5,10-dihydro-5,10-diethylphenazine | 62248-00-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: 5,10-dihydro-5,10-diethylphenazine
• 英文别名: 5,10-diethyl-5,10-dihydro-phenazine；5,10-Diaethyl-5,10-dihydro-phenazin；5,10-Diethyl-5,10-dihydro-phenazin；5,10-Dihydro-5,10-diethyl-phenazin；5,10-Diethylphenazine
• CAS: 62248-00-4
• 化学式: C₁₆H₁₈N₂
• 分子量: 238.332
• InChiKey: NLWQIZYSEISWOK-UHFFFAOYSA-N

物化性质

• 熔点：
  127-128 °C(Solv: ethanol (64-17-5))
• 沸点：
  367.8±12.0 °C(Predicted)
• 密度：
  1.067±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  5,10-dihydro-5,10-diethylphenazine 、 7,7,8,8-四氰基对苯二醌二甲烷 以 乙腈 为溶剂， 生成 5,10-dihydro-5,10-diethylphenaziniumyl 2,2'-(2,5-cyclohexadiene-1,4-diylidene)-bispropanedinitrilate
  参考文献：
  名称：

  Dietz, K.; Endres, H.; Keller, H. J., Zeitschrift fur Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1982, vol. 37, # 4, p. 437 - 442

  摘要：

  DOI：
• 作为产物：
  描述：

  氯乙烷 、 alkaline earth salt of/the/ methylsulfuric acid 在 乙二醇二甲醚 作用下， 生成 5,10-dihydro-5,10-diethylphenazine
  参考文献：
  名称：

  Michailow; Blochina, Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1950, p. 304,309, 312

  摘要：

  DOI：

文献信息

• ORGANIC COMPOUND, ELECTROCHROMIC COMPOUND, AND ELECTROCHROMIC ELEMENT, OPTICAL FILTER, LENS UNIT, IMAGING DEVICE, AND WINDOW COMPONENT HAVING SAME
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20170329195A1

  公开（公告）日：2017-11-16

  An organic compound represented by General Formula (1), in which, in General Formula (1), R 1 represents an alkyl group or an alkoxy group, X 1 and X 2 are each independently selected from an alkyl group which may have a substituent, an aryl group which may have a substituent, or an aralkyl group which may have a substituent, and A 1 − and A 2 − each independently represent a monovalent anion.

  在通用公式(1)中，R1代表一个烷基或烷氧基，X1和X2各自独立地从可能含有一个取代基的烷基、可能含有一个取代基的芳基或可能含有一个取代基的芳烷基中选择，A1-和A2-各自独立地代表一个单价阴离子。
• ORGANIC COMPOUND, ELECTROCHROMIC ELEMENT CONTAINING THE SAME, OPTICAL FILTER, LENS UNIT, IMAGING DEVICE, AND WINDOW MATERIAL
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20170313934A1

  公开（公告）日：2017-11-02

  An organic compound represented by the following general formula is provided. In the above formula (1), R 11 to R 15 each independently represent a hydrogen atom, an alkyl group, an alkoxy group, an aryl group, an aryloxy group, an aralkyl group, an acyl group, or a halogen atom provided that at least one of R 11 , R 13 , and R 15 represents the alkoxy group or the aryloxy group; and R 11 to R 15 may form a ring structure therebetween, R 5 and R 6 each independently represent an alkyl group, an aryl group, or an aralkyl group. In addition, R 21 to R 24 each independently represent a hydrogen atom, an alkyl group, an alkoxy group, an aryl group, an aryloxy group, an aralkyl group, an acyl group, or a halogen atom and may form a ring structure therebetween. The above groups except the acyl group may be substituted when necessary.

  提供以下一般式所代表的有机化合物。在上述式（1）中，R11到R15分别独立地代表氢原子、烷基基团、烷氧基团、芳基团、芳氧基团、芳基烷基团、酰基团或卤素原子，其中至少有一个R11、R13和R15代表烷氧基团或芳氧基团；R11到R15之间可以形成环结构，R5和R6分别独立地代表烷基基团、芳基团或芳基烷基团。此外，R21到R24分别独立地代表氢原子、烷基基团、烷氧基团、芳基团、芳氧基团、芳基烷基团、酰基团或卤素原子，并且它们之间可以形成环结构。除酰基团外，上述基团在必要时可以被取代。
• ORGANIC COMPOUND, ELECTROCHROMIC ELEMENT CONTAINING THE SAME, OPTICAL FILTER, LENS UNIT, IMAGING DEVICE, AND WINDOW COMPONENT
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20160246152A1

  公开（公告）日：2016-08-25

  Provided is an electrochromic material that displays a yellow color and can be reversibly colored and breached in a stable manner through chemical reduction. To be more specific, provided is an organic compound represented by general formula (1) or (2). In general formulae (1) and (2), X 1 and X 2 are each independently selected from a substituted or unsubstituted alkyl group and a substituted or unsubstituted aralkyl group. R 11 to R 20 represent a hydrogen atom or a substituent. A 1 − and A 2 − each independently represent a monovalent anion.

  提供一种电致变色材料，显示黄色，并可通过化学还原稳定地可逆着色和漂白。更具体地说，提供的是由通用式（1）或（2）表示的有机化合物。在通用式（1）和（2）中，X1和X2分别独立选择自取代或未取代的烷基团和取代或未取代的芳基烷基团。R11到R20代表氢原子或取代基。A1-和A2-每个独立表示一价阴离子。
• ORGANIC COMPOUND, ELECTROCHROMIC ELEMENT, OPTICAL FILTER, LENS UNIT, IMAGE PICKUP APPARATUS, AND WINDOW MEMBER
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20180237393A1

  公开（公告）日：2018-08-23

  Provided is an organic compound, which is represented by the general formula (1): in the general formula (1), R 1 and R 2 are each independently selected from the group consisting of an alkyl group having 1 or more and 20 or less carbon atoms, an aryl group, an aralkyl group, and a heteroaryl group, R 3 and R 4 are each independently selected from an alkyl group having 1 or more and 10 or less carbon atoms, and an alkoxy group having 1 or more and 10 or less carbon atoms, and A 1 − and A 2 − each independently represent a monovalent anion.

  提供的是一种有机化合物，其通式表示为（1）：在通式（1）中，R1和R2各自独立地选自由1个或多个至20个或更少碳原子的烷基基团、芳基团、芳基烷基基团和杂环芳基团中的一种，R3和R4各自独立地选自由1个或多个至10个或更少碳原子的烷基基团和1个或多个至10个或更少碳原子的烷氧基团，A1-和A2-各自独立地代表一价阴离子。
• ORGANIC COMPOUND AND ELECTROCHROMIC ELEMENT
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20190241798A1

  公开（公告）日：2019-08-08

  An organic compound according to one embodiment of the present invention is an organic compound represented by general formula (1). Each of X 1 and X 2 is an alkyl group or the like that may have a substituent. Each of R 11 to R 18 is a hydrogen atom, an alkyl group that may have a substituent, or the like. Each of R 21 and R 22 is a hydrogen atom, an alkyl group that may have a substituent, or the like. A 1 − and A 2 − independently represent a monovalent anion, respectively.

  根据本发明的一种实施例，有机化合物是由通式（1）表示的有机化合物。X1和X2中的每一个是可以具有取代基的烷基基团或类似物。R11到R18中的每一个是氢原子，可以具有取代基的烷基基团或类似物。R21和R22中的每一个是氢原子，可以具有取代基的烷基基团或类似物。A1−和A2−分别独立表示单价阴离子。