(Zn(S2P(OC6H4Me-p)2)2) | 74895-05-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (Zn(S2P(OC6H4Me-p)2)2)
• 英文别名: ZINC;bis(4-methylphenoxy)-sulfanylidene-sulfido-lambda5-phosphane；zinc;bis(4-methylphenoxy)-sulfanylidene-sulfido-λ5-phosphane
• CAS: 74895-05-9
• 化学式: C₂₈H₂₈O₄P₂S₄Zn
• 分子量: 684.129
• InChiKey: GAOPNGJOJKSJQX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  9.06
• 重原子数：
  39
• 可旋转键数：
  8
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  103
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  (Zn(S2P(OC6H4Me-p)2)2) 、 (NMe4)(S2P(OC6H4Me-p)2) 以 异丙醇 为溶剂， 以40%的产率得到tetramethylammonium bis(OO'-di-p-tolyl dithiophosphato-S) (OO'-di-p-tolyl dithiophosphato-SS')zincate
  参考文献：
  名称：

  橡胶硫化的无机化学方面。第4部分。锌的二烷基和二芳基-二硫代磷酸酯和-二硫代次膦酸酯配合物：磷31核磁共振光谱研究和[NMe 4 ] [Zn {S 2 P（OC 6 H 4 Me- p）2 } 3 ]的结构和[NEt 4 ] [Zn（S 2 PPh 2）3 ]

  摘要：

  通过[Zn（S ）的处理制备了配合物[NMe 4 ] [Zn {S 2 P（OC 6 H 4 Me- p）2 } 3 ]和[NEt 4 ] [Zn（S 2 PPh 2）3 ]。2 PR 2）2 ]与[NR' 4 ] [S 2 PR 2 ]（R = OC 6 H ^ 4 ME- p或pH，R'= Me或Et）。的制备[ZNL 2 {S 2 P（OPR我）2 }] -并且，[Zn（S 2 PR 2）2（S 2 CNME 2）] -（R = OC 6 H ^ 4 ME- p或PH）还描述。从反应[锌{S 2 P（OR）2 } 2 ]（R = PR我或C 6 H ^ 4 ME- p）用H 2 ö 2或卜吨O（OH），锌磷酸盐和硫酸锌4已得到[Zn {S 2 P（OPh）2 } 2 ]和[Zn {S 2P（OPh）2 } 3 ] –与ROH（R ​​= Et或Pr i）在溶液中反应，得到其他产物[Zn

  DOI：

  10.1039/dt9830000627
• 作为产物：
  描述：

  zinc(II) sulfate heptahydrate 、 O,O-di-p-tolyl hydrogen phosphorodithioate 以 水 、 甲苯 为溶剂， 以80%的产率得到(Zn(S2P(OC6H4Me-p)2)2)
  参考文献：
  名称：

  橡胶硫化的无机化学方面。第4部分。锌的二烷基和二芳基-二硫代磷酸酯和-二硫代次膦酸酯配合物：磷31核磁共振光谱研究和[NMe 4 ] [Zn {S 2 P（OC 6 H 4 Me- p）2 } 3 ]的结构和[NEt 4 ] [Zn（S 2 PPh 2）3 ]

  摘要：

  通过[Zn（S ）的处理制备了配合物[NMe 4 ] [Zn {S 2 P（OC 6 H 4 Me- p）2 } 3 ]和[NEt 4 ] [Zn（S 2 PPh 2）3 ]。2 PR 2）2 ]与[NR' 4 ] [S 2 PR 2 ]（R = OC 6 H ^ 4 ME- p或pH，R'= Me或Et）。的制备[ZNL 2 {S 2 P（OPR我）2 }] -并且，[Zn（S 2 PR 2）2（S 2 CNME 2）] -（R = OC 6 H ^ 4 ME- p或PH）还描述。从反应[锌{S 2 P（OR）2 } 2 ]（R = PR我或C 6 H ^ 4 ME- p）用H 2 ö 2或卜吨O（OH），锌磷酸盐和硫酸锌4已得到[Zn {S 2 P（OPh）2 } 2 ]和[Zn {S 2P（OPh）2 } 3 ] –与ROH（R ​​= Et或Pr i）在溶液中反应，得到其他产物[Zn

  DOI：

  10.1039/dt9830000627

文献信息

• Compositions for use in golf balls
  申请人：Bulpett A. David

  公开号：US20050245652A1

  公开（公告）日：2005-11-03

  A golf ball comprises a core, an outer cover layer, and, optionally, an intermediate layer disposed between the core and the outer cover layer. The outer cover layer may comprise a polyurethane or polyurea composition. At least one portion of the golf ball comprises a composition that enhances physical properties and/or performance characteristics (e.g., coefficient of restitution) of the golf ball. Preferably, the coefficient of restitution of the core is 0.8 or greater.

  高尔夫球由内核、外覆盖层和可选的中间层组成，外覆盖层可以包括聚氨酯或聚脲组成。高尔夫球的至少一部分包含一种增强物理特性和/或性能特征（例如反弹系数）的组合物。最好，内核的反弹系数为0.8或更高。
• COMPOSITIONS FOR USE IN GOLF BALLS
  申请人：Sullivan Michael J.

  公开号：US20080227567A1

  公开（公告）日：2008-09-18

  A golf ball comprises a core, an outer cover layer, and, optionally, an intermediate layer disposed between the core and the outer cover layer. The outer cover layer may comprise a polyurethane or polyurea composition. At least one portion of the golf ball comprises a composition that enhances physical properties and/or performance characteristics (e.g., coefficient of restitution) of the golf ball. Preferably, the coefficient of restitution of the core is 0.8 or greater.

  一个高尔夫球包括一个核心、一个外覆盖层，以及可选的介质层，介质层位于核心和外覆盖层之间。外覆盖层可能包括聚氨酯或聚脲组成。高尔夫球的至少一部分包含一种增强高尔夫球物理性能和/或性能特征（例如反弹系数）的组成。最好，核心的反弹系数为0.8或更高。
• Compositions for Use in Golf Balls
  申请人：Bulpett David A.

  公开号：US20080176678A1

  公开（公告）日：2008-07-24

  A golf ball comprising a core and at least one layer disposed about the core, wherein at least one of the core or the layer is formed from a composition comprising a base polymer, a crosslink initiator, and an additive comprising an aromatic iodonium compound or an aromatic iodonium salt.

  一颗高尔夫球包括一个核心和至少一层沿核心排列的材料，其中核心或层中的至少一个是由包含基础聚合物、交联引发剂和添加剂的组合物形成的，该添加剂包括芳香碘化物或芳香碘化盐。
• LUBRICATING OIL COMPOSITION
  申请人：Nippon Oil Corporation

  公开号：EP1516910A1

  公开（公告）日：2005-03-23

  Disclosed are lubricating oil compositions excellent in friction reducing effect and long drain properties and particularly suitable for internal combustion engines, which comprise a lubricating base oil, a specific phosphorus compound in an amount of 0.005 to 0.5 percent by mass in terms of phosphorus based on the total mass of the composition, and at least one additive selected from the group consisting of (C) metallic detergents, (D) ashless dispersants, and (E) anti-oxidants, and further contains (F) a sulfur-containing organic molybdenum complex and (G) an ashless friction modifier and which satisfy prescribed requirements and have a sulfated ash content not exceeding a specified level.

  所公开的润滑油组合物具有优异的减摩效果和长换油期特性，尤其适用于内燃机，它包括润滑基础油、特定磷化合物（以组合物总质量计，磷的含量为 0.005 至 0.5% （以重量计）的特定磷化合物，以及至少一种添加剂，这些添加剂选自 (C) 金属清净剂、(D) 无灰分散剂和 (E) 抗氧化剂组成的组，还包含 (F) 含硫有机钼络合物和 (G) 无灰摩擦改进剂，这些添加剂满足规定要求，硫酸盐灰分含量不超过规定水平。
• ROLLING DEVICE EMPLOYING LUBRICATING GREASE COMPOSITION AND ELECTRIC POWER STEERING APPARATUS EMPLOYING THE ROLLING DEVICE
  申请人：JTEKT Corporation

  公开号：EP1889897A1

  公开（公告）日：2008-02-20

  A rolling device is provided which employs a lubricating grease composition which considerably diminishes irregular friction fluctuations occurring on rolling/sliding friction surfaces, shows stable low-torque characteristics in a wide temperature range, can retain a sufficient oil film even at high temperatures, has a long life, and contains a novel thickener. Also provided is an electric power steering apparatus employing the rolling device. The rolling device is characterized by employing a lubricating grease composition comprising: a thickener which is a mixed thickener comprising a mixture of (a) one or more diurea compounds which are one or more aliphatic diurea compounds having an average molecular weight of 500-750 in which 10-70% by mole of the linear hydrocarbon groups are unsaturated components, the aliphatic diurea compounds having been produced using as a raw material one or more primary amines having a total amine value in the range of 200-400, (b) at least one fatty acid metal salt, and (c) at least one amide compound selected from the group consisting of aliphatic amides and aliphatic bisamides represented by formulae (I) and (II):         R1CONH2     (I)         R1CONHR2NHCOR1     (II) (wherein R1 represents a saturated or unsaturated alkyl group having 15-17 carbon atoms and R2 represents a methylene group or an ethylene group), the proportions of (a) and of (b) and (c) satisfying the relationship: a/b+c=0.2-10 provided that (1) the proportion of ingredient (a) is 1-10, (2) the proportion of ingredient (b) is 0.5-2.5, and (3) the proportion of ingredient (c) is 0.5-2.5, the amount of the thickener being 2-30% by weight, based on the whole composition; (d) a base oil which is a lube base oil having a pour point of -25°C or lower and comprising a synthetic hydrocarbon oil as the main component; and (e) an additive which is a mixture comprising an organomolybdenum complex, an organozinc compound of a dithiocarbamic acid, and an organozinc compound of dithiophosphoric acid, the amount of the additive being 1-7% by weight, based on the whole composition.

  本发明提供了一种滚动装置，该装置采用了一种润滑脂组合物，可显著减少滚动/滑动摩擦面上出现的不规则摩擦波动，在宽温度范围内显示出稳定的低扭矩特性，即使在高温下也能保持足够的油膜，具有较长的使用寿命，并且含有一种新型增稠剂。此外，还提供了一种采用该滚动装置的电动助力转向装置。 该滚动装置的特点是采用了一种润滑脂组合物，其中包括一种稠化剂，它是一种混合稠化剂，包括以下物质的混合物 (a) 一种或多种二脲化合物，它是一种或多种脂肪族二脲化合物，平均分子量为 500-750，其中 10-70%（摩尔）的线性烃基为不饱和组分、(b) 至少一种脂肪酸金属盐，以及 (c) 至少一种酰胺化合物，选自由式 (I) 和 (II) 所代表的脂肪族酰胺和脂肪族双酰胺组成的组： R1CONH2 (I) R1CONHR2NHCOR1 (II) (其中 R1 代表具有 15-17 个碳原子的饱和或不饱和烷基，R2 代表亚甲基或亚乙 烯基），(a)和(b)及(c)的比例满足以下关系：a/b+c=0.2-10 条件是 (1) 成分（a）的比例为 1-10、 (2) 成分（b）的比例为 0.5-2.5，以及 (3) 成分(c)的比例为 0.5-2.5，增稠剂的用量为整个组合物重量的 2-30%； (d) 基础油，即倾点为-25°C 或更低的润滑油基础油，其主要成分为合成烃油； (e) 添加剂，即由有机钼络合物、二硫代氨基甲酸的有机锌化合物和二硫代磷酸的 有机锌化合物组成的混合物，添加剂的用量为整个组合物重量的 1-7%。