2-tosylamino(2'-pyridyl)aniline | 209965-01-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-tosylamino(2'-pyridyl)aniline
• 英文别名: 4-methyl-N-[2-(pyridin-2-yliminomethyl)phenyl]benzenesulfonamide
• CAS: 209965-01-5
• 化学式: C₁₉H₁₇N₃O₂S
• 分子量: 351.429
• InChiKey: GIMLPRYIRCIURM-UHFFFAOYSA-N

物化性质

• 沸点：
  544.5±60.0 °C(Predicted)
• 密度：
  1.22±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  25
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  79.8
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  2-tosylamino(2'-pyridyl)aniline 、 镉 在 Me₄NClO₄ 作用下， 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Electrochemical synthesis of metal (II) complexes of Schiff base 2-tosylamino (2′-pyridyl)aniline: the crystal structure of bis-[2-tosylamino(2′-pyridyl)anilinato]cobalt(II)

  摘要：

  Complexes of cobalt(II): nickel(II), copper(II), zinc(II) and cadmium(II) with the anion of the Schiff base 2-tosylamino (2'-pyridyl) aniline (HL) have been prepared by using an electrochemical procedure. These compounds were characterized by elemental analysis, IR, UV and NMR spectroscopy, and in the case of [CoL2] by X-ray diffraction methods. In this compound the cobalt(II) atom is in a distorted tetrahedral environment, each Schiff base anion acting as a bidentate ligand with the pyridine nitrogen atom uncoordinated. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(97)00376-8

文献信息

• Electrochemical synthesis of metal (II) complexes of Schiff base 2-tosylamino (2′-pyridyl)aniline: the crystal structure of bis-[2-tosylamino(2′-pyridyl)anilinato]cobalt(II)
  作者：Jose A. Garcia-Vazquez、Jaime Romero、Maria L. Duran、Antonio Sousa、Alexander D. Garnovskii、Anatolii S. Burlov、Dimitrii A. Garnovskii

  DOI：10.1016/s0277-5387(97)00376-8

  日期：1998.1

  Complexes of cobalt(II): nickel(II), copper(II), zinc(II) and cadmium(II) with the anion of the Schiff base 2-tosylamino (2'-pyridyl) aniline (HL) have been prepared by using an electrochemical procedure. These compounds were characterized by elemental analysis, IR, UV and NMR spectroscopy, and in the case of [CoL2] by X-ray diffraction methods. In this compound the cobalt(II) atom is in a distorted tetrahedral environment, each Schiff base anion acting as a bidentate ligand with the pyridine nitrogen atom uncoordinated. (C) 1998 Elsevier Science Ltd. All rights reserved.