1,1,3,3,5-penta(2-naphthoxy)-5-[(4-benzyloxy)phenoxy]cyclotriphosphazatriene | 1359720-90-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,1,3,3,5-penta(2-naphthoxy)-5-[(4-benzyloxy)phenoxy]cyclotriphosphazatriene
• 英文别名: 2,2,4,4,6-Pentanaphthalen-2-yloxy-6-(4-phenylmethoxyphenoxy)-3-aza-1,5-diazanida-2lambda5-phospha-4,6-diphosphoniacyclohex-2-ene；2,2,4,4,6-pentanaphthalen-2-yloxy-6-(4-phenylmethoxyphenoxy)-3-aza-1,5-diazanida-2λ5-phospha-4,6-diphosphoniacyclohex-2-ene
• CAS: 1359720-90-3
• 化学式: C₆₃H₄₆N₃O₇P₃
• 分子量: 1050.0
• InChiKey: OKJMQVIIEZDJFX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  18.4
• 重原子数：
  76
• 可旋转键数：
  15
• 环数：
  13.0
• sp3杂化的碳原子比例：
  0.02
• 拓扑面积：
  79
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  1,1,3,3,5-penta(2-naphthoxy)-5-[(4-benzyloxy)phenoxy]cyclotriphosphazatriene 在 20 wt.% Pd(OH)2 on activated carbon 、 环己烯 作用下， 以 四氢呋喃 、 乙醇 为溶剂， 反应 24.0h， 以62%的产率得到1,1,3,3,5-penta(2-naphthoxy)-5-[(4-hydroxy)phenoxy]cyclotriphosphazatriene
  参考文献：
  名称：

  Synthesis, thermal and photophysical properties of naphthoxycyclotriphosphazenyl-substituted dendrimeric cyclic phosphazenes

  摘要：

  The synthesis and properties of naphthoxycyclotriphosphazenyl-substituted dendrimeric cyclic phosphazenes are reported. Compound 3, [N3P3(ONp)(5)OPhOH], is prepared by the sequential reactions of hexachlorocyclotriphosphazene with 2-naphthol and 4-benzyloxyphenol derivatives, as side groups. The dendrimeric compounds 5,6 and 7 have been obtained by the reactions of compound 3 with hexachlorocyclotriphosphazene, N3P3Cl6, octachlorocyclotetraphosphazene, N4P4Cl8, and bisphenol bridged cyclophosphazene, N6P6Cl10 (4), respectively. The newly synthesized compounds have been fully characterized by elemental analysis, ESI, MALDI-TOF mass spectrometry, FT-IR, H-1, C-13 and P-31 NMR spectroscopy. The thermal stability and fluorescence spectral properties of all these novel compounds are investiga ted. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.01.013
• 作为产物：
  描述：

  4-苄氧基苯酚 、 2,2,4,4,6-pentanaphthoxy-6-chlorocyclotriphosphazene 在 caesium carbonate 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 以61%的产率得到1,1,3,3,5-penta(2-naphthoxy)-5-[(4-benzyloxy)phenoxy]cyclotriphosphazatriene
  参考文献：
  名称：

  Synthesis, thermal and photophysical properties of naphthoxycyclotriphosphazenyl-substituted dendrimeric cyclic phosphazenes

  摘要：

  The synthesis and properties of naphthoxycyclotriphosphazenyl-substituted dendrimeric cyclic phosphazenes are reported. Compound 3, [N3P3(ONp)(5)OPhOH], is prepared by the sequential reactions of hexachlorocyclotriphosphazene with 2-naphthol and 4-benzyloxyphenol derivatives, as side groups. The dendrimeric compounds 5,6 and 7 have been obtained by the reactions of compound 3 with hexachlorocyclotriphosphazene, N3P3Cl6, octachlorocyclotetraphosphazene, N4P4Cl8, and bisphenol bridged cyclophosphazene, N6P6Cl10 (4), respectively. The newly synthesized compounds have been fully characterized by elemental analysis, ESI, MALDI-TOF mass spectrometry, FT-IR, H-1, C-13 and P-31 NMR spectroscopy. The thermal stability and fluorescence spectral properties of all these novel compounds are investiga ted. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.01.013