S-cinnamyl diethyl dithiocarbamate | 89045-69-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: S-cinnamyl diethyl dithiocarbamate
• 英文别名: 3-Phenylprop-2-en-1-yl diethylcarbamodithioate；3-phenylprop-2-enyl N,N-diethylcarbamodithioate
• CAS: 89045-69-2
• 化学式: C₁₄H₁₉NS₂
• 分子量: 265.444
• InChiKey: USTRRPOSPKLFKB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  17
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  60.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-氯苯甲醇 以 二氯甲烷 、 乙腈 为溶剂， 反应 0.33h， 生成 S-cinnamyl diethyl dithiocarbamate
  参考文献：
  名称：

  Bandgar; Sadavarte; Uppalla, Journal of Chemical Research - Part S, 2000, # 9, p. 450 - 451

  摘要：

  DOI：

文献信息

• <i>S</i>-Alkylation of dithiocarbamates <i>via</i> a hydrogen borrowing reaction strategy using alcohols as alkylating agents
  作者：Hima P、Spandan Hati、Raju Dey

  DOI：10.1039/d3ob00958k

  日期：——

  synthesis of S-benzyl/alkyl dithiocarbamates via a hydrogen borrowing reaction between alcohols and dithiocarbamate anions catalyzed using a hydroxyapatite-supported copper nano-catalyst. This strategy has a broad substrate scope and offers high yields of products using inexpensive and readily available alcohols as starting materials. The catalyst was prepared by easy and straightforward methods and

  在此，我们报告了一种操作简单、环境友好且可扩展的方法，通过使用羟基磷灰石负载的铜纳米催化剂催化醇和二硫代氨基甲酸根阴离子之间的借氢反应来合成S-苄基/烷基二硫代氨基甲酸酯。该策略具有广泛的底物范围，并使用廉价且容易获得的醇作为起始材料提供高产率的产品。该催化剂通过简单直接的方法制备，并通过多种分析技术进行分析，例如FESEM、HR-TEM、BET、XRD、EDS和XPS，证明了Cu纳米颗粒在零氧化态下锚定在羟基磷灰石上。
• S-cinnamyl esters of thiocarbonic acids as additives to lubricating oils
  作者：N. P. Mustafaev、M. A. Kulieva、Yu. B. Ramazanova、K. N. Mustafaev、N. N. Novotorzhina

  DOI：10.1134/s1070427208090085

  日期：2008.9

  A series of cinnamul esters of xanthic, trithiocarbonic, and dithiocarbamic acids were prepared. The optimal conditions of their synthesis were found. The cinnamyl esters were studied by thermal analysis, and the dependence of their lubricating power on the composition and structure was revealed. The tribological properties of lubricating oils with additions of cinnamyl esters of thiocarbonic acids were studied. A correlation between the structure of the esters synthesized and their antiscuff properties was found.