10-nitro-1-((tetrahydrofuran-3-yl)methyl)-1,2,3,5,6,7,8,9-octahydro-5,9-epoxyimidazo[1,2-a]azocine | 1231770-65-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧烷类
• 英文名称: 10-nitro-1-((tetrahydrofuran-3-yl)methyl)-1,2,3,5,6,7,8,9-octahydro-5,9-epoxyimidazo[1,2-a]azocine
• 英文别名: 7-nitro-5-(oxolan-3-ylmethyl)-12-oxa-2,5-diazatricyclo[6.3.1.02,6]dodec-6-ene
• CAS: 1231770-65-2
• 化学式: C₁₄H₂₁N₃O₄
• 分子量: 295.338
• InChiKey: YXQNICOIKKYZCA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  21
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  70.8
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  咪唑烷,2-(硝基亚甲基)-1-[(四氢-3-呋喃基)甲基]- 、 戊二醛 在 盐酸 作用下， 以 水 、 乙腈 为溶剂， 以36%的产率得到10-nitro-1-((tetrahydrofuran-3-yl)methyl)-1,2,3,5,6,7,8,9-octahydro-5,9-epoxyimidazo[1,2-a]azocine
  参考文献：
  名称：

  HETEROCYCLIC NITROGENOUS OR OXYGENOUS COMPOUNDS WITH INSECTICIDAL ACTIVITY FORMED FROM DIALDEHYDES AND THEIR PREPARATION AND USES THEREOF

  摘要：

  提供了由二醛形成的具有化学式(A)、(B)、(C)或(D)的杂环氮或氧化合物，它们的光学异构体、顺式和反式异构体，或者农药可接受的盐，它们的制备方法，包括这些化合物的农药组合物以及它们的用途。这些化合物及其衍生物对几种农业和林业害虫具有高杀虫活性，包括同翅目和鳞翅目害虫，如蚜虫、蝉总科昆虫、烟粉虱、叶蝉、普通飞虱、棉铃虫、甘蓝青虫、甘蓝蛾、棉叶螟、军虫等。

  公开号：

  US20110269751A1

文献信息

• DIVALENT AND OXABRIDGED HETEROCYCLIC NEONICOTINOID COMPOUNDS AND PREPARATION METHODS THEREOF
  申请人：Qian Xuhong

  公开号：US20120245126A1

  公开（公告）日：2012-09-27

  Nitromethylene analogues of imidacloprid and divalent and oxabridged heterocyclic neonicotinoid compounds constructed by dialdehydes, preparation methods and uses thereof are disclosed. Compounds represented by formula (A) or (B), their optical isomers or agrochemically acceptable salts are provided. Agrochemical compositions comprising the said compounds, their optical isomers or agrochemically acceptable salts, the uses of the said agrochemical compositions and the preparation methods of the said compounds, their optical isomers or agrochemically acceptable salts are also disclosed. The compounds and their derivatives have high insecticidal activities to several farming and forestry pests including homoptera and lepidoptera pests, such as aphis , fulgorid, whitefly, leafhopper, common thrips, cotton bollworm, cabbage caterpillar, cabbage moth, cotton leafworm and armyworm.

  本文揭示了由二醛构建的硝基咪虫啉类和二价及氧桥杂环新烟碱类化合物的亚硝基甲烯类似物，其制备方法和用途。提供了由式（A）或（B）表示的化合物及其光学异构体或农业化学上可接受的盐。还揭示了包含所述化合物、其光学异构体或农业化学上可接受的盐的农药组合物，所述农药组合物的用途以及所述化合物、其光学异构体或农业化学上可接受的盐的制备方法。这些化合物及其衍生物对多种农林害虫具有高效的杀虫活性，包括同翅目和鳞翅目害虫，如蚜虫、叶蝉、白粉虱、跳小蜂、普通蓟马、棉铃虫、菜青虫、小菜蛾、棉叶虫和军农虫。
• Heterocyclic nitrogenous or oxygenous compounds with insecticidal activity formed from dialdehydes and their preparation and uses thereof
  申请人：Li Zhong

  公开号：US08563546B2

  公开（公告）日：2013-10-22

  The heterocyclic nitrogenous or oxygenous compounds of formula (A), (B), (C) or (D) formed from dialdehydes, their optical isomers, cis- and trans-isomers, or agrochemically acceptable salts, their preparation methods, agrochemical compositions comprising the compounds and the uses thereof are provided. The compounds and their derivatives have high insecticidal activities to several farming and forestry pests including homoptera and lepidoptera pests, such as aphis, fulgorid, whitefly, leafhopper, common thrips, cotton bollworm, cabbage caterpillar, cabbage moth, cotton leafworm, armyworm and so on.

  提供由二醛(A)、(B)、(C)或(D)形成的杂环氮或氧化合物，它们的光学异构体、顺反异构体或农药可接受的盐，它们的制备方法，包括这些化合物的农药组成物及其用途。这些化合物及其衍生物对几种农林害虫具有高度的杀虫活性，包括同翅目和鳞翅目害虫，如蚜虫、叶蝉、白粉虱、飞虱、普通蓟马、棉铃虫、卷叶蛾、甘蓝蛾、棉叶虫、斜纹夜蛾等。
• US8563546B2
  申请人：——

  公开号：US8563546B2

  公开（公告）日：2013-10-22
• US8809319B2
  申请人：——

  公开号：US8809319B2

  公开（公告）日：2014-08-19
• HETEROCYCLIC NITROGENOUS OR OXYGENOUS COMPOUNDS WITH INSECTICIDAL ACTIVITY FORMED FROM DIALDEHYDES AND THEIR PREPARATION AND USES THEREOF
  申请人：East China University of Science and Technology

  公开号：EP2377845B1

  公开（公告）日：2015-01-28