cadmium chloride * 2 pyridine | 14024-90-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: cadmium chloride * 2 pyridine
• 英文别名: Dichlorocadmium;pyridine
• CAS: 14024-90-9；36812-30-3
• 化学式: C₁₀H₁₀CdCl₂N₂
• 分子量: 341.519
• InChiKey: DSBBVYOYUKPDOH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  3.54
• 重原子数：
  15
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  cadmium chloride * 2 pyridine 在 吡啶 作用下， 生成 cadmium chloride * 6 pyridine
  参考文献：
  名称：

  Mason, R. B.; Mathews, J. H., Journal of Physical Chemistry, 1925, vol. 29, p. 1178 - 1183

  摘要：

  DOI：
• 作为产物：
  描述：

  cadmium chloride * 6 pyridine 生成 cadmium chloride * 2 pyridine
  参考文献：
  名称：

  Mason, R. B.; Mathews, J. H., Journal of Physical Chemistry, 1925, vol. 29, p. 1178 - 1183

  摘要：

  DOI：

文献信息

• Strecker, W.; Schwinn, E., Journal fur praktische Chemie (Leipzig 1954), 1939, vol. 152, p. 205 - 218
  作者：Strecker, W.、Schwinn, E.

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cd: SVol., 18.1, page 756 - 764
  作者：

  DOI：——

  日期：——
• Spacu, G.; Caton, L., Buletinul Societatii de Stiinte din Cluj, 1924, vol. 2, p. 306 - 331
  作者：Spacu, G.、Caton, L.

  DOI：——

  日期：——
• Dubsky, J. V.; Dostal, V., 1934, # 196, p. 17 - 23
  作者：Dubsky, J. V.、Dostal, V.

  DOI：——

  日期：——
• The effect of pressure on the Raman spectra of solids. VII. The internal Raman bands in solid and coordinated pyridine
  作者：A. M. Heyns、M. W. Venter

  DOI：10.1063/1.459389

  日期：1990.12

  The pressure dependences of the internal Raman-active modes of solid pyridine and pyridine-d5 in both the crystalline and glassy modifications as well as of the complexes Zn(py)2Cl2, Ni(py)2Cl2, and Ni(py)4Cl2 are reported. When pyridine is frozen by the application of pressure, some ring modes as well as those involving the hydrogen atoms reflect this transformation. Upon the coordination of pyridine to metal ions, the ring vibrations show appreciable blue shifts. The pressure dependences of ν1, the C–C stretching mode, and ν12, the in-plane ring bending mode of the pyridine rings, are discussed in detail. The unusually high d5–h5 isotopic ratio of ν12 and its contrasting pressure dependences in the liquid and condensed phases of pyridine-d5 are explained. The association of pyridine molecules in the condensed phase does not occur through hydrogen bonds and the C–H stretching modes, in particular, show that repulsive intermolecular forces become very significant at higher pressures. The ratio of the intensities Iν12/Iν1 varies linearly with the strength of the M–N bonds in a series of pyridine complexes and a correlation also exists between Iν12/Iν1 and ∂ν12/∂p. The vibrations ν1 and ν2 are coupled through Fermi resonance in pyridine and its complexes and the pressure dependence of the Fermi resonance constant W is calculated for Zn(py)2Cl2. The C–H stretching modes reflect the presence of more than one distinct pyridine group in the lattice and are of much lower intensity than in complexes where only one distinct pyridine group is found.