4,7,12,15-Tetrabenzhydrylidene-20-azabicyclo[16.3.1]docosa-1(22),18,20-trien-2,5,8,10,13,16-hexayne | 518287-73-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,7,12,15-Tetrabenzhydrylidene-20-azabicyclo[16.3.1]docosa-1(22),18,20-trien-2,5,8,10,13,16-hexayne
• 英文别名: 4,7,12,15-tetrabenzhydrylidene-20-azabicyclo[16.3.1]docosa-1(22),18,20-trien-2,5,8,10,13,16-hexayne
• CAS: 518287-73-5
• 化学式: C₇₃H₄₃N
• 分子量: 934.151
• InChiKey: OESAOSVGVDVBBT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  18
• 重原子数：
  74
• 可旋转键数：
  8
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  trans-dichlorobis(diethyl sulfide)platinum(II) 、 4,7,12,15-Tetrabenzhydrylidene-20-azabicyclo[16.3.1]docosa-1(22),18,20-trien-2,5,8,10,13,16-hexayne 以 二氯甲烷 为溶剂， 以40%的产率得到
  参考文献：
  名称：

  Functionalized Macrocyclic Ligands:  Big Building Blocks for Metal Coordination

  摘要：

  Two large, conjugated, macrocyclic ligands, 5a and 5b, have been efficiently prepared from easily accessible precursors. Both macrocycles incorporate a 3,5-diethynylpyridine subunit, making them suitable for further elaboration, as demonstrated via their coordination to give Pt complexes 6a and 6b.

  DOI：

  10.1021/om020738k

文献信息

• Functionalized Macrocyclic Ligands:  Big Building Blocks for Metal Coordination
  作者：Katie Campbell、Robert McDonald、Michael J. Ferguson、Rik R. Tykwinski

  DOI：10.1021/om020738k

  日期：2003.3.1

  Two large, conjugated, macrocyclic ligands, 5a and 5b, have been efficiently prepared from easily accessible precursors. Both macrocycles incorporate a 3,5-diethynylpyridine subunit, making them suitable for further elaboration, as demonstrated via their coordination to give Pt complexes 6a and 6b.