Method for producing anellated tetrahydro-{1h}-triazoles
  申请人：——

  公开号：US20040097728A1

  公开（公告）日：2004-05-20

  The present invention relates to a process for preparing fused tetrahydro-[ 1 H]-triazoles of the formula I 1 where the variables R a , Z, Z 1 , X, W, n and Q are as defined in claim 1, by cyclization of compounds of the formula II 2 where R is C(X)OR 2 or C(X)SR 2 , where X is oxygen or sulfur, and R 2 is as defined in claim 1, in the presence of a base. The invention also relates to compounds of the formula I where W is sulfur if Z is a methylene group optionally substituted by R a , and furthermore to compounds of the formula I where Q is a benzoxazole or benzothiazole radical, and to the use of these compounds as herbicides.

  本发明涉及一种制备公式I的熔融四氢咪唑的方法，其中变量Ra、Z、Z1、X、W、n和Q如权利要求1中定义，通过在碱存在下，将公式II的化合物环化得到，其中R为C(X)OR2或C(X)SR2，其中X为氧或硫，R2如权利要求1中定义。该发明还涉及公式I的化合物，其中如果Z是可选地由Ra取代的亚甲基基团，则W为硫，此外还涉及公式I的化合物，其中Q为苯并噁唑或苯并噻唑基团，并将这些化合物用作除草剂。
• [DE] 1-AMINO-3-BENZYLURACILE<br/>[EN] 1-AMINO-3-BENZYLURACILS<br/>[FR] 1-AMINO-3-BENZYLURACILES
  申请人：BASF AKTIENGESELLSCHAFT

  公开号：WO1997001543A1

  公开（公告）日：1997-01-16

  (DE) 1-Amino-3-benzyluracile (I) und deren Salze (R1 = Halogen; R2, R3 = H, CN, SCN, Halogen, C1-C4-Halogenalkyl, C1-C4-Halogenalkoxy, C1-C4-Halogenalkylthio; R4 = R3 + C1-C4-Alkyl, C1-C4-Alkoxy, C1-C6-Alkyl-NH-CO-; R5 = H, CN, NO2, OH, Halogen, gegebenenfalls substituiertes NH2, gegebenenfalls subst. C1-C6-Halogenalkoxy, C1-C6-Halogenalkylthio, C1-C6-Alkoxy, C1-C6-Alkylthio, C3-C8-Cycloalkoxy, C3-C8-Cycloalkylthio, C3-C6-Alkenyloxy, C3-C6-Alkenylthio, C3-C6-Alkinyloxy, C3-C6-Alkinylthio, C1-C6-Alkyl-COO-, C1-C6-Alkyl-COS-, C3-C6-Alkenyl-COO-, C3-C6-Alkenyl-COS-, C3-C6-Alkinyl-COO-, C3-C6-Alkinyl-COS-, C1-C6-Alkyl-SO2-O- oder C1-C6-Alkyl-SO2-; R6 = 1) H, OH, SH, Halogen, C1-C6-Halogenalkoxy, C1-C6-Halogenalkylthio, C1-C6-Alkylthio-(C1-C6-alkyl)carbonyl, C1-C6-Alkyliminooxy-CO-, 2) gegebenenfalls subst. C1-C6-Alkoxy, C1-C6-Alkylthio, C3-C8-Cycloalkoxy, C3-C8-Cycloalkylthio, C2-C6-Alkenyloxy, C2-C6-Alkenylthio, C2-C6-Alkinyloxy, C2-C6-Alkinylthio, C1-C6-Alkyl-COO-, C2-C6-Alkyl-COS-, C1-C6-Alkoxy-COO-, C2-C6-Alkenyl-COO-, C2-C6-Alkenyl-COS-, C2-C6-Alkinyl-COO-, C2-C6-Alkinyl-COS-, C1-C6-Alkyl-SO2-O-, C1-C6-Alkyl-SO2-, 3) -CY-R11 Y = -O-, -S-, gegebenenfalls subst. -NH-}, -C(R11)(Z1R12)(Z2R13) Z1, Z2 = -O-, -S-}, -C(R11)=C(R14)-CN, -C(R11)=C(R14)-CO-R15, -CH(R11)-CH(R14)-CO-R15, -C(R11)=C(R14)-CH2-CO-R15, -C(R11)=C(R14)-C(R16)=C(R17)-CO-R15, -C(R11)=C(R14)-CH2-CH(R18)-CO-R15, -CO-OR19, -CO-SR19, -CO-N(R19)-OR20, -C$m(0)C-CO-NH-OR20, -C$m(0)C-CO-N(R19)-OR20, -C$m(0)C-CS-NH-OR20, -C$m(0)C-CS-N(R19)-OR20, -C(R11)=C(R14)-CO-NH-OR20, -C(R11)=C(R14)-CO-N(R19)-OR20, -C(R11)=C(R14)-CS-NH-OR20, -C(R11)=C(R14)-CS-N(R19)-OR20, -C(R11)=C(R14)-C(R21)=N-OR20, -C(R21)=N-OR20, -C$m(0)C-C(R21)=N-OR20, -C(Z1R12)(Z2R13)-OR19, -C(Z1R12) (Z2R13)-SR19, -C(Z1R12) (Z2R13)-N(R23)R24, gegebenenfalls substituiertes Amino oder -CONH2, Azaheterocyclyl, -CO-Azaheterocyclyl, (N + O oder N + O + S) Heterocyclyl enthaltende Kette); als Herbizide, zur Dessikation/Defoliation von Pflanzen.(EN) The invention concerns 1-amino-3-benzyluracils of formula (I) and their salts. In said formula (I), R1 = halogen; R2, R3 = H, CN, SCN, halogen, C1¿-C¿4-alkyl halide, C1-C4-alkoxy halide, C1-C4-alkylthio halide; R4 = R3 + C1-C4-alkyl, C1-C4-alkoxy, C1-C6-alkyl-NH-CO-; R5 = H, CN, NO2, OH, halogen, optionally substituted NH2, optionally substituted C1-C6-alkoxy halide, C1-C6-alkylthio halide, C1-C6-alkoxy, C1-C6-alkylthio, C3-C8-cycloalkoxy, C3-C8-cycloalkylthio, C3-C6-alkenyloxy, C3-C6-alkenylthio, C3-C6-alkinyloxy, C3-C6-alkinylthio, C1-C6-alkyl-COO-, C1-C6-alkyl-COS-, C3-C6-alkenyl-COO-, C3-C6-alkenyl-COS-, C3-C6-alkinyl-COO-, C3-C6-alkinyl-COS-, C1-C6-alkyl-SO2-O- or C1-C6-alkyl-SO2-; R6 = 1) H, OH, SH, halogen, C1-C6-alkoxy halide, C1C6-alkylthio halide, C1-C6-alkylthio-(C1-C6-alkyl)carbonyl, C1-C6-alkyliminooxy-CO-, 2) optionally substituted C1C6-alkoxy, C1-C6-alkylthio, C3-C8-cycloalkoxy, C3-C8-cycloalkylthio, C2-C6-alkenyloxy, C2-C6-alkenylthio, C2-C6-alkinyloxy, C2-C6-alkinylthio, C1-C6-alkyl-COO-, C2-C6-alkyl-COS-, C1-C6-alkoxy-COO-, C2-C6-alkenyl-COO-, C2-C6-alkenyl-COS-, C2-C6-alkinyl-COO-, C2-C6-alkinyl-COS-, C1-C6-alkyl-SO2-O-, C1-C6-alkyl-SO2-, 3) -CY-R11 Y = -O-, -S-, optionally substituted -NH-}, -C(R11)(Z1R12)(Z2R13) Z1, Z2 = -O-, -S-}, -C(R11)=C(R14)-CN, -C(R11)=C(R14)-CO-R15, -CH(R11)-CH(R14)-CO-R15, -C(R11)=C(R14)-CH2-CO-R15, -C(R11)=C(R14)-C(R16)=C(R17)-CO-R15, -C(R11)=C(R14)-CH2-CH(R18)-CO-R15, -CO-OR19, -CO-SR19, -CO-N(R19)-OR20, -C$m(0)C-CO-NH-OR20, -C$m(0)C-CO-N(R19)-OR20, -C$m(0)C-CS-NH-OR20, -C$m(0)C-CS-N(R19)-OR20, -C(R11)=C(R14)-CO-NH-OR20, -C(R11)=C(R14)-CO-N(R19)-OR20,-C(R11)=C(R14)-CS-NH-OR20, -C(R11)=C(R14)-CS-N(R19)-OR20, -C(R11)=C(R14)-C(R21)=N-OR20, -C(R21)=N-OR20, -C$m(0)C-C(R21)=N-OR20, -C(Z1R12)(Z2R13)-OR19, -C(Z1R12)(Z2R13)-SR19, -C(Z1R12)(Z2R13)-N(R23)R24, optionally substituted amino or -CONH2, azaheterocyclyl, -CO-azaheterocyclyl, or a chain comprising (N + O or N + O + S) heterocyclyl. These compounds can be used as herbicides for desiccating/defoliating plants.(FR) L'invention concerne des 1-amino-3-benzyluraciles de la formule (I) et leurs sels. Dans ladite formule (I), R1 représente de l'halogène; R2, R3 représentent H, CN, SCN, halogène, halogénure d'alkyle C1-C4, halogénure d'alcoxy C1-C4, halogénure d'alkylthio C1-C4; R4 représente R3 + alkyle C1-C4, alcoxy C1-C4, alkyle C1-C6 -NH-CO-; R5 représente H, CN, NO2, OH, halogène, NH2 éventuellement substitué, halogénure d'alcoxy C1-C6 éventuellement substitué, halogénure d'alkylthio C1-C6, alcoxy C1-C6, alkylthio C1-C6, cycloalcoxy C3-C8, cycloalkylthio C3-C8, alcényloxy C3-C6, alcénylthio C3-C6, alkinyloxy C3-C6, alkinylthio C3-C6, alkyle C1-C6-COO-, alkyle C1-C6-COS-, alcényle C3-C6-COO-, alcényle C3-C6-COS-, alkinyle C3-C6-COO-, alkinyle C3-C6-COS-, alkyle C1-C6-SO2-O- ou alkyle C1-C6-SO2-; R6 représente 1) H, OH, SH, halogène, halogénure d'alcoxy C1-C6, halogénure d'alkylthio C1-C6, alkylthio C1-C6-(alkyle C1-C6) carbonyle, alkyliminooxy C1-C6-CO-, 2) alcoxy C1-C6 éventuellement substitué, alkylthio C1-C6, cycloalcoxy C3-C8, cycloalkylthio C3-C8, alcényloxy C2-C6, alcénylthio C2-C6, alkinyloxy C2-C6, alkinylthio C2-C6, alkyle C1-C6-COO-, alkyle C2-C6-COS, alcoxy C1-C6-COO-, alcényle C2-C6-COO-, alcényle C2-C6 -COS-, alkinyle C2-C6-COO-, alkinyle C2-C6 -COS-, alkyle C1-C6-SO2-O-, alkyle C1-C6-SO2-, 3) -CY-R11 Y = -O-, -S-, -NH- éventuellement substitué}, -C(R11)(Z1R12)(Z2R13) Z1, Z2 = -O-, -S-}, -C(R11)=C(R14)-CN, -C(R11)=C(R14)-CO-R15, -CH(R11)-CH(R14)-CO-R15, -C(R11)=C(R14)-CH2-CO-R15, -C(R11)=C(R14)-C(R16)=C(R17)-CO-R15, -C(R11)=C(R14)-CH2-CH(R18)-CO-R15, -CO-OR19, -CO-SR19, -CO-N(R19)-OR20, -C$m(0)C-CO-NH-OR20, -C$m(0)C-CO-N(R19)-OR20, -C$m(0)C-CS-NH-OR20, -C$m(0)C-CS-N(R19)-OR20, -C(R11)=C(R14)-CO-NH-OR20, -C(R11)=C(R14)-CO-N(R19)-OR20, -C(R11)=C(R14)-CS-NH-OR20, -C(R11)=C(R14)-CS-N(R19)-OR20, -C(R11)=C(R14)-C(R21)=N-OR20, -C(R21)=N-OR20, -C$m(0)C-C(R21)=N-OR20, -C(Z1R12)(Z2R13)-OR19, -C(Z1R12)(Z2R13)-SR19, -C(Z1R12)(Z2R13)-N(R23)R24, amino éventuellement substitué ou -CONH2, azahétérocyclyle, -CO-azahétérocyclyle, ou une chaîne comprenant de un hétérocyclyle (N + O ou N + O + S). Ces composés chimiques peuvent être utilisés comme herbicides pour la dessication/défoliation des plantes.

  （DE）1-氨基-3-苯并嘧啶尿嘧啶（I）及其衍生物的盐类（R1 = 卤素；R2, R3 = H, CN, SCN, 卤素, C1-C4卤代烷基, C1-C4卤代烷氧基, C1-C4卤代烷硫基; R4 = R3 + C1-C4烷基, C1-C4烷氧基, C1-C6-NH-CO-烷基; R5 = H, CN, NO2, OH, 卤素, 可能是取代的NH2, 可能是取代的C1-C6卤代烷氧基, C1-C6卤代烷硫基, C1-C6烷氧基, C1-C6烷硫基, C3-C8环烷氧基, C3-C8环烷硫基, C3-C6烯基氧基, C3-C6烯基硫基, C3-C6炔基氧基, C3-C6炔基硫基, C1-C6烷基-COO-, C1-C6烷基-COS-, C3-C6烯基-COO-, C3-C6烯基-COS-, C3-C6炔基-COO-, C3-C6炔基-COS-, C1-C6烷基-SO2-O-或C1-C6烷基-SO2-; R6 = 1) H, OH, SH, 卤素, C1-C6卤代烷氧基, C1-C6卤代烷硫基, C1-C6烷硫基-(C1-C6烷基)羰基, C1-C6烷基亚胺氧基-CO-, 2) 可能是取代的C1-C6烷氧基, C1-C6烷硫基, C3-C8环烷氧基, C3-C8环烷硫基, C2-C6烯基氧基, C2-C6烯基硫基, C2-C6炔基氧基, C2-C6炔基硫基, C1-C6烷基-COO-, C2-C6烷基-COS-, C1-C6烷氧基-COO-, C2-C6烯基-COO-, C2-C6烯基-COS-, C2-C6炔基-COO-, C2-C6炔基-COS-, C1-C6烷基-SO2-O-, C1-C6烷基-SO2-, 3) -CY-R11 Y = -O-, -S-, 可能是取代的-NH-}, -C(R11)(Z1R12)(Z2R13) Z1, Z2 = -O-, -S-}, -C(R11)=C(R14)-CN, -C(R11)=C(R14)-CO-R15, -CH(R11)-CH(R14)-CO-R15, -C(R11)=C(R14)-CH2-CO-R15, -C(R11)=C(R14)-C(R16)=C(R17)-CO-R15, -C(R11)=C(R14)-CH2-CH(R18)-CO-R15, -CO-OR19, -CO-SR19, -CO-N(R19)-OR20, -C(*)(0)C-CO-NH-OR20, -C(*)(0)C-CO-N(R19)-OR20, -C(*)(0)C-CS-NH-OR20, -C(*)(0)C-CS-N(R19)-OR20, -C(R11)=C(R14)-CO-NH-OR20, -C(R11)=C(R14)-CO-N(R19)-OR20, -C(R11)=C(R14)-CS-NH-OR20, -C(R11)=C(R14)-CS-N(R19)-OR20, -C(R11)=C(R14)-C(R21)=N-OR20, -C(R21)=N-OR20, -C(*)(0)C-C(R21)=N-OR20, -C(Z1R12)(Z2R13)-OR19, -C(Z1R12)(Z2R13)-SR19, -C(Z1R12)(Z2R13)-N(R23)R24, 可能是取代的氨基或-CONH2, 含氮杂环基, -CO-含氮杂环基, 或包含（N + O或N + O + S）的杂环基链）。这些化合物可用作除草剂，用于植物的脱水/脱叶。 （EN）The invention concerns 1-amino-3-benzyluracils of formula (I) and their salts. In said formula (I), R1 = halogen; R2, R3 = H, CN, SCN, halogen, C1-C4-alkyl halide, C1-C4-alkoxy halide, C1-C4-alkylthio halide; R4 = R3 + C1-C4-alkyl, C1-C4-alkoxy, C1-C6-alkyl-NH-CO-; R5 = H, CN, NO2, OH, halogen, optionally substituted NH2, optionally substituted C1-C6-alkoxy halide, C1-C6-alkylthio halide, C1-C6-alkoxy, C1-C6-alkylthio, C3-C8-cycloalkoxy, C3-C8-cycloalkylthio, C3-C6-alkenyloxy, C3-C6-alkenylthio, C3-C6-alkinyloxy, C3-C6-alkinylthio, C1-C6-alkyl-COO-, C1-C6-alkyl-COS-, C3-C6-alkenyl-COO-, C3-C6-alkenyl-COS-, C3-C6-alkinyl-COO-, C3-C6-alkinyl-COS-, C1-C6-alkyl-SO2-O- or C1-C6-alkyl-SO2-; R6 = 1) H, OH, SH, halogen, C1-C6-alkoxy halide, C1-C6-alkylthio halide, C1-C6-alkylthio-(C1-C6-alkyl)carbonyl, C1-C6-alkyliminooxy-CO-, 2) optionally substituted C1-C6-alkoxy, C1-C6-alkylthio, C3-C8-cycloalkoxy, C3-C8-cycloalkylthio, C2-C6-alkenyloxy, C2-C6-alkenylthio, C2-C6-alkinyloxy, C2-C6-alkinylthio, C1-C6-alkyl-COO-, C2-C6-alkyl-COS-, C1-C6-alkoxy-COO-, C2-C6-alkenyl-COO-, C2-C6-alkenyl-COS-, C2-C6-alkinyl-COO-, C2-C6-alkinyl-COS-, C1-C6-alkyl-SO2-O-, C1-C6-alkyl-SO2-, 3) -CY-R11 Y = -O-, -S-, optionally substituted -NH-}, -C(R11)(Z1R12)(Z2R13) Z1, Z2 = -O-, -S-}, -C(R11)=C(R14)-CN, -C(R11)=C(R14)-CO-R15, -CH(R11)-CH(R14)-CO-R15, -C(R11)=C(R14)-CH2-CO-R15, -C(R11)=C(R14)-C(R16)=C(R17)-CO-R15, -C(R11)=C(R14)-CH2-CH(R18)-CO-R15, -CO-OR19, -CO-SR19, -CO-N(R19)-OR20, -C$(m)(0)C-CO-NH-OR20, -C$(m)(0)C-CO-N(R19)-OR20, -C$(m)(0)C-CS-NH-OR20, -C$(m)(0)C-CS-N(R19)-OR20, -C(R11)=C(R14)-CO-NH-OR20, -C(R11)=C(R14)-CO-N(R19)-OR20, -C(R11)=C(R14)-CS-NH-OR20, -C(R11)=C(R14)-CS-N(R19)-OR20, -C(R11)=C(R14)-C(R21)=N-OR20, -C(R21)=N-OR20, -C$(m)(0)C-C(R21)=N-OR20, -C(Z1R12)(Z2R13)-OR19, -C(Z1R12)(Z2R13)-SR19, -C(Z1R12)(Z2R13)-N(R23)R24, optionally substituted amino or -CONH2, azaheterocyclyl, -CO-azaheterocyclyl, or a chain comprising (N + O or N + O + S) heterocyclyl. These compounds can be used as herbicides for desiccating/defoliating plants. （FR）L'invention concerne des 1-amino-3-benzyluraciles de la formule (I) et leurs sels. Dans ladite formule (I), R1 représente de l'halogène; R2, R3 représentent H, CN, SCN, halogène, halogénure d'alkyle C1-C4, halogénure d'alcoxy C1-C4, halogénure d'alkylthio C1-C4; R4 représente R3 + alkyle C1-C4, alcoxy C1-C4, alkyle C1-C6 -NH-CO-; R5 Represents H, CN, NO2, OH, halogène, NH2 éventuellement substitué, halogénure d'alcoxy C1-C6 éventuellement substitué, halogénure d'alkylthio C1-C6, alcoxy C1-C6, alkylthio C1-C6, cycloalcoxy C3-C8, cycloalkylthio C3-C8, alcényloxy C3-C6, alcénylthio C3-C6, alkinyloxy C3-C6, alkinylthio C3-C6, alkyle C1-C6-COO-, alkyle C1-C6-COS-, alcényle C3-C6-COO-, alcényle C3-C6-COS-, alkinyle C3-C6-COO-, alkinyle C3-C6-COS-, alkyle C1-C6-SO2-O- ou alkyle C1-C6-SO2-; R6 représente 1) H, OH, SH, halogène, halogénure d'alcoxy C1-C6, halogénure d'alkylthio C1-C6, alkylthio C1-C6-(alkyle C1-C6) carbonyle, alkyliminooxy C1-C6-CO-, 2) alcoxy C1-C6 éventuellement substitué, alkylthio C1-C6, cycloalcoxy C3-C8, cycloalkylthio C3-C8, alcényloxy C2-C6, alcénylthio C2-C6, alkinyloxy C2-C6, alkinylthio C2-C6, alkyle C1-C6-COO-, alkyle C2-C6-COS, alcoxy C1-C6-COO-, alcényle C2-C6-COO-, alcényle C2-C6-COS-, alkinyle C2-C6-COO-, alkinyle C2-C6-COS-, alkyle C1-C6-SO2-O-, alkyle C1-C6-SO2-, 3) -CY-R11 Y = -O-, -S-, -NH- éventuellement substitué}, -C(R11)(Z1R12)(Z2R13) Z1, Z2 = -O-, -S-}, -C(R11)=C(R14)-CN, -C(R11)=C(R14)-CO-R15, -CH(R11)-CH(R14)-CO-R15, -C(R11)=C(R14)-CH2-CO-R15, -C(R11)=C(R14)-C(R16)=C(R17)-CO-R15, -C(R11)=C(R14)-CH2-CH(R18)-CO-R15, -CO-OR19, -CO-SR19, -CO-N(R19)-OR20, -C$(m)(0)C-CO-NH-OR20, -C$(m)(0)C-CO-N(R19)-OR20, -C$(m)(0)C-CS-NH-OR20, -C$(m)(0)C-CS-N(R19)-OR20, -C(R11)=C(R14)-CO-NH-OR20, -C(R11)=C(R14)-CO-N(R19)-OR20, -C(R11)=C(R14)-CS-NH-OR20, -C(R11)=C(R14)-CS-N(R19)-OR20, -C(R11)=C(R14)-C(R21)=N-OR20, -C(R21)=N-OR20, -C$(m)(0)C-C(R21)=N-OR20, -C(Z1R12)(Z2R13)-OR19, -C(Z1R12)(Z2R13)-SR19, -C(Z1R12)(Z2R13)-N(R23)R24, amino éventuellement substitué ou -CONH2, azahétérocyclyle, -CO-azahétérocyclyle, ou une chaîne comprenant de un hétérocyclyle (N + O ou N + O + S). Ces composés chimiques peuvent être utilisés comme herbicides pour la dessication/défoliation des plantes.
• [DE] SUBSTITUIERTE 1-METHYL-3-BENZYLURACILE<br/>[EN] SUBSTITUTED 1-METHYL-3-BENZYLURACILS<br/>[FR] 1-METHYLE-3-BENZYLURACILES SUBSTITUES
  申请人：BASF AKTIENGESELLSCHAFT

  公开号：WO1997035845A1

  公开（公告）日：1997-10-02

  (DE) Substituierte 1-Methyl-3-benzyluracile der Formel (I), deren Salze und Enolether als Herbizide oder Desikkantien/Defoliantien, wobei R1 = C1-C4-Halogenalkyl; R2 = H, Halogen; R3 = R2, CN, SCN, C1-C4-Halogenalkyl, C1-C4-Halogenalkoxy, C1-C4-Halogenalkylthio; R4 = R3, C1-C4-Alkyl, C1-C4-Alkoxy, (C1-C6-Alkylamino)-CO-; R5 = R2, CN, NO2, OH, ggf. substituiertes Amino, Alkoxy, Alkylthio, Alkyl-CO2-, Alkyl-COS-, Alkyl-SO2-O-, Alkyl-SO2-, wobei die 6 letztgenannten Reste ggf. funktionalisiert und/oder substituiert sein können; R6 an $g(a), wobei R5 dann an $g(b) steht: OH, SH, Alkyl, Alkoxy, Alkylthio, Alkyl-CO2-, Alkyl-COS-, Alkoxy-CO-, Alkoxy-CO2-, Alkyl-SO2-O-, Alkyl-SO2-, Alkyl-CO-, Alkyl-CS-, Alkyl-(N-alkyl)-imino, Alkyl-(N-alkoxy)-imino, wobei die 13 letztgenannten Reste ggf. funktionalisiert und/oder substituiert sein können; durch ggf. substituiertes Alkoxy, Alkylthio zweifach und ggf. Alkyl einfach substituiertes Methyl; an $g(b), wobei R5 dann an $g(a) steht: die voranstehend für R6 genannten Bedeutungen, sowie Alkylamino-CO-, Alkoxy-CO-, Alkylthio-CO-, Alkyl-CO-, Alkyliminooxycarbonyl, Alkyl-(N-alkoxy)-imino, Alkoxy-(N-alkoxy)-imino, Alkylthio-(N-alkoxy)-imino, wobei die 8 letztgenannten Reste ggf. funktionalisiert und/oder substituiert sein können; durch ggf. substituiertes Alkoxy, Alkylthio, Alkylamino dreifach substituiertes Methyl.(EN) The invention concerns substituted 1-methyl-3-benzyluracils (I) and their salts and enol ethers as herbicides or desiccating/defoliating agents. In formula (I), R1 is C1-C4 alkyl halide; R2 is H or halogen; R3 is R2, CN, SCN, C1-C4 alkyl halide, C1-C4 alkoxy halide or C1-C4 alkylthio halide; R4 is R3, C1-C4 alkyl, C1-C4 alkoxy or (C1-C6 alkylamino)-CO-; R5 is R2, CN, NO2, OH, optionally substituted amino, alkoxy, alkylthio, alkyl-CO2-, alkyl-COS-, alkyl-SO2-O- or alkyl-SO2-, the six last-mentioned groups optionally being functionalized and/or substituted; R6, if it is in the $g(a) position with R5 then being in the $g(b) position, is OH, SH, alkyl, alkoxy, alkylthio, alkyl-CO2-, alkyl-COS-, alkoxy-CO-, alkoxy-CO2-, alkyl-SO2-O-, alkyl-SO2-, alkyl-CO-, alkyl-CS-, alkyl-(N-alkyl)-imino or alkyl-(N-alkoxy)-imino, the thirteen last-mentioned groups optionally being functionalized and/or substituted, or methyl substituted twice by optionally substituted alkoxy and alkylthio and optionally substituted once by alkyl; or R6 in the $g(b) position, with R5 then being in the $g(a) position, has the above meanings, as well as alkyl-amino-CO-, alkoxy-CO-, alkylthio-CO-, alkyl-CO-, alkylimino-oxycarbonyl, alkyl-(N-alkoxy)-imino, alkoxy-(N-alkoxy)-imino or alkylthio-(N-alkoxy)-imino, the eight last-mentioned groups optionally being functionalized and/or substituted, or methyl substituted three times by optionally substituted alkoxy, alkylthio and alkylamino.(FR) L'invention concerne des 1-méthyle-3-benzyluraciles substitués de la formule (I), leurs sels et éthers d'énol utilisés comme herbicides ou dessiccateurs/défoliants. Dans cette formule, R1 = halogénure d'alkyle C1-C4; R2 = H, halogène; R3 = R2, CN, SCN, halogénure d'alkyle C1-C4, halogénure d'alcoxy C1-C4, halogénure d'alkylthio C1-C4; R4 = R3, alkyle C1-C4, alcoxy C1-C4, (alkylamino C1-C6)-CO-; R5 = R3, CN, NO2, OH, amino éventuellement substitué, alcoxy, alkylthio, alkyle-CO2, alkyle-COS, alkyle-SO2-O-, alkyle-SO2-, les 6 derniers restes pouvant être fonctionnalisés et/ou substitués; R6 désigne en $g(a), R5 se trouvant alors en $g(b): OH, SH, alkyle, alcoxy, alkylthio, alkyle-CO2-, alkyle-COS-, alcoxy-CO-, alcoxy-CO2-, alkyle-SO2-O-, alkyle-SO2-, alkyle-CO-, alkyle-CS-, alkyle-(N-alkyle)-imino, alkyle-(N-alcoxy)-imino, les 13 derniers restes étant éventuellement fonctionnalisés et/ou substitués; méthyle substitué deux fois par alcoxy, alkylthio évent. subst. et une fois par alkyle évent. subst.; en $g(b), R5 se trouvant alors en $g(a): les notations mentionnées précédemment pour R6, ainsi que alkyle-amino-CO-, alcoxy-CO-, alkylthio-CO-, alkyle-CO-, alkylimino-oxycarbonyle, alkyle-(N-alcoxy)-imino, alcoxy-(N-alcoxy)-imino, alkylthio-(N-alcoxy)-imino, les 8 derniers restes pouvant être fonctionnalisés et/ou substitués; méthyle substitué trois fois par alcoxy, alkylthio, alkylamino évent. subst.

  该发明涉及取代的译码1-甲基-3-苯基尿嘧啶(I)，其盐及其κ-β-烯醇作为除草剂或去水剂/防止扩展剂。在公式(I)中，R1为甲基 C1-C4卤化物；R2为 H 或卤素；R3为 R2, CN, SCN, 甲基 C1-C4卤化物, 甲基 C1-C4卤氧化物或甲基 C1-C4硫化物；R4为 R3, 甲基 C1-C4烷基, 甲基 C1-C4卤氧或(C1-C6烷基氨基)-CO-；R5为 R2, CN, NO2, OH, 氵l可选氨基、卤氧、烷基硫化、烷基-COO-或烷基-COS-，六个最后提到的基团可被功能化和/或替代；R6在 $g(a)位置时，当 R5位于 $g(b)位置时，则为 OH, SH,烷基、卤氧、烷基硫化、烷基-COO-、烷基-COS-、卤氧-COO-、卤氧-COO-、烷基-SO2-O-、烷基-SO2-、烷基-CO-、烷基-CS-、烷基-(N-烷基)二胺或烷基-(N-卤氧)二胺，这些十三个最后提到的基团可被功能化和/或替代，或通过可能带有卤氧和烷基硫回味二次的甲基，而且再通过取代可能带有烷基的第二个替换基团；或者、当 R6在 $g(b)位置时，当 R5位于 $g(a)位置时，前面提到对于 R6的基团，再加上烷基-氨基-CO-、卤氧-CO-、烷基硫化-CO-、烷基-CO-、烷基二酰氨基-oxycarbonyl、烷基-(N-卤氧)二胺、卤氧-(N-卤氧)二胺、烷基硫化-(N-卤氧)二胺，这些八个最后提到的基团可被功能化和/或替代，或通过可能带有卤氧、烷基硫化和烷基氨基三次取代的甲基。
• [DE] SUBSTITUIERTE 3-PHENYLISOXAZOLINE<br/>[EN] SUBSTITUTED 3-PHENYL ISOXAZOLINES<br/>[FR] 3-PHENYLISOXAZOLINE SUBSTITUEE
  申请人：BASF AKTIENGESELLSCHAFT

  公开号：WO1999005130A1

  公开（公告）日：1999-02-04

  (DE) Substituierte 3-Phenylisoxazoline der Formel (I), deren Salze und Enolether als Herbizide, wobei X = -O-, -S-, -N(R9)-; R1 = CN, C1-C4-Alkyl, C1-C4-Halogenalkyl, C1-C4-Halogenalkoxy, C1-C4-Alkylsulfonyl; R2 = H oder gegebenenfalls substituiertes C1-C6-Alkyl, (C1-C6-Alkyl)carbonyl, C1-C6-Alkylsulfonyl, C2-C6-Alkenyl, (C2-C6-Alkenyl)carbonyl, C2-C6-Alkinyl, (C2-C6-Alkinyl)-carbonyl; R3 = H, Halogen; R4 = CN, Halogen, C1-C3-Halogenalkyl; R5 = H, CN, Halogen, C1-C3-Halogenalkyl; R6 = H, CN, Halogen, C1-C3-Halogenalkyl oder gegebenenfalls subst. C1-C6-Alkoxy; R7 = CN, Halogen; R8 an $g(a), wobei R7 dann an $g(b) steht, oder an $g(b), wobei R7 dann an $g(a) steht; 1) H, OH, SH, CN, NO2, Halogen, C1-C6-Alkyl, C1-C6-Halogenalkyl, C1-C6-Halogenalkoxy, C1-C6-Halogenalkylthio, C1-C6-Alkylthio-(C1-C6-alkyl)-carbonyl, (C1-C6-Alkyl)iminooxycarbonyl, C1-C6-Alkoxy-C1-C6-alkyl, C1-C6-Alkoxyamino-C1-C6-alkyl, C1-C6-Alkoxy-C1-C6-alkylamino-C1-C6-alkyl, 2) gegebenenfalls substituiertes C1-C6-Alkoxy, C1-C6-Alkylthio, C3-C6-Cycloalkoxy, C3-C6-Cycloalkylthio, C2-C6-Alkenyloxy, C2-C6-Alkenylthio, C2-C6-Alkinyloxy, C2-C6-Alkinylthio, (C1-C6-Alkyl)carbonyloxy, (C1-C6-Alkyl)carbonylthio, (C1-C6-Alkoxy)carboxyloxy, (C2-C6-Alkenyl)carbonyloxy, (C2-C6-Alkenyl)carbonylthio, (C2-C6-Alkinyl)carbonyloxy, (C2-C6-Alkinyl)carbonylthio, C1-C6-Alkylsulfonyloxy oder C1-C6-Alkylsulfonyl, 3) 29 weitere Reste; R9 = H, C1-C6-Alkyl, C3-C6-Cycloalkyl, C3-C6-Alkenyl, C3-C6-Alkinyl, C1-C6-Alkoxy-C1-C6-alkyl, (C1-C6-Alkoxy)carbonyl-C1-C6-alkyl, (C3-C6-Alkenyloxy)carbonyl-C1-C6-alkyl, gegebenenfalls substituiertes Phenyl oder Phenyl-C1-C6-alkyl.(EN) The invention relates to substituted 3-phenyl isoxazolines of formula (I) and salts and enol ethers thereof, and to their use as herbicides. In said formula (I), X represents -O-, -S-, -N(R9)-; R1 represents CN, C1-C4alkyl, C1-C4alkyl halide, C1-C4halogen alkoxy, C1-C4alkyl sulfonyl; R2 represents H or optionally, substituted C1-C6 alkyl, (C1-C6 alkyl) carbonyl, C1-C6alkyl sulfonyl, C2-C6 alkenyl, (C2-C6 alkenyl) carbonyl, C2-C6alkinyl, (C2-C6alkinyl) carbonyl; R3 represents H, halogen; R4 represents CN, halogen, C1-C3 alkyl halide; R5 represents H, CN, halogen, C1-C3alkyl halide; R6 represents H, CN, halogen, C1-C3 alkyl halide or optionally, substituted C1-C6 alkoxy; R7 represents CN, halogen; R8 is at $g(a) when R7 is at $g(b), or at $g(b) when R7 is at $g(a) and represents: 1) H, OH, SH, CH, NO2, halogen, C1-C6alkyl, C1-C6alkyl halide, C1-C6halogen alkoxy, C1-C6 halogenalkylthio, C1-C6 alkylthio (C1-C6alkyl) carbonyl, (C1-C6 alkyl) iminooxycarbonyl, C1-C6alkoxy C1-C6alkyl, C1-C6alkoxyamino C1-C6alkyl, C1-C6alkoxy C1-C6alkylamino C1-C6alkyl, 2) optionally, substituted C1-C6alkoxy, C1-C6 alkylthio, C3-C6 cycloalkoxy, C3-C6 cycloalkylthio, C2-C6 alkenyloxy, C2-C6alkenylthio, C2-C6 alkinyloxy, C2-C6 alkinylthio, (C1-C6 alkyl) carbonyloxy, (C1-C6 alkyl) carbonylthio, (C1-C6 alkoxy) carboxyloxy, (C2-C6 alkenyl) carbonyloxy, (C2-C6 alkenyl) carbonylthio, (C2-C6 alkinyl) carbonyloxy, (C2-C6 alkinyl) carbonylthio, C1-C6 alkylsulfonyloxy or C1-C6 alkylsulfonyl and 3) 29 other radicals; and R9 represents H, C1-C6 alkyl, C3-C6 cycloalkyl, C3-C6 alkenyl, C3-C6 alkinyl, C1-C6 alkoxy C1-C6alkyl, (C3-C6 alkenyloxy) carbonyl C1-C6alkyl and optionally, substituted phenyl or phenyl C1-C6alkyl.(FR) L'invention concerne des 3-phénylisoxazoline substituées représentés par la formule (I), ainsi que les sels et enoléthers de ces dernières, utilisés comme herbicides. Dans la formule (I), X = -O-, -S-, -N(R9)-; R1 = CN, alkyle C1-C4, halogénalkyle C1-C4, halogénalkoxy C1-C4, Alkylsulfonyle C1-C4; R2 = H ou éventuellement alkyle C1-C6, (alkyl C1-C6)carbonyle, alkylsulfonyle C1-C6, alcényle C2-C6, (alcényl C2-C6)carbonyle, alcynyle C2-C6, (alcynyl C2-C6)carbonyle; R3 = H, halogène; R4 = CN, halogène, halogénalkyle C1-C3; R5 = H, CN, halogène, halogénalkyle C1-C3, R6 = H, CN, halogène, halogénalkyle C1-C3 ou éventuellement alkoxy C1-C6 substitué; R7 = CN, halogène; R8 est en $g(a), lorsque R7 est en $g(b), ou R8 est en $g(b) lorsque R7 est en $g(a): 1) H, OH, SH, CN, NO2, halogène, alkyle C1-C6, halogénalkyle C1-C6, halogénalcoxy C1-C6, halogénalkylthio C1-C6, alkylthio C1-C6-(alkyl C1-C6)-carbonyle, (alkyl C1-C6)imino-oxycarbonyle, alcoxy C1-C6-alkyle C1-C6, alcoxy C1-C6-amino-alkyle C1-C6, alcoxy C1-C6-alkylamino-alkyle C1-C6, 2) éventuellement alcoxy C1-C6, alkylthio C1-C6, cycloalkoxy C3-C6, cycloalkylthio C3-C6, alcényloxy C2-C6, alcénylthio C2-C6, alcynyloxy C2-C6, alcynylthio C2-C6, (alkyl C1-C6)carbonyloxy, (alkyl C1-C6)carbonylthio, (alkoxy C1-C6)carboxyloxy, (alcényl C2-C6)carbonyloxy, (alcényl C2-C6)carbonylthio, (alcynyl C2-C6)carbonyloxy, (alcynyl C2-C6)carbonylthio, alkylsulfonyloxy C1-C6 ou Alkylsulfonyl C1-C6 substitués, 3) 29 groupes additionnels; R9 = H, alkyle C1-C6, cycloalkyle C3-C6, alcényle C3-C6, alcynyle C3-C6, alkoxy C1-C6-alkyle C1-C6, (alkoxy C1-C6)carbonyl-alkyle C1-C6, (alcényloxy C3-C6)carbonyle-alkyle C1-C6, éventuellement phényle substitué ou phényl-alkyle C1-C6.

  这是一项涉及3-苯并噻吩取代物及其盐和甲基醚的发明，用于化学除草剂的使用。在该公式中，X代表-O-、-S-、-N(R9)-；R1代表CN、1-4号碳链基团、1-4号碳链基团含卤素、1-4号碳链基团含氧、1-4号碳链基团硫基；R2代表H或可选的1-6号碳链基团、1-6号碳链基团碳骨架、1-6号碳链基团硫基、2-6号烯基、2-6号烯基碳骨架、2-6号氮烯基、2-6号氮烯基碳骨架；R3代表H、卤素；R4代表CN、卤素、1-3号碳链含卤素；R5代表H、CN、卤素、1-3号碳链含卤素；R6代表H、CN、卤素、1-3号碳链含卤素或可选的1-6号氧杂基团；R7代表CN、卤素；R8位于Rb(g)(a)，当R7位于Rb(g)(b)时，或位于Rb(g)(b)，当R7位于Rb(g)(a)时。1) H、OH、SH、CN、NO2、卤素、1-6号碳链基团、1-6号碳链含卤素、1-6号碳氧含卤素基团、1-6号碳链硫基、1-6号碳链硫基碳骨架、1-6号氧杂基团碳链、1-6号氧杂基团碳链碳骨架、1-6号碳链硫基氧杂基团、1-6号氧杂基团碳链、1-6号氧杂基团碳链碳骨架、1-6号硫代碳链基团、1-6号硫代碳链基团；2)可选的1-6号氧杂基团、1-6号硫代碳链基团、3-6号环烷氧基、3-6号环烷硫代基团、2-6号烯氧基、2-6号烯硫代基团、2-6号键碱氧基、2-6号键碱硫代基团、1-6号碳链酸氧基、2-6号烯氧碳骨架、2-6号烯硫代基团、2-6号键碱氧碳骨架、2-6号键碱硫代碳骨架、1-6号碳链硫基氧、1-6号碳链硫基硫；3) 29个其他基团；R9代表H、1-6号碳链基团、3-6号环烷基团、3-6号烯基、3-6号键碱基团、1-6号氧杂基团碳链基团、3-6号烯基氧骨架碳骨架、可选的苯基或苯基1-6号碳链基团。
• 1-AMINO-3-BENZYLURACILE
  申请人：BASF AKTIENGESELLSCHAFT

  公开号：EP0835248A1

  公开（公告）日：1998-04-15