N¹-tert-butyl-4-methyl-m-phenylenediamine | 106917-61-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N¹-tert-butyl-4-methyl-m-phenylenediamine
• 英文别名: N¹-tert-Butyl-4-methyl-m-phenylendiamin；N-tertiarybutyl toluenediamine；1,3-Benzenediamine, N1-(1,1-dimethylethyl)-4-methyl-；1-N-tert-butyl-4-methylbenzene-1,3-diamine
• CAS: 106917-61-7
• 化学式: C₁₁H₁₈N₂
• 分子量: 178.277
• InChiKey: JYBTVKOMMYMILH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  38
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2,4-二氨基甲苯 、 叔丁醇 在 碘 作用下， 生成 N¹-tert-butyl-4-methyl-m-phenylenediamine
  参考文献：
  名称：

  Production of n-tertiary-alkylated aromatic secondary monoamines

  摘要：

  公开号：

  US02692287A1

文献信息

• Alkylation of aromatic amines in the presence of acidic, crystalline molecular sieves
  申请人：AIR PRODUCTS AND CHEMICALS, INC.

  公开号：EP0226781A1

  公开（公告）日：1987-07-01

  This invention relates to a process for producing ring alkylated aromatic amines. In the process an aromatic amine is reacted with an olefin using an acidic crystalline molecular sieve as a catalyst. Under the conditions of the process the catalyst is extremely active and with amines that are capable of alkylation at the ortho and para positions, high selectivity to the ortho alkylated isomer can be achieved.

  本发明涉及一种生产环状烷基化芳香胺的工艺。 在该工艺中，使用酸性结晶分子筛作为催化剂，使芳香胺与烯烃发生反应。 在该工艺的条件下，催化剂极为活跃，对于能够在正位和对位发生烷基化反应的胺，可以实现对正位烷基化异构体的高选择性。
• N-tert-butyl derivatives of toluenediamine and mixtures as antioxidant for organic materials
  申请人：AIR PRODUCTS AND CHEMICALS, INC.

  公开号：EP0272651A2

  公开（公告）日：1988-06-29

  This invention relates to the use of tertiary butyl derivatives of toluenediamine and specifically N-tert-butyl-2,6-toluenediamine as an antioxidant material for preventing oxidation of organic materials.

  本发明涉及使用甲苯二胺的叔丁基衍生物，特别是 N-叔丁基-2,6-甲苯二胺作为防止有机材料氧化的抗氧化材料。
• Separating toluenediamine from N-tertiarybutyl toluenediamine
  申请人：AIR PRODUCTS AND CHEMICALS, INC.

  公开号：EP0320879A1

  公开（公告）日：1989-06-21

  This invention relates to an improved process for separating an azeotrope of toluenediamine from N-tertiary-butyl-toluenediamine by contacting the azeotrope with a hydrocarbon which forms a lower boiling azeotrope with toluenediamine and one in which the solubility of toluenediamine is less than 30 grams/100 grams of hydrocarbon.

  本发明涉及一种从 N-叔丁基对苯二胺中分离对苯二胺共沸物的改进工艺，其方法是将对苯二胺共沸物与一种碳氢化合物接触，该碳氢化合物与对苯二胺形成低沸点共沸物，且对苯二胺在其中的溶解度小于 30 克/100 克碳氢化合物。
• ELASTIC POLYURETHANE FOAM AND PROCESS FOR ITS PRODUCTION
  申请人：Asahi Glass Co., Ltd.

  公开号：EP0394487A1

  公开（公告）日：1990-10-31

  The invention relates to an elastic polyurethane foam having a resonance frequency of up to 3.5 Hz and a process for producing same. This foam is lobtained by using as main reactant materials at least one polyol selected from among specific polyoxyalkylene polyols and polymer dispersion polyols based on said polyoxyalkylene polyols as the matrix land a polyisocyanate compound. This foam is produced by using a polyoxyalkylene polyol having a particularly low hydroxyl value (X mg KOH/g) and a particularly low total unsaturation (Y meq/g) or a polymer dispersion polyol based on said polyoxyalkylene polyol as the matrix. More specifically the polyoxyalkylene polyol has a hydroxyl value (X mg KOH/g) of 5 to 38 and a total unsaturation (Y meq/g) of up to 0.07, with the proviso that Y ≤ 0.9/(X-10). A preferred polyoxyalkylene polyol is one containing 70 wt.% or more oxypropylene groups and 5 wt.% or more oxyethylene groups. The use of a small amount of a crosslinking agent together with the polyoxyalkylene polyol is preferred. This foam has vibration properties suited for seat cushions of automobiles. Therefore, it can give a comfortable ride.

  本发明涉及一种共振频率高达 3.5 赫兹的弹性聚氨酯泡沫塑料及其生产工艺。这种泡沫塑料是通过使用至少一种选自特定聚氧亚烷基多元醇的多元醇和基于所述聚氧亚烷基多元醇的聚合物分散体多元醇作为主要反应物材料，并以多异氰酸酯化合物为基体，从而获得的。使用羟值特别低（X 毫克 KOH/克）、总不饱和度特别低（Y meq/克）的聚氧烷基多元醇或以上述聚氧烷基多元醇为基质的聚合物分散体多元醇作为基质，可以产生这种泡沫。更具体地说，聚氧亚烷基多元醇的羟值（X 毫克 KOH/克）为 5 至 38，总不饱和度（Y meq/克）最高为 0.07，但 Y ≤ 0.9/(X-10)。优选的聚氧亚烷基多元醇是含有 70 wt.% 或更多氧丙烯基团和 5 wt.% 或更多氧乙烯基团的多元醇。在使用聚氧烷基多元醇的同时，最好使用少量的交联剂。这种泡沫塑料具有适合汽车坐垫的振动特性。因此，它能带来舒适的乘坐体验。
• Method for producing polyurethane flexible foam
  申请人：ASAHI GLASS COMPANY LTD.

  公开号：EP0443614A2

  公开（公告）日：1991-08-28

  A method for producing a polyurethane flexible foam, which comprises reacting at least one high molecular weight polyol selected from the group consisting of a polyoxyalkylene polyol having a hydroxyl value of from 5 to 38 mgKOH/g, from 2 to 8 hydroxyl groups and a total unsaturation degree of not more than 0.07 meq/g and a polymer-dispersed polyol containing said polyoxyalkylene polyol as the matrix, an optional crosslinking agent and a polyisocyanate compound in the presence of a low viscosity compound having an addition-polymerizable unsaturated group, a catalyst, a foaming agent and a foam stabilizer.

  一种生产聚氨酯软质泡沫塑料的方法，包括使至少一种选自由羟值为 5 至 38 mgKOH/g、羟基数为 2 至 8 个、总不饱和度不超过 0.07 meq/g 的聚氧烷基多元醇，以及在具有可加成聚合的不饱和基团的低粘度化合物、催化剂、发泡剂和泡沫稳定剂存在下，含有上述聚氧烷基多元醇作为基体、任选交联剂和多异氰酸酯化合物的聚合物分散多元醇。