2-(1-Naphthyl)-5-(4-vinylphenyl)-1,3,4-oxadiazole | 197089-41-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2-(1-Naphthyl)-5-(4-vinylphenyl)-1,3,4-oxadiazole
• 英文别名: 2-(4-Ethenylphenyl)-5-naphthalen-1-yl-1,3,4-oxadiazole
• CAS: 197089-41-1
• 化学式: C₂₀H₁₄N₂O
• 分子量: 298.344
• InChiKey: GBKPXHHFQITEQS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  23
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  38.9
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-(1-Naphthyl)-5-(4-vinylphenyl)-1,3,4-oxadiazole 、 乙烯基三乙氧基硅烷 在 Grubbs catalyst first generation 作用下， 以 苯 为溶剂， 反应 16.0h， 以12%的产率得到2-(1-Naphthyl)-5-{4-[(E)-(triethoxysilyl)]ethenylphenyl}-1,3,4-oxadiazole
  参考文献：
  名称：

  Functionalisation of 2-(1-Naphthyl)-5-phenyl-1,3,4-oxadiazole with Alkoxysilanes

  摘要：

  通过Heck反应，以溴化合物3与乙烯基烷氧基硅烷4、5、6反应，以及通过钯催化的乙烯基化反应与苯乙烯11和与乙烯基硅烷的交叉复分解反应，描述了制备具有刚性连接到烷氧基硅烷7、8、9的2,5-二芳基-1,3,4-噁二唑的短路线。通过硅烷取代的苯乙烯13，可以将共轭系统扩展到14。

  DOI：

  10.1055/s-2001-13420
• 作为产物：
  描述：

  5-(naphthalen-1-yl)-1H-tetrazole 在 palladium diacetate 吡啶 、 三乙胺 、 三(邻甲基苯基)磷 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 100.0 ℃ 、3.0 MPa 条件下， 反应 41.5h， 生成 2-(1-Naphthyl)-5-(4-vinylphenyl)-1,3,4-oxadiazole
  参考文献：
  名称：

  Functionalisation of 2-(1-Naphthyl)-5-phenyl-1,3,4-oxadiazole with Alkoxysilanes

  摘要：

  通过Heck反应，以溴化合物3与乙烯基烷氧基硅烷4、5、6反应，以及通过钯催化的乙烯基化反应与苯乙烯11和与乙烯基硅烷的交叉复分解反应，描述了制备具有刚性连接到烷氧基硅烷7、8、9的2,5-二芳基-1,3,4-噁二唑的短路线。通过硅烷取代的苯乙烯13，可以将共轭系统扩展到14。

  DOI：

  10.1055/s-2001-13420

文献信息

• Nitrogen-containing heterocyclic compound
  申请人：——

  公开号：US20030057826A1

  公开（公告）日：2003-03-27

  A nitrogen-containing heterocyclic compound represented by the following formula (I): 1 wherein X 1 and X 2 each represent an electron attractive group such as a cyano group; and the rings Z 1 and Z 2 each represent a hydrocarbon ring or a heterocycle (e.g., benzene ring having an electron donative group such as hydroxyl group, an alkoxy group, amino group and an N-substituted amino group, or a condensed ring being a benzene ring condensed with a heterocycle having a nitrogen atom as a hetero atom) is provided. An organic EL device is obtained by allowing an organic layer containing the compound described-above to be interposed between a pair of electrodes. The present invention provides a nitrogen-containing heterocyclic compound useful as a functional material and a process for producing the same, and an organic EL device using the same.

  提供一种含氮杂环化合物，其化学式如下（I）：其中X1和X2各代表一个电子吸引基团，如氰基；环Z1和Z2各代表一个碳氢环或杂环（例如，苯环具有一个电子给体基团，如羟基、烷氧基、氨基和N-取代氨基，或者是一个与氮原子作为杂原子的杂环缩合环的苯环）。通过在一对电极之间插入含有上述化合物的有机层，可以获得有机EL器件。本发明提供了一种作为功能材料有用的含氮杂环化合物，以及制备该化合物的方法和使用该化合物的有机EL器件。
• Azepine compounds
  申请人：——

  公开号：US20020091256A1

  公开（公告）日：2002-07-11

  The azepine compound capable of emitting a light by light-irradiation or action of an electric field is represented by the following formula (I) or (II): 1 wherein X 1 and X 2 are the same or different, each representing an electron attractive group; R 1 represents a hydrogen atom, an alkyl group, an aryl group, an aralkyl group, or an alkoxy group; R 2 represents an amino group or an N-substituted amino group, or, in the formula (I), R 2 bonds a carbon atom adjacent to a ring Z to form a ring; and the ring Z represents a hydrocarbon ring which may have a substituent or a heterocycle which may have a substituent. The compound is useful as a functional material, thus, an organic electroluminescence device can be obtained by interposing an organic layer composed of the above compound between a pair of electrodes.

  具有通过光照射或电场作用而发出光的氮杂环化合物的化学式如下（I）或（II）：1其中，X1和X2相同或不同，分别表示电子吸引基团；R1表示氢原子、烷基、芳基、芳基烷基或烷氧基；R2表示氨基或N-取代氨基，或在式（I）中，R2与环Z相邻的碳原子连接以形成环；环Z表示可能具有取代基的碳氢环或可能具有取代基的杂环。该化合物可用作功能材料，因此，在一对电极之间插入由上述化合物组成的有机层可获得有机电致发光器件。
• Material for organic electroluminescence device and process for producing the same
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP1107331A2

  公开（公告）日：2001-06-13

  An organic electroluminescence material is produced by bringing a source (1) containing at least an emission center-forming compound absorptive of a laser beam and defined in the predetermined pattern into contact with targets (2a, 2b) which is transmittable of the laser beam and has at least one function selected from an electron-transporting function and a hole-transporting function, and irradiating with the laser beam from the target (2) side to implant the emission center-forming compound (3) contained in the source (1) into the target (2a). The organic electroluminescence device thus obtained has emission centers in the area corresponding to the pattern of the source. The source may be constituted solely of the emission center-forming compound. The present invention provides an organic EL material susceptible of fine patterning, a process for producing the same, and an organic EL device using the same.

  生产有机电致发光材料的方法是：将至少含有可吸收激光束并以预定图案确定的发射中心形成化合物的光源（1）与可透过激光束并具有至少一种从电子传输功能和空穴传输功能中选择的功能的靶材（2a、2b）接触，并用激光束从靶材（2）一侧照射，将光源（1）中所含的发射中心形成化合物（3）植入靶材（2a）中。这样得到的有机电致发光装置在与光源图案相对应的区域内具有发射中心。光源可以完全由形成发射中心的化合物构成。本发明提供了一种可精细图案化的有机电致发光材料、一种生产该材料的工艺以及一种使用该材料的有机电致发光器件。
• MATERIAL FOR ORGANIC ELECTROLUMINESCENCE DEVICE AND ITS MANUFACTURING METHOD
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP1347670A1

  公开（公告）日：2003-09-24

  A process for producing for a material for an organic electroluminescent device having an emission center comprises irradiating a laser beam to implant an emission center-forming compound 3 constituting a source 1 into a target 2 having at least one function selected from an electron-transporting function and a hole-transporting function. According to the process, the laser beam and at least the target are relatively moved with irradiating the beam to form the emission center with a predetermined pattern. Moreover, the source and the target being in contact with each other may be moved relative to the laser beam for forming the emission center with a predetermined pattern. Further, the emission center at an area, corresponding to an interference pattern of an interference light, of the target may be formed by irradiating the interference light of the laser beam.

  一种用于生产具有发射中心的有机电致发光器件材料的工艺，包括照射一束激光，将构成光源1的发射中心形成化合物3植入具有至少一种从电子传输功能和空穴传输功能中选择的功能的靶2中。根据该工艺，激光束和至少靶标在照射激光束时相对移动，以形成具有预定图案的发射中心。此外，相互接触的光源和目标可以相对于激光束移动，以形成具有预定图案的发射中心。此外，还可以通过照射激光束的干涉光，在目标的干涉光干涉图案对应的区域形成发射中心。
• PHOSPHORS AND PROCESS FOR PRODUCTION THEREOF, LUMINESCENT COMPOSITIONS, AND ORGANIC ELECTROLUMINESCENT DEVICES AND PROCESSES FOR PRODUCTION THEREOF
  申请人：JSR Corporation

  公开号：EP1516901A1

  公开（公告）日：2005-03-23

  Disclosed herein are, a phosphorescent agent which can form a thin film by a wet method and provide an organic electroluminescence device having high luminance and production process thereof, and a luminescent composition containing the phosphorescent agent, an organic electroluminescence device having a luminescent layer containing the phosphorescent agent and production process thereof. A phosphorescent agent according to the present invention comprising a polymer having in its molecule a structural unit represented by the following general formula (1). [In the general formula (1), M represents a metal atom having a valence of 2 to 4, each of R1 and R2 represents a hydrogen atom, a halogen atom, a cycloalkyl group, an aryl group and a heterocycle group and R1 and R2 may be either the same or different, X1 represents a phenylene group or a carbonyloxy group, X2 represents an alkylene group, L represents an organic ligand, p is an integer of 1 to 3, and q is 0 or 1.]

  本发明公开了一种可通过湿法形成薄膜并提供具有高亮度的有机电致发光器件的磷光剂及其生产工艺，以及一种含有该磷光剂的发光组合物、一种具有含有该磷光剂的发光层的有机电致发光器件及其生产工艺。 根据本发明的磷光剂包括一种聚合物，其分子中具有由以下通式（1）表示的结构单元。 [通式（1）中，M 代表价数为 2 至 4 的金属原子，R1 和 R2 分别代表氢原子、卤素原子、环烷基、芳基和杂环基，且 R1 和 R2 可以相同或不同，X1 代表亚苯基或碳酰氧基，X2 代表亚烷基，L 代表有机配位体，p 为 1 至 3 的整数，q 为 0 或 1。］