dibanzo-1,5,9,13-tetraaza-2,10-dioxo-4,12-diphenylcyclohexadecane | 1075689-94-9

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 大环内酰胺类
• 英文名称: dibanzo-1,5,9,13-tetraaza-2,10-dioxo-4,12-diphenylcyclohexadecane
• 英文别名: dibenzo-1,5,9,13-tetraaza-2,10-dioxo-4,12-diphenylcyclohexadecane；Bzo2[16]aneN4；5,15-Diphenyl-2,6,12,16-tetrazatricyclo[15.3.1.17,11]docosa-1(20),7(22),8,10,17(21),18-hexaene-3,13-dione；5,15-diphenyl-2,6,12,16-tetrazatricyclo[15.3.1.17,11]docosa-1(20),7(22),8,10,17(21),18-hexaene-3,13-dione
• CAS: 1075689-94-9
• 化学式: C₃₀H₂₈N₄O₂
• 分子量: 476.578
• InChiKey: PMGIRCAFLXTHLR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  36
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  82.3
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  硫酸氧钒水合物 、 dibanzo-1,5,9,13-tetraaza-2,10-dioxo-4,12-diphenylcyclohexadecane 在 (C₂H₅)3N 作用下， 以 乙醇 为溶剂， 生成 [VO(dibenzo-1,5,9,13-tetraaza-2,10-dioxo-4,12-diphenylcyclohexadecane)]SO₄
  参考文献：
  名称：

  Synthesis, characterization and liquid-phase hydroxylation of phenol with hydrogen peroxide over host (nanopores of zeolite-Y)/guest (oxovanadium(IV) complexes of tetraaza macrocyclic ligands) nanocatalyst

  摘要：

  Oxovanadium(IV) tetraaza complexes of [14]aneN(4)n: 1,5,8,12-tetraaza-2,9-dioxo-4,11-diphenylcyclotetradecane; [16]aneN(4): 1,5,9,13-tetraaza-2,10-dioxo-4,12-diphenylcyclohexadecane; Bzo(2)[14]aneN(4): dibenzo-1,5,8,12-tetraaza-2,9-dioxo-4,11-diphenylcyclotetradecane and Bzo(2)[16] aneN(4): dibenzo-1,5,9,13-tetraaza-2,10-dioxo-4,12-diphenylcyclohexadecane have been encapsulated in the nanopores of zeolite-Y by a two-step process in the liquid phase: (i) adsorption of [bis(diamine)VO(IV)] (diamine = 1,2-diaminoethane, 1,3-diaminopropane, 1,2-diaminobenzene, 1,3-diaminobenzene); [VO(N-N)(2)](2+)-NaY; in the nanopores of the zeolite-Y and (ii) in situ condensation of the oxovanadium(IV) precursor complex with ethylcinnamate. The new host-guest nanocatalysts were characterized by several techniques: chemical analysis and spectroscopic methods (FT-infrared (FT-IR), ultraviolet-visible (UV-Vis), X-ray diffraction (XRD), nitrogen adsorption and diffuse reflectance spectra (DRS)) technique. The analytical data indicated a composition corresponding to the mononuclear complex of tetraaza ligand. The characterization data showed the absence of extraneous complexes, retention of zeolite crystalline structure and encapsulation in the nanopores. Liquid-phase selective hydroxylation of phenol with H2O2 to a mixture of catechol and hydroquinone in CH3CN have been reported using oxovanadium(IV) tetraaza complexes encapsulated in zeolite-Y as catalysts. All these catalysts are more selective toward catechol formation. (c) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.09.043
• 作为产物：
  描述：

  肉桂酸乙酯 、 间苯二胺 在 盐酸 作用下， 以 乙醇 为溶剂， 生成 dibanzo-1,5,9,13-tetraaza-2,10-dioxo-4,12-diphenylcyclohexadecane
  参考文献：
  名称：

  乙苯在主体（沸石-Y）/客体（四氮杂大环配体的铜（II）配合物）纳米复合材料上的合成、表征和催化氧化

  摘要：

  14 元和 16 元四氮杂大环配体的 Cu(II) 配合物已通过液相中的两步法封装在沸石-Y 的纳米孔中：（1）吸附 [双（二胺）铜（II）] （二胺 = 1,2-二氨基乙烷、1,3-二氨基丙烷、1,2-二氨基苯和 1,3-二氨基苯）；[Cu(N–N)2]2+–NaY；在沸石-Y 的纳米孔中和 (2) 铜 (II) 前体络合物与肉桂酸乙酯的原位缩合。新的主客体纳米复合材料通过化学分析和光谱方法进行了表征。使用叔丁基过氧化氢作为氧化剂，“纯”和包封的复合物在 333 K 下对乙苯的氧化表现出良好的催化活性。

  DOI：

  10.1080/00958972.2010.510557

文献信息

• Synthesis, characterization of cobalt(II) complex nanoparticles encapsulated within nanoreactors of zeolite-Y and their catalytic activities
  作者：Masoud Salavati-Niasari

  DOI：10.1016/j.molcata.2009.05.018

  日期：2009.9

  Cobalt(II) complex nanoparticles of [14]aneN(4): 1,5,8,12-tetraaza-2,9-dioxo-4,11-diphenylcyclotetradecane [16]aneN(4): 1,5,9,13-tetraaza-2,10-dioxo-4,12-diphenylcyclohexadecane; Bzo(2)[14]aneN(4): dibenzo-1,5,8,12-tetraaza-2,9-dioxo-4,11-diphenylcyclotetradecane and Bzo(2)[16]aneN(4): dibenzo-1,5,9,13-tetraaza-2,10-dioxo-4,12-diphenylcyclohexadecane have been encapsulated in the nanopores of zeolite-Y by a two-step process in the liquid phase: (i) adsorption of [bis(diamine)cobalt(II)] (diamine = 1,2-diaminoethane, 1,3-diaminopropane, 1,2-diaminobenzene, 1,3-diaminobenzene): [Co(N-N)(2)](2+)-NaY; in the nanopores of the zeolite-Y. and (ii) in situ condensation of the cobalt(II) precursor complex with ethylcinnamate. The new complex nanoparticles entrapped in the nanoreactor of zeolite-Y were characterized by several techniques: BET, chemical analysis and spectroscopic methods (FT-IR, UV-vis, XRD, and DRS). These complexes (neat and encapsulated) were used for epoxidation of styrene with O-2 as oxidant in different solvents. Electronic spectra of the reaction mixture indicated that the oxidation proceeds through a free radical mechanism. (C) 2009 Elsevier B.V. All rights reserved.
• Synthesis, characterization and catalytic oxidation of cyclohexene with molecular oxygen with host (nanopores of zeolite-Y)/guest (Ni(II) complexes of 14- and 16-membered tetraaza dioxo diphenyl macrocyclic ligands) nanocomposite materials
  作者：Masoud Salavati-Niasari

  DOI：10.1016/j.poly.2008.06.033

  日期：2008.9

  Ni(II) complexes of [14]aneN(4): 1,5,8,12-tetraaza-2,9-dioxo-4,11-diphenylcyclotetradecane; [16]aneN(4): 1,5,9,13-tetraaza-2,10-dioxo-4,12-diphenylcyclohexadecane; Bzo(2)[14]aneN(4): dibenzo-1,5,8,12-tetraaza-2,9-dioxo-4,11-diphenylcyclotetradecane and Bzo(2)[16]aneN(4): dibenzo-1,5,9,13-tetraaza-2,10-dioxo-4,12-diphenylcyclohexadecane have been encapsulated in the nanopores of zeolite-Y by a two-step process in the liquid phase: (i) adsorption of [bis(diamine)nickel(II)] (diamine = 1,2-diaminoethane, 1,3-diaminopropane, 1,2-diaminobenzene, 1,3-diaminobenzene); [Ni(N-N)(2)](2+)-NaY; in the nanopores of the zeolite-Y, and (ii) in situ condensation of the nickel(II) precursor complex with ethylcinnamate. The new host-guest nanocomposite materials (HGNM) were characterized by several techniques: chemical analysis and spectroscopic methods (FT-IR, UV/Vis, XRD and DRS) and the BET technique. These complexes were used for oxidation of cyclohexene with molecular oxygen. (C) 2008 Elsevier Ltd. All rights reserved.