2-[4-[2-(diethylamino)ethylimino]pentan-2-ylideneamino]-N,N-diethylethanamine | 431876-24-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2-[4-[2-(diethylamino)ethylimino]pentan-2-ylideneamino]-N,N-diethylethanamine
• CAS: 431876-24-3
• 化学式: C₁₇H₃₆N₄
• 分子量: 296.5
• InChiKey: BSVLZCKENPXPLF-UHFFFAOYSA-N

物化性质

• 沸点：
  377.1±42.0 °C(Predicted)
• 密度：
  0.89±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  21
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  31.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-[4-[2-(diethylamino)ethylimino]pentan-2-ylideneamino]-N,N-diethylethanamine 以 四氢呋喃 、 正己烷 为溶剂， 生成
  参考文献：
  名称：

  Formation and Characterization of the First Monoalumoxane, LAlO⋅B(C6F5)3

  摘要：

  DOI：

  10.1002/1521-3773(20021115)41:22<4294::aid-anie4294>3.0.co;2-w

文献信息

• Synthesis and structure of LLnBr2 (L=Et2NCH2CH2NC(Me)CHC(Me)NCH2CH2NEt2; Ln=Y, Sm, and Yb)
  作者：Ana Mirela Neculai、Dante Neculai、Herbert W. Roesky、Jörg Magull

  DOI：10.1016/j.poly.2003.10.009

  日期：2004.1

  The reaction of the in situ prepared LLi (L=Et2NCH2CH2NC(Me)CHC(Me)NCH2CH2NEt2) with LnBr(3) (Ln = Y, Sm, and Yb) led to the solvent and alkali salt free dibromoderivative of type LLnBr(2) (Ln = Y, 1, Sm, 2, and Yb, 3). Compounds 1-3 were characterized by X-ray crystallography, elemental analysis, and NMR (1), and their structural features were correlated with those of other compounds bearing the same ligand. (C) 2003 Elsevier Ltd. All rights reserved.
• Synthesis and structure of the heterobimetallic Yb(II) complex of composition L2Yb2LiI3 supported with the β-diketiminato ligand [L=Et2NCH2CH2NC(Me)CHC(Me)NCH2CH2NEt2]
  作者：Grigori B Nikiforov、Herbert W Roesky、Denis Vidovic、Jörg Magull

  DOI：10.1016/s0022-2860(03)00333-8

  日期：2003.8

  The heterobimetallic Yb(II) mixed ligand complex L2Yb2LiI3 1 has been prepared by the reaction of the lithium salt of the ligand L with the ytterbium diiodide. Compound I is characterized by single crystal X-ray structural analysis, multinuclear NMR and mass spectrometry. Complex 1 consists of LYbI and LLi units connected with the central Yb(l) atom. The latter is surrounded by the LYbI and LLi moieties in a sandwich like structure including two bridging iodine atoms. The NCCCN unsaturated system of the ligand in each of the units is almost planar and pi coordinated to the Yb(l) atom. These two planar units are tilted to each other and the pendant arms of the beta-diketiminato ligand in each moiety are bent. The metal atoms are located out of the NCCCN plane of the ligands and the three metal atoms in complex 1 form almost a straight line. (C) 2003 Elsevier B.V. All rights reserved.