3,3'-(octamethylenedioxy)dibenzoyl chloride | 111244-81-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,3'-(octamethylenedioxy)dibenzoyl chloride
• 英文别名: 3,3'-[Octane-1,8-diylbis(oxy)]dibenzoyl chloride；3-[8-(3-carbonochloridoylphenoxy)octoxy]benzoyl chloride
• CAS: 111244-81-6
• 化学式: C₂₂H₂₄Cl₂O₄
• 分子量: 423.336
• InChiKey: HHICBWVNGVZGJF-UHFFFAOYSA-N

物化性质

• 沸点：
  546.5±35.0 °C(Predicted)
• 密度：
  1.208±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  28
• 可旋转键数：
  13
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  (6,8,15,17-tetramethyldibenzo[b,i][1,4,8,11]-tetraazacyclotetradecinato)nickel(II) 、 3,3'-(octamethylenedioxy)dibenzoyl chloride 在 三乙胺 作用下， 以 苯 为溶剂， 以87%的产率得到(6,8,15,17-tetramethyl-7,16-(3,3'-octamethylenedioxydibenzoylo)-dibenzo{b,i}{1,4,8,11}tetraazacyclotetradecinato)nickel(II)*1.5CH2Cl2
  参考文献：
  名称：

  Sakata, Kazunori; Hori, Takashi, Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1990, vol. 20, p. 263 - 274

  摘要：

  DOI：

文献信息

• Molecular design based on inclusion chemistry. Synthesis, characterization, and crystal structures of a new family of lacunar Schiff base complexes with promise as broad-range host molecules
  作者：Dorai. Ramprasad、Wang Kan. Lin、Kenneth A. Goldsby、Daryle H. Busch

  DOI：10.1021/ja00213a020

  日期：1988.3

  Preparation des coordinats par addition d'un groupe pontant qui recouvre la base de Schiff bis(acetylacetone)ethylenediamine. Structure cristalline de [Ni(Me 2 R 2 Me 2 maleu)]•2CHCl 3

  制备 de coordinats par added d'un groupe ponant qui recouvre la base de Schiff 双（乙酰丙酮）乙二胺。结构 cristalline de [Ni(Me 2 R 2 Me 2maleu)]•2CHCl 3
• Preparation and Characterization of Four Strapped Tetraaza[14]annulene Copper(II) Complexes
  作者：Kazunori Sakata、Yutaka Saitoh、Kohji Kawakami、Naoki Nakamura、Takashi Hori、Yo-ichi Nakano、Mamoru Hashimoto

  DOI：10.1080/00945719608004367

  日期：1996.8

  The reaction between a tetraaza[14]annulene copper(II) complex and four dibenzoic dichlorides led to the corresponding strapped copper(II) complexes in 21-53 % yield at 70 degrees C in dry toluene containing excess, triethylamine. The mass spectra reveal the molecular ion signals caused by the strapped products, respectively. The infrared spectra exhibit the intense stretching mode of C=O in the 1650-1660 cm(-1) range and the two strong stretching modes of C-O-C at about 1250 cm(-1) and 1050 cm(-1). All elemental analyses of the strapped copper(II) complexes agree with the anticipated constitution. These copper(II) complexes assume roughly square-planar coordination based on their d-->d* transition bands. The spin Hamiltonian parameters are consistent with those of the copper(II) complex which is not strapped which is square-planar with an unpaired electron in the dx(2)-y(2) orbital. These results support the structure of the strapped complexes.