2-acetyl-2H-phthalazin-1-one | 1133-73-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: 2-acetyl-2H-phthalazin-1-one
• 英文别名: 2-Acetyl-2H-phthalazin-1-on；2-Acetyl-1-oxo-1,2-dihydro-phthalazin；2-Acetyl-phthalazon-(1)；2-Acetylphthalazin-1-one
• CAS: 1133-73-9
• 化学式: C₁₀H₈N₂O₂
• 分子量: 188.186
• InChiKey: PZTWFIMBPRYBOD-UHFFFAOYSA-N

物化性质

• 沸点：
  347.3±25.0 °C(Predicted)
• 密度：
  1.29±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.4
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  49.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  邻羧基苯甲醛 生成 2-acetyl-2H-phthalazin-1-one
  参考文献：
  名称：

  Liebermann; Bistrzycki, Chemische Berichte, 1893, vol. 26, p. 534

  摘要：

  DOI：

文献信息

• Photothermographic element comprising improved base precursors and methods for their use
  申请人：——

  公开号：US20040185352A1

  公开（公告）日：2004-09-23

  Photothermographic elements employing improved base precursors that undergo thermal decomposition are disclosed. Thermal-dye-bleach agents, and in particular, a novel class of salts of arylsulfonylacetic acids as bleaching agents for photothermographic use are disclosed. Photothermographic elements employing these thermal-dye-bleach agents are suitable for use as acutance and antihalation systems, bleachable filter dye materials, and in promoting unblocking of various components such as blocked developers, especially in photothermographic elements.

  本发明公开了采用经过热分解的改进型基体前体的光热元件。公开了热染料漂白剂，特别是一类新型的芳基磺酰乙酸盐作为光热使用漂白剂。采用这些热染料漂白剂的光热元件适用于用作锐度和防晕染系统、可漂白滤光片染料材料，以及促进各种组分的去阻塞，特别是在光热元件中。
• Imaging element containing a blocked photographically useful compound
  申请人：EASTMAN KODAK COMPANY

  公开号：EP1113322A2

  公开（公告）日：2001-07-04

  This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: wherein the substituents are as defined in the specification.

  本发明涉及一种成像元件，该元件由成像层组成，成像层中含有结构 I 的化合物： 其中取代基如说明书中所定义。
• Color photothermographic elements comprising blocked developing agents
  申请人：EASTMAN KODAK COMPANY

  公开号：EP1164418A2

  公开（公告）日：2001-12-19

  This invention relates to a color photothermographic element comprising an imaging layer having associated therewith a compound of Structure I: wherein DEV, LINK, TIME, n, T, t, C*, R12,D, p, X, q, W, and w are defined in the application. Such compounds have good reactivity as developing agents when thermally activated under preselected conditions. The invention is also directed to a method of developing a color photothermographic element, including dry development systems.

  本发明涉及一种彩色光热成像元件，该元件由成像层组成，成像层中含有结构 I 的化合物： 其中 DEV、LINK、TIME、n、T、t、C*、R12、D、p、X、q、W 和 w 在本申请中定义。在预选条件下进行热活化时，此类化合物作为显影剂具有良好的反应活性。本发明还涉及一种彩色光热成像元件的显影方法，包括干式显影系统。
• An aqueous thermally bleachable composition useful in a photothermographic element
  申请人：EASTMAN KODAK COMPANY

  公开号：EP1217431A2

  公开（公告）日：2002-06-26

  This invention relates to a photothermographic element comprising a support, at least one photothermographic image-receiving layer, and at least one antihalation layer or a filter layer, wherein the antihalation or filer layer comprises an aqueous heat-bleachable composition comprising at least one dye and at least one hexaarylbiimidazole in the form of particles dispersed in a matrix comprising a hydrophilic or aqueous dispersible polymer.

  本发明涉及一种光热成像元件，该元件包括一个支架、至少一个光热成像图像接收层和至少一个防光晕层或过滤层，其中防光晕层或过滤层包括一种水性热漂白组合物，该组合物包括至少一种染料和至少一种六芳基咪唑，该染料和六芳基咪唑以颗粒的形式分散在由亲水性或水分散性聚合物组成的基质中。
• Photographic element containing a high-dye-yield coupler for producing a yellow hue
  申请人：EASTMAN KODAK COMPANY

  公开号：EP1291715A2

  公开（公告）日：2003-03-12

  A color photographic element is disclosed comprising at least three light-sensitive units which have their individual sensitivities in different wavelength regions, comprising at least one imaging layer comprising a light-sensitive silver-halide emulsion, binder, and a yellow coupler represented by the following structure: Wherein COUP is a photographic coupler residue capable of coupling with oxidized color developer to form a first yellow dye L is a linking group selected from the group consisting of -OC(=O)-, -OC(=S)-, -SC(=O)-, and -SC(=S)-, and -DYE is a releasable second yellow dye or yellow dye precursor, wherein COUP is an acetanilide compound that contains one or more electron-withdrawing groups such that the pKa at the coupling site is less than 8.7. Such yellow couplers improve activity and enhance dye densities.

  本发明公开了一种彩色感光元件，该元件由至少三个感光单元组成，它们在不同的波长区域具有各自的感光度，至少包括一个成像层，该成像层由感光卤化银乳剂、粘合剂和黄色耦合剂组成，其结构如下： 其中 COUP 是能与氧化显色剂偶联形成第一种黄色染料的感光偶联剂残基 L 是选自-OC(＝O)-、-OC(＝S)-、-SC(＝O)-和-SC(＝S)-的连接基团，-DYE 是可释放的第二种黄色染料或黄色染料前体，其中 COUP 是乙酰苯胺化合物，它含有一个或多个抽电子基团，使偶联位点的 pKa 小于 8。7.这种黄色偶联剂可提高活性和染料密度。