4-phenyl-1,2-epocycyclohexane | 35901-91-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环己烷
• 英文名称: 4-phenyl-1,2-epocycyclohexane
• 英文别名: 1,2-epoxy-4-phenyl-cyclohexane；1,2-Epoxy-4-phenyl-cyclohexan；3-Phenyl-7-oxabicyclo[4.1.0]heptane
• CAS: 35901-91-8
• 化学式: C₁₂H₁₄O
• 分子量: 174.243
• InChiKey: KQNIOTJMXWFGHV-UHFFFAOYSA-N

物化性质

• 沸点：
  274.8±9.0 °C(Predicted)
• 密度：
  1.086±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4-phenyl-1,2-epocycyclohexane 在 三氟化硼 、 丙酮 作用下， 生成 4-苯基-1,2-环己二醇
  参考文献：
  名称：

  关于水合芳香族环氧树脂。第二次通讯†

  摘要：

  Diels - Alder二烯合成的某些加合物的环氧化反应生成了3,4-环氧-环己烷-腈（1），3,4-环氧-1-羰基甲氧基-环己烷和3,4-环氧-1-苯基-环己烷的二氧化物显示了三个异构体双丁二烯醌。

  DOI：

  10.1002/hlca.19570400605
• 作为产物：
  描述：

  过氧乙酸 、 alkaline earth salt of/the/ methylsulfuric acid 生成 4-phenyl-1,2-epocycyclohexane
  参考文献：
  名称：

  关于水合芳香族环氧树脂。第二次通讯†

  摘要：

  Diels - Alder二烯合成的某些加合物的环氧化反应生成了3,4-环氧-环己烷-腈（1），3,4-环氧-1-羰基甲氧基-环己烷和3,4-环氧-1-苯基-环己烷的二氧化物显示了三个异构体双丁二烯醌。

  DOI：

  10.1002/hlca.19570400605

文献信息

• Lubricating composition for cylinders of marine two-stroke diesel engines
  申请人：Infineum International Limited

  公开号：EP1085076A1

  公开（公告）日：2001-03-21

  The cylinders of a two-stroke cross-head marine diesel engine characterised by a power output of 4,000 kW per cylinder or greater are lubricated by a cylinder lubricant comprising a basestock of lubricating viscosity, on overbased metal detergent and an oil-soluble sulfur-containing compound or phosphorus-containing compound, thereby to raise the onset temperature of scuffing-type mechanical wear of the cylinder walls.

  二冲程十字头船用柴油机的气缸由气缸润滑剂润滑，气缸润滑剂包括润滑粘度基质、过基金属洗涤剂和油溶性含硫化合物或含磷化合物，其特点是每缸输出功率为 4,000 千瓦或更大，从而提高了气缸壁擦伤型机械磨损的起始温度。
• Trunk piston engine lubrication
  申请人：Infineum International Limited

  公开号：EP1191088A1

  公开（公告）日：2002-03-27

  A lubricant suitable for use in a trunk piston diesel engine characterised by a power output of 200 kW or greater. The trunk piston diesel engine may be for use in marine, power generation or rail traction applications. The lubricant comprises a basestock of lubricating viscosity, an overbased metal detergent, preferably having an ash content of at least 0.85% sulfated ash, and an ashless or metal-free auxiliary additive comprising at least one of: an oil-soluble sulfurized alkylphenol, a phosphorosulfurized or sulfurized hydrocarbon, a sulfide of an oil, a fat or a polyolefin, or an amine phosphate.

  一种适用于输出功率为 200 千瓦或更大的干式活塞柴油发动机的润滑油。干式活塞柴油发动机可用于船舶、发电或铁路牵引应用。润滑剂包括具有润滑粘度的基质、过碱金属洗涤剂（灰分含量最好至少为 0.85% 的硫酸盐灰分）和无灰或无金属辅助添加剂，其中辅助添加剂至少包括以下一种：油溶性硫化烷基酚、磷化硫化或硫化碳氢化合物、油、脂肪或聚烯烃的硫化物或磷酸胺。
• Combinations of phosphorus-containing compounds for use as anti-wear additives in lubricant compositions
  申请人：Afton Chemical Corporation

  公开号：EP2298854A1

  公开（公告）日：2011-03-23

  The present disclosure relates to a lubricant composition comprising a first phosphorus compound, a second phosphorus compound, and a third phosphorus compound, wherein the first phosphorus compound is present in the lubricant composition in an amount to provide between about 120 and 350 ppm phosphorus. The lubricant composition may provide robust anti-wear and reduced pitting.

  本公开涉及一种包含第一磷化合物、第二磷化合物和第三磷化合物的润滑剂组合物，其中第一磷化合物在润滑剂组合物中的含量为约 120 至 350 ppm。该润滑油组合物可提供强大的抗磨性并减少点蚀。
• Combinations of phosphorous-containing compounds for use as anti-wear additives in lubricant compositions
  申请人：Afton Chemical Corporation

  公开号：US11214750B2

  公开（公告）日：2022-01-04

  The present disclosure relates to a lubricant composition comprising a first phosphorus compound, a second phosphorus compound, and a third phosphorus compound, wherein the first phosphorus compound is present in the lubricant composition in an amount to provide between about 120 and 350 ppm phosphorus. The lubricant composition may provide robust anti-wear and reduced pitting.

  本公开涉及一种包含第一磷化合物、第二磷化合物和第三磷化合物的润滑剂组合物，其中第一磷化合物在润滑剂组合物中的含量为约 120 至 350 ppm。该润滑油组合物可提供强大的抗磨性并减少点蚀。
• Building with Cubane-1,4-diyl. Synthesis of Aryl-Substituted Cubanes, <i>p</i>-[<i>n</i>]Cubyls, and Cubane-Separated Bis(arenes)¹
  作者：Philip E. Eaton、Kakumanu Pramod、Todd Emrick、Richard Gilardi

  DOI：10.1021/ja983441f

  日期：1999.5.1

  On treatment with an organolithium 1,4-diiodocubane generates cubane-1,4-diyl, a highly reactive species, shown here to be a versatile precursor to numerous aryl substituted cubanes, available now for the first time in high yield. The diyl is demonstrated to provide a good route to bicubyl and its derivatives. A kind of "living polymerization" of the diyl is developed to give the p-[n]cubyls. These oligomers are rigid rods made up of cubanes linked together at the 1 and 4 positions, each cubane adding similar to 4.15 Angstrom to the length. The properties of these rods, some more than 15 Angstrom long, are discussed, as are methods for modifying their solubility. X-ray crystallographic analyses of some of these compounds an presented, with emphasis on packing parameters.