4-vinyloxymethyl-7-oxabicyclo[4.1.0]heptane | 131718-57-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环己烷
• 英文名称: 4-vinyloxymethyl-7-oxabicyclo[4.1.0]heptane
• 英文别名: 3-(Ethenoxymethyl)-7-oxabicyclo[4.1.0]heptane
• CAS: 131718-57-5
• 化学式: C₉H₁₄O₂
• 分子量: 154.209
• InChiKey: ZHQCNWAUPONEAM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  21.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1,2-环氧-4-羟甲基环己烷 、 乙酸乙烯酯 在 bis(1,5-cyclooctadiene)diiridium(I) dichloride sodium carbonate 作用下， 以 甲苯 为溶剂， 以95%的产率得到4-vinyloxymethyl-7-oxabicyclo[4.1.0]heptane
  参考文献：
  名称：

  Vinyl ether compounds and polymerizable compositions

  摘要：

  揭示了一种含氧杂环乙烯醚化合物，包括一个或多个芳香或非芳香碳环和/或两个或更多个乙烯醚结构，例如Formula公式的化合物： 其中环Z1为非芳香碳环；Ra为Formula公式的乙烯基： 其中R1、R2和R3中的每一个是氢或C1-C4烷基；Wa为单键或具有(m+1)价的有机基团；X1为例如烃基；"m"和"q"各自为1或2；"p"为0至5。还揭示了一种含脂环氧基的乙烯醚化合物，其Formula为： 其中环Z2为非芳香碳环；Rb为Formula公式的乙烯基： 其中R4、R5和R6中的每一个为氢或C1-C4烷基；Wb为单键或具有(r+1)价的有机基团；Rc和Rd为氢或烷基；"r"和"s"为1或2。

  公开号：

  EP1972622A3

文献信息

• Fluorine-containing copolymer, composition for forming a film, anti-reflection film, and image display device
  申请人：——

  公开号：US20030120008A1

  公开（公告）日：2003-06-26

  A fluorine-containing copolymer of the following formula. A film-forming composition containing the copolymer. An anti-reflection film having a low-refractive-index layer containing the copolymer. An anti-reflection film having the above anti-reflection film on a transparent support. An image display device having the anti-reflection film. formula 1 In the formula, Rf 1 represents a specific fluorine-containing alkyl group; Rf 2 represents a specific perfluoroalkyl group; A represents a constituent having at least one reactive group capable of contributing to a cross-linking reaction; B represents an arbitrary constituent; a to d each represent a mole fraction (%) of each constituent, which satisfy the following conditions: 55≦ a+b ≦95, 5≦ a ≦90, 5≦ b ≦70, 5≦ c ≦45, 0≦ d ≦40

  以下是中文翻译： 一种含氟共聚物，其化学式如下。一种含有该共聚物的成膜组合物。一种具有低折射率层的抗反射膜，其中包含该共聚物。一种在透明支撑体上具有上述抗反射膜的抗反射膜。一种具有抗反射膜的图像显示装置。其中，化学式中，Rf1表示特定的含氟烷基；Rf2表示特定的全氟烷基；A表示至少具有一个反应性基团能够参与交联反应的组分；B表示任意组分；a到d分别表示每个组分的摩尔分数（%），满足以下条件：55≤a+b≤95，5≤a≤90，5≤b≤70，5≤c≤45，0≤d≤40。
• Epoxycyclohexane vinyl ether compounds and their use in polymerizable compositions
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP2233475A1

  公开（公告）日：2010-09-29

  Disclosed is an alicyclic epoxy-containing vinyl ether compound represented by following Formula (3c) or (3d): wherein Rb represents a substituted or unsubstituted vinyl group represented by following Formula (4): wherein each of R4, R5 and R6 independently represents a hydrogen atom or an alkyl group containing one to four carbon atoms; These vinyl ether compunds are useful as polymerizable compounds that will polymerize or cure by the application of light and/or heat.

  本发明公开了由下式（3c）或（3d）表示的含脂环族环氧乙烯基醚化合物： 其中 Rb 代表下式（4）所代表的取代或未取代的乙烯基： 其中 R4、R5 和 R6 各自独立地代表氢原子或含有一至四个碳原子的烷基； 这些乙烯基醚化合物可用作可聚合化合物，在光和/或热的作用下聚合或固化。
• PRESSURE-SENSITIVE ADHESIVE COMPOSITION, PRESSURE-SENSITIVE ADHESIVE AND OPTICAL FILM
  申请人：Nippon Carbide Industries Co., Inc.

  公开号：EP2330170A1

  公开（公告）日：2011-06-08

  A pressure-sensitive adhesive composition which is excellent in durability under high temperature and humidity conditions and can thus inhibit bright defect even when applied to a large-sized optical film; a pressure-sensitive adhesive; and an optical film. A pressure-sensitive adhesive composition comprising an acrylic copolymer (A) bearing a reactive functional group, an acrylic copolymer (B) and an isocyanate compound (C), wherein the quantity of the isocyanate compound (C) is 5 to 30 parts by weight per 100 parts by weight of a mixture of the acrylic copolymer (A) and the acrylic copolymer (B) and the elongation at break and 200% modulus as determined at 25 degrees C by the tensile test are 300 to 1000% and 0.2 to 3 N/mm2 respectively.

  一种压敏粘合剂组合物，它在高温高湿条件下具有优异的耐久性，因此即使涂在大尺寸光学薄膜上也能抑制亮缺陷；一种压敏粘合剂；以及一种光学薄膜。一种压敏型粘合剂组合物，由带活性官能团的丙烯酸共聚物（A）、丙烯酸共聚物（B）和异氰酸酯化合物（C）组成，其中异氰酸酯化合物（C）的数量为每 100 份丙烯酸共聚物（A）和丙烯酸共聚物（B）混合物的重量比为 5 至 30 份，在 25 摄氏度下通过拉伸试验测定的断裂伸长率和 200% 模量分别为 300 至 1000% 和 0.2 至 3 N/mm2。
• Oxetane-containing vinyl ether compounds and polymerizable compositions
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP2441761A1

  公开（公告）日：2012-04-18

  Disclosed is an oxetane-containing vinyl ether compound comprising: (a) at least one oxetane ring; and (b) two or more vinyl ether structures, per molecule, wherein the oxetane-containing vinyl ether compound is represented by the following Formula (1b): wherein Ra respresents a substituted or unsubstitued vinyl group represented by the following Formula (2):

  公开了一种含氧杂环丁基醚化合物，该化合物包括 (a) 至少一个氧杂环；和 (b) 两个或多个乙烯基醚结构、 每个分子 其中含氧乙烷的乙烯基醚化合物由下式（1b）表示： 其中 Ra 代表由下式（2）表示的取代或未取代的乙烯基：
• COATING COMPOSITION FOR SOLAR-HEAT-COLLECTING REFLECTIVE PLATE, SOLAR-HEAT-COLLECTING REFLECTIVE PLATE, AND PROCESS FOR PRODUCING SAME
  申请人：Asahi Glass Company, Limited

  公开号：EP2544031A1

  公开（公告）日：2013-01-09

  The present invention is to provide a coating composition for surface coating capable of forming a cured coating film layer that protects a reflective substrate of a solar heat-collecting reflective plate and that is excellent in the impact resistance and the weather resistance such as the heat resistance and the water resistance, as well as a solar heat-collecting reflective plate having such a cured coating film layer, and a process for its production. A coating composition for surface coating to be used for the production of a solar heat-collecting reflective plate having a reflective substrate made of metal, which comprises a fluoropolymer (A) having units (A1) derived from a fluoroolefin and units (A2) having a crosslinkable group. Further, a solar heat-collecting reflective plate having a cured coating film layer formed from the coating composition for surface coating, and a process for its production.

  本发明旨在提供一种能够形成固化涂膜层的表面涂层用涂料组合物，该固化涂膜层能够保护太阳能集热反射板的反射基板，并且具有优异的抗冲击性和耐候性（例如耐热性和耐水性），以及具有该固化涂膜层的太阳能集热反射板及其生产工艺。一种表面涂层用涂料组合物，用于生产具有金属制反射基板的太阳能集热反射板，该组合物由氟聚合物（A）组成，氟聚合物（A）具有从氟烯烃衍生的单元（A1）和具有可交联基团的单元（A2）。此外，还包括一种太阳能集热反射板，该板具有由该涂层组合物形成的固化涂膜层，用于表面涂层，还包括其生产工艺。