4H,4'H-2,2'-Spirobis[benzo[d][1,3,2]dioxasilin]-4,4'-dione | 18419-78-8

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: 4H,4'H-2,2'-Spirobis[benzo[d][1,3,2]dioxasilin]-4,4'-dione
• 英文别名: [2,2']spirobi(benzo[1,3,2]dioxasiline)-4,4'-dione；4H,4'H-2,2'-Spirobi[[1,3,2]benzodioxasiline]-4,4'-dione；2,2'-spirobi[1,3,2-benzodioxasiline]-4,4'-dione
• CAS: 18419-78-8
• 化学式: C₁₄H₈O₆Si
• 分子量: 300.299
• InChiKey: SSZFUPFHXLVWMC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.92
• 重原子数：
  21
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  四氯化硅 、 三甲基甲硅烷醇三硅甲烷氧基水杨酯 反应 10.0h， 以90%的产率得到4H,4'H-2,2'-Spirobis[benzo[d][1,3,2]dioxasilin]-4,4'-dione
  参考文献：
  名称：

  2-Halo-2-organyl-4H-benzo[d][1,3,2]dioxasilin-4-ones

  摘要：

  [GRAPHICS]Original method has been developed for the preparation of previously unknown cyclic organosilicon esters of salicylic acid, containing halogen-silicon bonds. This method is based on the reaction of trimethylsilyl ester of 2-(trimethylsiloxy) benzoic acid with organylhalosilanes (RRSiXY)-Si-1 under mild conditions, where R, R-1 = Cl, Me, CH=CH2, Ph; X, Y = Cl, F.

  DOI：

  10.1007/s10593-015-1698-1

文献信息

• 2-Halo-2-organyl-4H-benzo[d][1,3,2]dioxasilin-4-ones
  作者：Sergey V. Basenko、Lev E. Zelenkov

  DOI：10.1007/s10593-015-1698-1

  日期：2015.3

  [GRAPHICS]Original method has been developed for the preparation of previously unknown cyclic organosilicon esters of salicylic acid, containing halogen-silicon bonds. This method is based on the reaction of trimethylsilyl ester of 2-(trimethylsiloxy) benzoic acid with organylhalosilanes (RRSiXY)-Si-1 under mild conditions, where R, R-1 = Cl, Me, CH=CH2, Ph; X, Y = Cl, F.