申请人:Mitsui Chemicals, Inc.
公开号:EP2469618A1
公开(公告)日:2012-06-27
The invention provides a piezoelectric polymer material comprising a helical chiral polymer having a weight average molecular weight of from 50,000 to 1,000,000 and optical activity, the piezoelectric polymer material having: crystallinity as obtained by a DSC method of from 40% to 80%; a transmission haze with respect to visible light of from 0.0% to 40%; a standardized molecular orientation MORc, which is measured with a microwave transmission-type molecular orientation meter at a reference thickness of 50 µm, of from 3.5 to 15.0; and a product of the crystallinity and the standardized molecular orientation MORc of from 100 to 700, and a piezoelectric polymer material comprising a polylactic acid-based polymer and polyvinylidene fluoride, wherein a content of the polyvinylidene fluoride is from more than 0 mass% to 5 mass% with respect to the total mass of the polylactic acid-based polymer, and wherein a piezoelectric constant d14 measured by a resonance method at 25°C is 10 pC/N or more. According to the invention, a method of producing a piezoelectric polymer material that exhibits a large piezoelectric constant d14 and excellent transparency and dimensional stability.
本发明提供了一种压电聚合物材料,该材料由重量平均分子量为 50,000 至 1,000,000 的螺旋手性聚合物和光学活性组成,该压电聚合物材料具有:通过 DSC 方法获得的结晶度为 40% 至 80%;相对于可见光的透射雾度为 0.0% 至 40%;在基准厚度为 50 µm 时用微波透射型分子取向仪测量的标准化分子取向 MORc 为 3.5 至 15.0;以及结晶度和标准化分子取向 MORc 的乘积为 100 至 700。根据本发明,一种压电聚合物材料,包括聚乳酸基聚合物和聚偏氟乙烯,其中聚偏氟乙烯的含量相对于聚乳酸基聚合物的总质量为0质量%以上至5质量%,并且在25℃下通过共振法测得的压电常数d14为10 pC/N或以上。根据本发明,一种生产压电聚合物材料的方法,该材料具有较大的压电常数 d14 以及优异的透明度和尺寸稳定性。