10-(9,9'-Spirobi[fluorene]-3-yl)phenoxazine | 1428932-80-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 10-(9,9'-Spirobi[fluorene]-3-yl)phenoxazine
• 英文别名: 10-(9,9'-spirobi[fluorene]-3-yl)phenoxazine
• CAS: 1428932-80-2
• 化学式: C₃₇H₂₃NO
• 分子量: 497.596
• InChiKey: KOEOSBXAEHNJRL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.2
• 重原子数：
  39
• 可旋转键数：
  1
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-amino-2-bromobenzophenone 在 盐酸 、 正丁基锂 、 三叔丁基膦 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 、 sodium t-butanolate 、 sodium nitrite 作用下， 以 乙醚 、 水 、 丙酮 、 甲苯 为溶剂， 反应 1.0h， 生成 10-(9,9'-Spirobi[fluorene]-3-yl)phenoxazine
  参考文献：
  名称：

  Spirobifluorene compounds for light emitting devices

  摘要：

  用于发光装置的新型螺联苯化合物，其中螺联苯环系统包含至少一个在间位上结合到螺联苯上的配体，该配体通过一个异原子与螺联苯结合，该异原子不属于一个环系统。

  公开号：

  EP2574608A1

文献信息

• LIGHT-EMITTING ELEMENT
  申请人：Sumitomo Chemical Company Limited

  公开号：EP3618134A1

  公开（公告）日：2020-03-04

  To provide a light emitting device excellent in luminance life. A light emitting device having an anode, a cathode, a first organic layer disposed between the anode and the cathode and a second organic layer disposed between the anode and the cathode, wherein the first organic layer is a layer containing a compound represented by the formula (C-1), and the second organic layer is a layer containing a compound represented by the formula (C-1) and a cross-linked body of a crosslinkable material: [wherein, Ring R1C and Ring R2C represent an aromatic hydrocarbon ring or an aromatic hetero ring. RC represents an oxygen atom, a sulfur atom or a group represented by the formula (C'-1).] [wherein, Ring R3C and Ring R4C represent an aromatic hydrocarbon ring or an aromatic hetero ring. RC' represents a carbon atom, a silicon atom, a germanium atom, a tin atom or a lead atom.]

  提供一种亮度寿命极佳的发光器件。 一种发光器件，具有阳极、阴极、设置在阳极和阴极之间的第一有机层以及设置在阳极和阴极之间的第二有机层，其中 第一有机层是含有式（C-1）表示的化合物的层，以及 第二有机层是含有式（C-1）表示的化合物和可交联材料的交联体的层： 其中 环 R1C 和环 R2C 代表芳香烃环或芳香杂环。 RC 代表氧原子、硫原子或由式（C'-1）代表的基团。］ 其中 环 R3C 和环 R4C 代表芳香烃环或芳香杂环。 RC'代表碳原子、硅原子、锗原子、锡原子或铅原子]。
• COMPOSITION AND LIGHT-EMITTING ELEMENT USING SAME
  申请人：Sumitomo Chemical Company Limited

  公开号：EP3618578A1

  公开（公告）日：2020-03-04

  To provide a composition which is useful for production of a light emitting device excellent in external quantum efficiency. A composition comprising two or more compounds represented by the formula (C-1) and a phosphorescent compound, wherein at least one of the above-described two or more compounds represented by the formula (C-1) is a compound represented by the formula (C-1) in which RC is a group represented by the formula (C'-1) : [wherein, Ring R1C and Ring R2C represent an aromatic hydrocarbon ring or an aromatic hetero ring. RC represents an oxygen atom, a sulfur atom or a group represented by the formula (C'-1).] [wherein, Ring R3C and Ring R4C represent an aromatic hydrocarbon ring or an aromatic hetero ring. RC' represents a carbon atom, a silicon atom, a germanium atom, a tin atom or a lead atom.].

  提供一种可用于生产外部量子效率极佳的发光器件的组合物。 一种由两种或两种以上由式（C-1）表示的化合物和一种磷光化合物组成的组合物，其中上述两种或两种以上由式（C-1）表示的化合物中至少有一种是由式（C-1）表示的化合物，其中 RC 是由式（C'-1）表示的基团： 其中 环 R1C 和环 R2C 代表芳香烃环或芳香杂环。 RC 代表氧原子、硫原子或由式（C'-1）代表的基团]。 其中 环 R3C 和环 R4C 代表芳香烃环或芳香杂环。 RC'代表碳原子、硅原子、锗原子、锡原子或铅原子]。
• Composition and light emitting device using the same
  申请人：Sumitomo Chemical Company, Limited

  公开号：US11532790B2

  公开（公告）日：2022-12-20

  A composition which is useful for producing a light emitting device having excellent external quantum efficiency contains two or more compounds represented by the formula (C-1) and a phosphorescent compound, in which at least one of the compounds represented by the formula (C-1) is a compound in which R C is a group represented by the formula (C′-1). Ring R 1C and Ring R 2C represent an aromatic hydrocarbon ring or an aromatic hetero ring. R C represents an oxygen atom, a sulfur atom or a group represented by the formula (C′-1). Ring R 3C and Ring R 4C represent an aromatic hydrocarbon ring or an aromatic hetero ring. R C ′ represents a carbon atom, a silicon atom, a germanium atom, a tin atom or a lead atom.

  一种可用于生产具有极佳外部量子效率的发光器件的组合物含有两种或两种以上由式（C-1）表示的化合物和一种磷光化合物，其中至少一种由式（C-1）表示的化合物是其中 R C 是式 (C′-1) 所代表的基团。 环 R 1C 和环 R 2C 代表芳香烃环或芳香杂环。R C 代表氧原子、硫原子或由式 (C′-1) 代表的基团。 环 R 3C 和环 R 4C 代表芳香烃环或芳香杂环。R C 代表碳原子、硅原子、锗原子、锡原子或铅原子。
• SPIROBIFLUORENE COMPOUNDS FOR LIGHT EMITTING DEVICES
  申请人：Sumitomo Chemical Co., Ltd.

  公开号：EP2760847B1

  公开（公告）日：2018-04-25
• COMPOSITION AND LIGHT EMITTING DEVICE USING THE SAME
  申请人：Sumitomo Chemical Company, Limited

  公开号：US20200044156A1

  公开（公告）日：2020-02-06

  A composition which is useful for producing a light emitting device having excellent external quantum efficiency contains two or more compounds represented by the formula (C-1) and a phosphorescent compound, in which at least one of the compounds represented by the formula (C-1) is a compound in which R C is a group represented by the formula (C′-1). Ring R 1C and Ring R 2C represent an aromatic hydrocarbon ring or an aromatic hetero ring. R C represents an oxygen atom, a sulfur atom or a group represented by the formula (C′-1). Ring R 3C and Ring R 4C represent an aromatic hydrocarbon ring or an aromatic hetero ring. R C ′ represents a carbon atom, a silicon atom, a germanium atom, a tin atom or a lead atom.