10-(4-methylphenyl)phenoxazine | 58736-73-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 10-(4-methylphenyl)phenoxazine
• CAS: 58736-73-5
• 化学式: C₁₉H₁₅NO
• 分子量: 273.334
• InChiKey: QDVXGDAXRMYHMW-UHFFFAOYSA-N

物化性质

• 沸点：
  411.4±25.0 °C(Predicted)
• 密度：
  1.195±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  21
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  邻碘溴苯 在 potassium phosphate 、 copper(l) iodide 、 iron(III)-acetylacetonate 、 DPEphos 、 palladium diacetate 、 sodium t-butanolate 作用下， 以 二甲基亚砜 、 甲苯 为溶剂， 反应 33.0h， 生成 10-(4-methylphenyl)phenoxazine
  参考文献：
  名称：

  Pd催化的伯胺双N芳基化反应合成吩恶嗪和吩噻嗪

  摘要：

  开发了在芳基卤化物和伯胺之间形成高效且通用的钯催化串联C–N键的方法。该转化允许从容易获得的前体一锅合成苯恶嗪和吩噻嗪衍生物，该苯恶嗪和吩噻嗪衍生物具有广泛的取代模式。

  DOI：

  10.1039/c7ob01540b

文献信息

• A general route for synthesis of N-aryl phenoxazines via copper(<scp>i</scp>)-catalyzed N-, N-, and O-arylations of 2-aminophenols
  作者：Nan Liu、Bo Wang、Wenwen Chen、Chulong Liu、Xinyan Wang、Yuefei Hu

  DOI：10.1039/c4ra09593f

  日期：——

  copper(I)-catalyzed tandem reaction of N- and O-arylations of 2-[N-(2-chlorophenyl)amino]phenols was developed, by which a series of structurally novel N-aryl phenoxazines were synthesized efficiently. This success owes much to the discovery of highly efficient homogeneous copper(I)-catalyzed intramolecular O-arylation of chlorobenzenes under ligand-free-like conditions. Since 2-[N-(2-chlorophenyl)amino]phenols

  开发了一种新型的铜（I）催化2- [ N-（2-氯苯基）氨基]苯酚的N-和O-芳基化串联反应，从而有效地合成了一系列结构新颖的N-芳基吩恶嗪。该成功很大程度上归功于在无配体样条件下高效高效的均相铜（I）催化的氯苯分子内O-芳基化的发现。由于2- [ N-（2-氯苯基）氨基]苯酚也是通过铜（I）催化的2-氨基苯酚的N-芳基化反应制备的，因此是有效合成N的一般途径。通过两步铜（I）催化2-氨基苯酚的N-，N-和O-芳基化反应建立了芳基吩恶嗪。
• Nickel-Catalyzed <i>N</i>-Arylation of Diarylamines for Triarylamine Synthesis
  作者：Kunjun Hu、Yunlong Gao、Jian Jin

  DOI：10.1021/acs.organomet.2c00025

  日期：2022.3.14

  A practical nickel-catalyzed C–N cross-coupling reaction between diarylamines and aryl halides has been developed using commercially available NiCl2(dppf) as the catalyst. This robust method can be efficiently applied to a variety of diarylamines which are privileged motifs in materials science, including phenoxazines, phenothiazines, carbazoles, diphenylamines, 9-10-dihydroacridines, 10,11-dihydro-5H-dibenzo[b

  已经使用市售的 NiCl 2 (dppf) 作为催化剂，开发了一种实用的镍催化二芳基胺和芳基卤化物之间的 C-N 交叉偶联反应。这种稳健的方法可以有效地应用于各种二芳基胺，它们是材料科学中的特权基序，包括吩恶嗪、吩噻嗪、咔唑、二苯胺、9-10-二氢吖啶、10,11-二氢-5 H-二苯并[ b , f ]氮杂类、5 H-二苯并[ b , f ]氮杂类和 9 H-三苯并[ b , d , f ]氮杂类。
• Benzindolocarbazole Derivative, Light-Emitting Element Material Produced Using Same, and Light-Emitting Element
  申请人：TORAY INDUSTRIES, INC.

  公开号：US20150280140A1

  公开（公告）日：2015-10-01

  The present invention provides an organic thin film light emitting device having high luminous efficiency and durable life realized by using a benzindolocarbazole derivative as represented by either general formula (1-1) or (1-2) given below: [Chemical compound 1] wherein R 1 to R 24 may be identical to or different from each other and are selected from the group consisting of a hydrogen atom, alkyl group, cycloalkyl group, heterocyclic group, amino group, alkenyl group, cycloalkenyl group, alkynyl group, alkoxy group, alkylthio group, aryl ether group, aryl thioether group, aryl group, heteroaryl group, halogen atom, carbonyl group, carboxyl group, oxycarbonyl group, carbamoyl group, silyl group, and —P(═O)R 25 R 26 ; R 25 and R 26 represent either an aryl group or a heteroaryl group; R 25 and R 26 may be condensed to form a ring; L 1 to L 4 independently represent a single bond, a substituted or unsubstituted arylene group, or a substituted or unsubstituted heteroarylene group; and A 1 to A 4 independently represent an amino group, aryl group, heterocyclic group, or heteroaryl group.

  本发明提供了一种有机薄膜发光装置，其具有高发光效率和耐久寿命，该装置是通过使用如下通式（1-1）或（1-2）所示的苯并咯吡唑衍生物实现的：[化合物1]其中R1至R24可以相同也可以不同，且选择自氢原子、烷基、环烷基、杂环基、氨基、烯基、环烯基、炔基、烷氧基、烷硫基、芳基醚基、芳基硫醚基、芳基、杂芳基、卤素原子、羰基、羧基、氧羰基、氨基甲酰基、硅烷基和—P(═O)R25R26的群组中；R25和R26表示芳基或杂芳基；R25和R26可以缩合形成环；L1至L4独立地表示单键、取代或未取代芳基烷基或取代或未取代杂芳基烷基；以及A1至A4独立地表示氨基、芳基、杂环基或杂芳基。
• Novel organic electroluminescent compounds and organic electroluminescent device using the same
  申请人：Gracel Display Inc.

  公开号：EP2100941A2

  公开（公告）日：2009-09-16

  The present invention relates to novel organic electroluminescent compounds, and organic light-emitting diodes and organic solar cells comprising the same. More specifically, the organic electroluminescent compounds according to the present invention are represented by Chemical Formula (1) The organic electroluminescent compounds according to the invention exhibit high luminous efficiency and excellent color purity and life property as a material, so that an OLED having very good operation life can be prepared therefrom.

  本发明涉及新型有机电致发光化合物，以及由其组成的有机发光二极管和有机太阳能电池。更具体地说，根据本发明的有机电致发光化合物由化学式（1）表示 根据本发明的有机电致发光化合物作为一种材料，具有高发光效率、优异的色纯度和寿命特性，因此可以制备出具有极佳工作寿命的有机发光二极管。
• Organic compound and organic electroluminescent element comprising same
  申请人：DOOSAN CORPORATION

  公开号：US10008675B2

  公开（公告）日：2018-06-26

  The present disclosure relates to a novel compound and an organic electroluminescent element including the same, and the compound according to the present disclosure is used for an organic material layer of the organic electroluminescent element, thereby improving the light emitting efficiency, driving voltage, lifetime, and the like of the organic electroluminescent element.

  本公开涉及一种新型化合物和包括该化合物的有机电致发光元件，根据本公开的化合物用于有机电致发光元件的有机材料层，从而提高有机电致发光元件的发光效率、驱动电压、寿命等。