3',4'-Dihydrospirohept-5-en-2,2'(1'H)-naphthalin>-1'-on | 7353-70-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 四氢化萘
• 英文名称: 3',4'-Dihydrospirohept-5-en-2,2'(1'H)-naphthalin>-1'-on
• 英文别名: 1,2-Benzo-cyclohexenon-3-4-spiro-5'-bicyclo<2.2.1>hepten-2'；Spiro[3,4-dihydronaphthalene-2,5'-bicyclo[2.2.1]hept-2-ene]-1-one
• CAS: 7353-70-0
• 化学式: C₁₆H₁₆O
• 分子量: 224.302
• InChiKey: UFRRAVBSKASZOZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3',4'-Dihydrospirohept-5-en-2,2'(1'H)-naphthalin>-1'-on 在 3-苄基羟乙基甲基噻唑氯化锂 三乙胺 作用下， 以 乙醇 为溶剂， 60.0~550.0 ℃ 、1.33 kPa 条件下， 反应 15.0h， 生成 3,4-Dihydro-2-(2-oxobutyl)-1(2H)-naphthalinon
  参考文献：
  名称：

  Stetter, Hermann; Haese, Wilfried, Chemische Berichte, 1984, vol. 117, # 2, p. 682 - 693

  摘要：

  DOI：
• 作为产物：
  描述：

  2-Piperidinomethyl-tetralon-(1) 、 环戊二烯 在 对苯二酚 作用下， 以 甲苯 为溶剂， 反应 7.0h， 生成 3',4'-Dihydrospirohept-5-en-2,2'(1'H)-naphthalin>-1'-on
  参考文献：
  名称：

  Brugidou,J.; Christol,H., Bulletin de la Societe Chimique de France, 1966, p. 1693 - 1698

  摘要：

  DOI：

文献信息

• METHOD FOR PRODUCING NORBORNENE DERIVATIVE
  申请人：Komatsu Shinichi

  公开号：US20120108851A1

  公开（公告）日：2012-05-03

  A method for producing a norbornene derivative includes forming a Mannich base represented by any of general formulae (5) to (7) by reacting a carbonyl compound represented by any of general formulae (1) to (3) and an amine compound represented by general formula (4) with each other in an acidic solvent, to thereby obtain a reaction liquid comprising the Mannich base in the acidic solvent, wherein the acidic solvent comprises a formaldehyde derivative and 0.01 mol/L or more of an acid represented by formula HX; reacting the Mannich base and a diene compound represented by general formula (8) with each other by adding an organic solvent, a base in an amount of 1.0 to 20.0 equivalents to the acid, and the diene compound to the reaction liquid, and then heating the reaction liquid, to thereby form the norbornene derivative represented by any of general formulae (9) to (11).

  一种制备诺博烯衍生物的方法，包括通过在酸性溶剂中反应通式（1）到（3）中的酮类化合物和通式（4）中的胺类化合物，以形成通式（5）到（7）中的曼尼希碱基，从而在酸性溶剂中获得包含曼尼希碱基的反应液，其中酸性溶剂包括福尔马林衍生物和0.01摩尔/升或更多的通式HX的酸；通过向反应液中添加有机溶剂、1.0到20.0当量的碱和通式（8）中的二烯化合物，并加热反应液，使曼尼希碱基和二烯化合物相互反应，从而形成通式（9）到（11）中表示的诺博烯衍生物。
• INVERSELY DISPERSIVE RETARDATION FILM, AND LIQUID CRYSTAL DISPLAY DEVICE COMPRISING SAME
  申请人：JX Nippon Oil & Energy Corporation

  公开号：EP2390690A1

  公开（公告）日：2011-11-30

  A reverse dispersion retardation film, formed by stretching a film comprising a norbornene-based ring-opening copolymer containing a structural unit (A) represented by the following general formula (1): [in the formula (1), m represents an integer of any one of 0 and 1, R1 represents a hydrogen atom or the like, X1 represents a group represented by a formula: -CH2CH2- or the like, a and b each independently represent an integer of 0 to 6, Y represents a methylene group or the like, and Z represents a methylene group or the like] and a structural unit (B) represented by the following general formula (2) : [in the formula (2), n represents an integer of any one of 0 and 1, X2 represents a group represented by a formula: -CH2CH2- or the like, R2, R3, R4, and R5 each represent a hydrogen atom or the like, wavy lines d and e each represent a configuration of any one of an endo and an exo, and a wavy line f represents a configuration of any one of an endo and an exto], wherein a total amount of the structural unit (A) and an exo-form structural unit, in which the wavy line f represents the exo configuration, among the structural units (B) is not less than 20 mol% but not more than 65 mol% of all the structural units.

  一种反向分散延缓膜，由降冰片烯基开环共聚物拉伸形成，该共聚物含有由下式（1）表示的结构单元（A）： [在式 (1) 中，m 代表 0 和 1 之间的整数，R1 代表氢原子或类似物，X1 代表由式表示的基团：-CH2CH2-或类似的基团，a 和 b 各自独立地代表 0 至 6 的整数，Y 代表亚甲基或类似的基团，Z 代表亚甲基或类似的基团]和由以下通式 (2) 代表的结构单元 (B) ： [在式 (2) 中，n 代表 0 和 1 之间的整数，X2 代表由式表示的基团：-R2、R3、R4 和 R5 分别代表氢原子或类似物，波浪线 d 和 e 分别代表内向型和外向型中任何一种构型，波浪线 f 代表内向型和外向型中任何一种构型]，其中结构单元 (A) 和外向型结构单元（其中波浪线 f 代表外向型构型）在结构单元 (B) 中的总量不低于所有结构单元的 20 摩尔%，但不超过 65 摩尔%。
• PHASE DIFFERENCE FILM, ORGANIC EL DISPLAY DEVICE AND LIQUID CRYSTAL DISPLAY USING THE SAME
  申请人：JX Nippon Oil & Energy Corporation

  公开号：EP2520956A1

  公开（公告）日：2012-11-07

  A retardation film, formed by stretching a film comprising a norbornene-based ring-opening copolymer containing a structural unit (A) represented by the following general formula (1): general formula (2): [in the formula (2), m represents an integer of any one of 0 and 1, X2 represents a group represented by a formula: -CH=CH- or the like, and R2, R3, R4, and R5 each independently represent a hydrogen atom or the like], wherein a content of the structural unit (A) is not less than 5 mol % but not more than 95 mol % relative to a total amount of the structural units (A) and (B).

  一种缓凝薄膜，通过拉伸由降冰片烯基开环共聚物组成的薄膜形成，该共聚物含有 由以下通式 (1) 表示的结构单元 (A)： 通式 (2)： [在式 (2) 中，m 代表 0 和 1 之间的整数，X2 代表由式表示的基团：-CH=CH-或类似的基团，R2、R3、R4 和 R5 各自独立地代表氢原子或类似的基团]，其中 相对于结构单元（A）和（B）的总量，结构单元（A）的含量不少于 5 摩尔%，但不超过 95 摩尔%。
• STETTER, H.;HAESE, W., CHEM. BER., 1984, 117, N 2, 682-693
  作者：STETTER, H.、HAESE, W.

  DOI：——

  日期：——
• RETARDATION FILM, AND ORGANIC EL DISPLAY DEVICE AND LIQUID CRYSTAL DISPLAY DEVICE USING THE SAME
  申请人：Koike Takeshi

  公开号：US20120302713A1

  公开（公告）日：2012-11-29

  A retardation film, formed by stretching a film comprising a norbornene-based ring-opening copolymer containing a structural unit (A) represented by the following general formula (1): [in the formula (1), n represents an integer of any one of 0 and 1, R 1 represents a hydrogen atom or the like, X 1 represents a group represented by a formula: —CH═CH— or the like, a and b each independently represent an integer of 0 to 6, Ys each independently represent a methylene group or the like, and Zs each independently represent a methylene group or the like], and a structural unit (B) represented by the following general formula (2): [in the formula (2), m represents an integer of any one of 0 and 1, X 2 represents a group represented by a formula: —CH═CH— or the like, and R 2 , R 3 , R 4 , and R 5 each independently represent a hydrogen atom or the like], wherein a content of the structural unit (A) is not less than 5 mol % but not more than 95 mol % relative to a total amount of the structural units (A) and (B).