4-carboxy methoxy phenyl acetic acid | 52299-08-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-carboxy methoxy phenyl acetic acid
• 英文别名: 4-carboxymethoxyphenylacetic acid；4-caroxymethoxyphenylacetic acid；(4-carboxymethoxy-phenyl)-acetic acid；(4-Carboxymethoxy-phenyl)-essigsaeure；2-[4-(Carboxymethyl)phenoxy]acetic acid；2-[4-(carboxymethoxy)phenyl]acetic acid
• CAS: 52299-08-8
• 化学式: C₁₀H₁₀O₅
• mdl: MFCD10595675
• 分子量: 210.186
• InChiKey: YWUHCLKKNFSBGK-UHFFFAOYSA-N

物化性质

• 熔点：
  180.5-181.5 °C
• 沸点：
  429.9±25.0 °C(Predicted)
• 密度：
  1.382±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  83.8
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  cadmium(II) nitrate tetrhydrate 、 4-carboxy methoxy phenyl acetic acid 在 NEt₃ 作用下， 以 水 为溶剂， 以67%的产率得到[Cd(II)(4-carboxymethoxyphenylacetate)]n
  参考文献：
  名称：

  (4-羧基甲氧基苯基)-乙酸酯衍生的三种镉配位聚合物的合成、结构和发光性能

  摘要：

  摘要 三种新型镉(II)配位聚合物{[Cd(bipy)(cpa)(H 2 O)]·2H 2 O} n ( 1 ), {[Cd(phen)(cpa)]·3H 2 O} n ( 2 ) 和 [Cd(cpa)] n ( 3 ) (bipy = 2,2'-联吡啶，phen = 1,10-菲咯啉，H 2 cpa = (4-羧甲氧基-苯基)-乙酸)表征。cpa 配体表现出多种配位模式，并在其结构的构建中发挥重要作用。1、2、3的结构由一维链、无限分子阶梯和(4,4)-连接(每个Cd(II)连接四个cpa，每个cpa连接四个Cd(II))三维组成网络，分别。图1、2和3分别揭示了室温下固态下在414、420和458nm处的蓝色发射最大值。

  DOI：

  10.1016/j.molstruc.2011.05.038
• 作为产物：
  描述：

  阿替洛尔 在 sodium hydroxide 、 potassium permanganate 作用下， 反应 4.0h， 生成 4-carboxy methoxy phenyl acetic acid
  参考文献：
  名称：

  Hiremath; Kulkarni; Nandibewoor, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2005, vol. 44, # 2, p. 245 - 250

  摘要：

  DOI：

文献信息

• Polyamides with improved gas barrier properties
  申请人：EASTMAN KODAK COMPANY

  公开号：EP0406127A1

  公开（公告）日：1991-01-02

  Polyamide resins useful for forming containers having improved resistance to gas permeability comprising the reaction product of (A) a dicarboxylic acid corresponding to the structure wherein X is hydrogen or unsubstituted alkyl containing 1-5 carbons and n is an integer in the range of 4 to 10, and (B) a diamine containing 5 to 36 carbon atoms.

  聚酰胺树脂可用于制造抗气体渗透性更强的容器，其反应产物包括以下物质 (A) 符合以下结构的二羧酸 其中 X 为氢或含 1-5 个碳原子的未取代烷基，n 为 4-10 之间的整数，以及 (B) 含 5 至 36 个碳原子的二胺。
• Tyler; Whittaker, Journal of Applied Chemistry, 1959, vol. 9, p. 594,595-599
  作者：Tyler、Whittaker

  DOI：——

  日期：——
• Mulla, R. M.; Kulkarni, R. M.; Nandibewoor, S. T., Journal of Chemical Research, Miniprint, 2003, # 6, p. 601 - 620
  作者：Mulla, R. M.、Kulkarni, R. M.、Nandibewoor, S. T.

  DOI：——

  日期：——
• Spectral and mechanistic investigations of ruthenium(III) catalyzed oxidation of atenolol by diperiodatocuprate(III) in aqueous alkaline medium
  作者：R. K. Patil、S. T. Nandibewoor、S. A. Chimatadar

  DOI：10.1134/s0036024412030247

  日期：2012.3

  The kinetics of ruthenium(III) catalyzed oxidation of atenolol by diperiodatocuprate(III) in aqueous alkaline medium at a constant ionic strength of I = 0.10 M has been studied spectrophotometrically at 27A degrees C. The reaction between diperiodatocuprate(III) and atenolol in alkaline medium in presence of ruthenium(III) exhibits 2: 1 stoichiometry (atenolol: diperiodatocuprate(III)). The main products were identified by spot test, IR, NMR, and LC-MS. The reaction is of first order in DPC concentrations and has less than unit order in both ATN and alkali concentrations. The order in ruthenium(III) was unity. Intervention of free radicals was observed in the reaction. Increase in periodate concentration decreases the rate. The oxidation reaction in alkaline medium has been shown to proceed via a ruthenium(III)-atenolol complex, which reacts with monoperiodatocuprate(III) in a rate determining step followed by other fast steps to give the products. Probable mechanism is proposed and discussed. The activation parameters with respect to the slow step of the mechanism and thermodynamic quantities were determined and discussed.
• Methine compound and silver halide photographic material containing the same
  申请人：Kobayashi Katsumi

  公开号：US20070004923A1

  公开（公告）日：2007-01-04

  Disclosed is a compound represented by the following formula (I): wherein Z 1 represents an atomic group necessary to form a 5- or 6-membered nitrogen-containing heterocyclic ring; Z 2 represents an atomic group necessary to form a 5- or 6-membered heterocyclic ring, Z 2 may further be substituted, or may be condensed with a hetero ring of a benzene ring; R 1 represents a hydrogen atom, a halogen atom, a mercapto group, an alkyl group, an alkenyl group, an aryl group, an alkylthio group, an alkenylthio group, or an arylthio group; L 1 and L 2 each represents a methine group; p 1 , represents 0 or 1; V 1 represents a substituent; and n represents 0, 1 or 2, and when n represents 2, a plurality of V 1 may be the same or different.