trichloromethanesulfinic acid | 7430-24-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 亚磺酸及其衍生物
• 英文名称: trichloromethanesulfinic acid
• 英文别名: trichloro-methanesulfinic acid；Trichlor-methansulfinsaeure；Trichlormethansulfinsaeure；Trichlormethylsulfinsaeure；Trichloromethanesulfinicacid
• CAS: 7430-24-2
• 化学式: CHCl₃O₂S
• 分子量: 183.443
• InChiKey: OLRICEKEOLIEMY-UHFFFAOYSA-N

物化性质

• 沸点：
  313.0±42.0 °C(Predicted)
• 密度：
  2.126±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  7
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  56.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  trichloromethanesulfinic acid 在 氯 作用下， 生成 三氯甲基磺酰氯
  参考文献：
  名称：

  Kolbe, Justus Liebigs Annalen der Chemie, 1845, vol. 54, p. 183

  摘要：

  DOI：
• 作为产物：
  描述：

  三氯甲基磺酰氯 在 potassium sulfite 作用下， 生成 trichloromethanesulfinic acid
  参考文献：
  名称：

  Rathke, Justus Liebigs Annalen der Chemie, 1872, vol. 161, p. 161

  摘要：

  DOI：

文献信息

• Highly reactive sulfinates. The synthesis, solvolysis and rearrangement of benzyl trichloromethanesulfinates
  作者：Samuel Braverman、Ytzhak Duar

  DOI：10.1016/s0040-4020(01)88389-7

  日期：1990.1

  Benzyl trichloromethanesulfinates are easily obtained by oxidation of the corresponding sulfenates, in excellent yields. Examination of their reactivity revealed some unique features. In contrast to benzyl arenesulfinates which undergo solvolysis with complete S-O bond fission, these esters undergo solvolysis with exclusive C-O bond fission, and with a rate enhancement by a factor of 6 powers of ten

  苄基三氯甲烷亚磺酸盐很容易通过氧化相应的亚磺酸盐而获得，产率很高。检查它们的反应性显示出一些独特的特征。与通过完全SO键裂变进行溶剂分解的苄基亚芳基磺酸盐相反，这些酯通过独家CO键裂变进行溶剂分解，并且速率可提高10倍6的倍数，与甲苯磺酸甲苯磺酸酯相当。类似地，与苄基亚芳基磺酸盐不同，这些酯在极性非羟基溶剂中加热时，容易重排成亚砜。已在各种条件下对这些反应进行了动力学研究，并通过检查Hammett和Winstein相关性分析了溶剂分解对取代基和溶剂作用的敏感性。讨论了两种反应的机理。
• Anlagerung von Sulfinsäuren an aktivierte Alkene. 1. Mitt. über Sulfone als chemische Transportformen germicid wirkender Stoffe
  作者：P. Messinger

  DOI：10.1002/ardp.19733060612

  日期：——

  Durch Anlagerung von Sulfinsäuren 3 an aktivierte Alkene 4,6,8,10 und 12 entstehen die Sulfone 5,7,9,11 und 13.

  将亚磺酸 3 添加到活化的烯烃 4、6、8、10 和 12 中会生成砜 5、7、9、11 和 13。
• Bussas, Reinhard; Kresze, Guenter, Liebigs Annalen der Chemie, 1982, # 3, p. 545 - 563
  作者：Bussas, Reinhard、Kresze, Guenter

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: S: SVol.4a/b, 1.3.10.1.4, page 260 - 262
  作者：

  DOI：——

  日期：——
• A Theory of the Firm with Non-binding Employment Contracts
  作者：Asher Wolinsky

  DOI：10.1111/1468-0262.00140

  日期：2000.7

  This paper examines an employment relation in which individual workers enjoy some bargaining power-vis-g-vis the firm although they are not unionized. The main elements of the situations studied here are that the employment contracts are non-binding across periods of production and that the firm has opportunities to replace workers.The paper analyzes a dynamic model in which the processes of contracting and recontracting between the firm and its workers are intertwined with the dynamic evolution of the firm's workforce. The analysis of the model is somewhat complicated because the employment level is a nondegenerate state variable that evolves over time and is affected by past decisions.The main analytical results characterize certain important equilibria: the profit maximizing and stationary equilibria. The unique stationary equilibrium is markedly inefficient: it exhibits inefficient over-employment and the steady state wages coincide with the workers' reservation wage. It confirms earlier results derived by Stole and Zwiebel (1996a, b) in the context of a static model and shows that they are very robust even when the firm has nearly frictionless hiring opportunities. In contrast, in the profit maximizing equilibrium the outcome is nearly efficient and the wage exhibits a mark-up over the reservation wage.