N'-butylhydrazinecarbodithioic acid decyl ester | 1138320-56-5

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫基化合物
• 英文名称: N'-butylhydrazinecarbodithioic acid decyl ester
• 英文别名: decyl 2-butylhydrazinecarbodithiolate；N'-butylhydrazinecarbodithioic acid n-decyl ester；decyl 2-butylhydrazinecarbodithioate；Decyl 2-butylhydrazinecarbodithioate；decyl N-(butylamino)carbamodithioate
• CAS: 1138320-56-5
• 化学式: C₁₅H₃₂N₂S₂
• 分子量: 304.564
• InChiKey: XRKOJVQJAMBIFW-UHFFFAOYSA-N

物化性质

• 熔点：
  120 °C
• 沸点：
  390.7±25.0 °C(predicted)
• 密度：
  0.973±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  19
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  81.4
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  二硫化碳 、 丁基肼 、 癸醇 在 三苯基膦 、 偶氮二甲酸二乙酯 作用下， 以 二甲基亚砜 为溶剂， 反应 1.5h， 以98%的产率得到N'-butylhydrazinecarbodithioic acid decyl ester
  参考文献：
  名称：

  使用Mitsunobu试剂通过相应的醇有效地一锅法合成氨基甲酸酯和二硫代氨基甲酸酯

  摘要：

  使用Mitsunobu的试剂和CO 2 / CS 2系统，已开发出一种新颖的基于Mitsunobu的新方案，可通过使用Mitsunobu的试剂和CO 2 / CS 2系统通过各种相应的伯醇，仲醇和叔醇以及各种取代的肼来合成氨基甲酸酯和二硫代氨基甲酸酯。

  DOI：

  10.1007/bf03249073

文献信息

• Triton-B Catalyzed, Green and Efficient Method for the Synthesis of Dithiocarbazates
  作者：Sadaf Zaidi、Mridula Saxena

  DOI：10.14233/ajchem.2019.21973

  日期：2019.6.10

  A novel, solvent free and high yielding method was accomplished for one-pot synthesis of dithiocarbazates by the reaction of various alkyl halides (primary, secondary and tertiary) with variety of substituted hydrazines using Triton-B (benzyl-trimethylammonium hydroxide) and carbon di sulphide. This new method of synthesizing dithiocarbazates involves mild conditions, simple procedures and high yields of the products as compared to previously used methods.

  一种新颖的无溶剂高产率的方法被成功实现，用于通过不同烷基卤化物（初级、次级和三级）与多种取代肼的反应，进行一步法合成二硫 Carbazates，所使用的试剂为 Triton-B（苄基三甲基铵氢氧化物）和二硫化碳。与之前采用的方法相比，这种新方法在合成二硫 Carbazates 方面具有温和的反应条件、简单的操作过程和高产率的优势。
• Efficient TBAI-CS₂ Promoted Synthesis of Substituted Hydrazinecarbodithiolates
  作者：Nitin Srivastava

  DOI：10.1080/00304948.2022.2111171

  日期：2022.11.2

  Published in Organic Preparations and Procedures International: The New Journal for Organic Synthesis (Vol. 54, No. 6, 2022)

  发表于国际有机制剂和程序：有机合成新期刊（印刷前，2022 年）
• An Efficient, Basic Resin-Mediated, One-Pot Synthesis of Dithiocarbazates Through Alcoholic Tosylates
  作者：Devdutt Chaturvedi、Nisha Mishra、Amit K. Chaturvdi、Virendra Mishra

  DOI：10.1080/10426500802203137

  日期：2009.3.10

  A quick and efficient, one-pot synthesis of dithiocarbazates was accomplished in high yields by the reaction of various alcoholic tosylates of primary, secondary, and tertiary alcohols, with substituted hydrazines using an Amberlite IRA 400 (basic resin)/CS2 system. The reaction conditions are mild with simpler work-up procedures than previously reported methods.
• Triton-B-Catalyzed, Efficient, One-Pot Synthesis of Dithiocarbazates Through Alcoholic Tosylates
  作者：Devdutt Chaturvedi、Nisha Mishra、Amit K. Chaturvedi、Virendra Mishra

  DOI：10.1080/00397910802519141

  日期：2009.3.10

  A quick, efficient, one-pot synthesis of dithiocarbazates was accomplished in high yields by the reaction of various tosylates of primary, secondary, and tertiary alcohols with a variety of substituted hydrazines using the benzyl-trimethylammonium hydroxide (Triton-B)/CS2 system. The reaction conditions are mild with simpler workup procedures than the reported methods.
• Triton-B catalyzed, efficient one-pot synthesis of dithiocarbazates
  作者：Devdutt Chaturvedi、Nisha Mishra、Virendra Mishra

  DOI：10.1007/s00706-008-0873-9

  日期：2008.9

  A quick and efficient, one-pot synthesis of dithiocarbazates was accomplished in high yields by the reaction of various primary, secondary, and tert. alkyl halides with a variety of substituted hydrazines using the benzyl-trimethylammonium hydroxide (Triton-B)/CS2 system. The reaction conditions are mild with simpler work-up procedures than the reported methods.