1,4-bis(10-phenoxazinyl)benzene | 71041-22-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,4-bis(10-phenoxazinyl)benzene
• 英文别名: 10H,10'H-10,10'-p-phenylene-bis-phenoxazine；1,4-di-phenoxazin-10-yl-benzene；1,4-Di-phenoxazin-10-yl-benzol；10-(4-Phenoxazin-10-ylphenyl)phenoxazine
• CAS: 71041-22-0
• 化学式: C₃₀H₂₀N₂O₂
• 分子量: 440.501
• InChiKey: YHFBRFYWJJDRKP-UHFFFAOYSA-N

物化性质

• 沸点：
  601.7±45.0 °C(Predicted)
• 密度：
  1.313±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.6
• 重原子数：
  34
• 可旋转键数：
  2
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  24.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  邻碘溴苯 在 potassium phosphate 、 copper(l) iodide 、 iron(III)-acetylacetonate 、 DPEphos 、 palladium diacetate 、 sodium t-butanolate 作用下， 以 二甲基亚砜 、 甲苯 为溶剂， 反应 90.0h， 生成 1,4-bis(10-phenoxazinyl)benzene
  参考文献：
  名称：

  Pd催化的伯胺双N芳基化反应合成吩恶嗪和吩噻嗪

  摘要：

  开发了在芳基卤化物和伯胺之间形成高效且通用的钯催化串联C–N键的方法。该转化允许从容易获得的前体一锅合成苯恶嗪和吩噻嗪衍生物，该苯恶嗪和吩噻嗪衍生物具有广泛的取代模式。

  DOI：

  10.1039/c7ob01540b

文献信息

• ORGANIC LIGHT-EMITTING DIODE MATERIALS
  申请人：President and Fellows of Harvard College

  公开号：US20180212158A1

  公开（公告）日：2018-07-26

  Described herin are molecules for use in organic light emitting diodes. Example molecules comprise at least one acceptor moiety A, at least one donor moiety D, and optionally one or more bridge moieties B. Each moiety A is covalently attached to either the moiety B or the moeity D, each moiety D is covalently attached to either the moeity B or the moeity A, and each B is covalently attached to at least one moiety A and at least one moiety D. Values and preferred values of moieties A, D and B are defined herein.

  本文描述了用于有机发光二极管的分子。示例分子包括至少一个受体基团A，至少一个给体基团D，以及可选地一个或多个桥接基团B。每个基团A与基团B或基团D中的任一基团共价连接，每个基团D与基团B或基团A中的任一基团共价连接，每个基团B与至少一个基团A和至少一个基团D共价连接。这里定义了基团A、D和B的值和首选值。
• 一种吩噁嗪化合物或吩噻嗪化合物的合成方法
  申请人：郑州大学

  公开号：CN106866570A

  公开（公告）日：2017-06-20

  本发明公开了一种系列新型吩噁嗪(吩噻嗪)类化合物及其合成新方法在氮气氛围下，将双卤化合物、伯胺、钯化合物、膦配体、碱溶解在有机溶剂中，加热搅拌反应，萃取、干燥、浓缩、纯化，制得一系列吩噁嗪或吩噻嗪类化合物。本发明涉及氧(硫)氮类化合物合成技术领域，具体涉及一种吩噁嗪(吩噻嗪)类化合物的制备方法。本发明通过钯催化双卤化合物与伯胺N位双芳香化合成吩噁嗪(吩噻嗪)类化合物，合成步骤简单、反应条件温和、操作简便易行、产物收率高达99％，而且所适用的底物范围广泛，为吩噁嗪(吩噻嗪)类化合物的合成提供了一种新思路，在有机合成方法学上具有重大的意义。
• The Preparation of Some 10-Substituted Phenoxazines¹
  作者：Henry Gilman、Leonard O. Moore

  DOI：10.1021/ja01570a048

  日期：1957.7
• CHARGE TRANSPORT MATERIAL AND ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：KITAMURA Tetsu

  公开号：US20100171417A1

  公开（公告）日：2010-07-08

  Provided is a charge transport material represented by the following general formula (1) or (2). In the foregoing general formulae, each of L 1 and L 2 independently represents a connecting group; each of R and R N independently represents a substituent; each of R 1 and R 2 independently represents a substituent, provided that R 1 and R 2 do not represent an aryl group at the same time; each A independently represents a carbon atom or a nitrogen atom; n represents an integer of 2 or more and not more than 10; and each m independently represents an integer.
• AMINE-TYPE POLYMERIC COMPOUND, AND LIGHT-EMITTING ELEMENT COMPRISING THE SAME
  申请人：Ohuchi Kazuei

  公开号：US20100230666A1

  公开（公告）日：2010-09-16

  Disclased is a polymeric compound having a constitutional unit represented by formula (1a), wherein ring A and ring B independently represent an aromatic hydrocarbon ring which may have a substituent; R1 represents a group represented by formula (2); and R2 represents an aryl group or a monovalent aromatic heterocyclic group which may be substituted by an alkyl group or the like. In formula (2), Ar1 to Ar3 independently represent an arylene group or a divalent group to which two or more arylene groups are attached via a single bond; Ar4 to Ar7 independently represent an aryl group or a monovalent aromatic heterocyclic group; R6 represents a hydrogen atom, an alkyl group, an aryl group or a monovalent aromatic heterocyclic group; Ar1 to Ar7 and R6 may be substituted by an alkyl group or the like; and k and kk independently represent an integer of 0 to 3, provided that at least one of k and kk represents an integer of 1 to 3.