2,2-bis(4-trifluorovinyloxyphenyl)-1,1,1,3,3,3-hexafluoropropane | 134130-23-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2-bis(4-trifluorovinyloxyphenyl)-1,1,1,3,3,3-hexafluoropropane
• 英文别名: 1-[1,1,1,3,3,3-hexafluoro-2-[4-(1,2,2-trifluoroethenoxy)phenyl]propan-2-yl]-4-(1,2,2-trifluoroethenoxy)benzene
• CAS: 134130-23-7
• 化学式: C₁₉H₈F₁₂O₂
• 分子量: 496.252
• InChiKey: JYIVNNKUQCLJQF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.5
• 重原子数：
  33
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.157
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  14

反应信息

• 作为产物：
  描述：

  2,2-bis(4-(1-bromo-tetrafluoroethoxy)phenyl)-1,1,1,3,3,3-hexafluoropropane 在 异丁酰胺 、 锌 作用下， 生成 2,2-bis(4-trifluorovinyloxyphenyl)-1,1,1,3,3,3-hexafluoropropane
  参考文献：
  名称：

  氟化双相体系中几乎无还原的脱卤的一般方法

  摘要：

  我们已经研究了在双相氟化/氢化溶剂系统中，直链和环状的卤代氟代烷烃和氟化醚以及含有芳族部分的卤代氟代烷烃的脱卤为其相应的不饱和物质。

  DOI：

  10.1016/j.jfluchem.2008.01.018

文献信息

• AMINOBENZENE COMPOSITIONS AND RELATED DEVICES AND METHODS
  申请人：Plextronics, Inc.

  公开号：US20130075670A1

  公开（公告）日：2013-03-28

  Oligomers and/or polymers comprising a backbone comprising arylamine and fluorinated alkyleneoxy moieties which may be crosslinked. Ink formulations and devices can be formed from the oligomers or polymers, or corresponding monomers. Doped compositions can be formed. Charge injection and transport layers can be formed. Improved stability can be achieved in organic electronic devices such as OLEDs and OPVs.

  由含有芳基胺和氟代烷氧基的骨架组成的寡聚体和/或聚合物，可以交联。可以从这些寡聚体或聚合物，或相应的单体中形成墨水配方和设备。可以形成掺杂的组合物。可以形成电荷注入和传输层。可以在有机电子器件（如OLED和OPV）中实现改善稳定性。
• Dehalogenation process
  申请人：Wlassics Ivan

  公开号：US20060252966A1

  公开（公告）日：2006-11-09

  A process for obtaining vinyl compounds by dehalogenation of halofluorinated compounds with aromatic substituents, having formula: T-Ar-(O) y -CFX′-CF 2 X″(I) wherein: X′=F, Cl, Br, I; X″=Cl, Br, I; y= 0, 1 ; when y= 0 X′≠F; T=H, -(O)Y-CFX′-CF 2 X″, wherein y, X′ and X″ are as above; Ar is a monocyclic, bicyclic or tricyclic bivalent aromatic radical from 6 to 14 carbon atoms, optionally containing heteroatoms, or Ar is formed of two aromatic rings linked by a bivalent radical; said process characterized in that the halofluorinated compounds are dehalogenated in the presence of a transition metal, by operating in a biphasic system of solvents immiscible among each other, formed of a (per)fluorinated solvent and a dipolar aprotic or protic solvent (co-solvent), wherein the ratio moles co-solvent/equivalents of the halofluorinated compound with aromatic substituents ranges from 0.5 to 10.

  一种通过芳基取代的卤氟化合物的去卤化反应来获得乙烯基化合物的方法，其具有以下化学式：T-Ar-(O)y-CFX′-CF2X″(I)其中：X′=F，Cl，Br，I；X″=Cl，Br，I；y=0，1；当y=0时，X′≠F；T=H，-(O)Y-CFX′-CF2X″，其中y，X′和X″如上所述；Ar是一个单环、双环或三环的双价芳香基团，由6到14个碳原子组成，可选地含有杂原子，或者Ar由两个芳香环通过一个双价基团连接而成；所述方法的特征在于，在过渡金属的存在下，通过在两种不相溶的溶剂的双相系统中操作，其中一种是(per)氟化溶剂，另一种是双极无水溶剂或质子溶剂（共溶剂），其中共溶剂的摩尔比/具有芳基取代的卤氟化合物的当量比范围从0.5到10。
• Fluorinated reactive compositions for golf balls
  申请人：Rajagopalan Murali

  公开号：US20060199937A1

  公开（公告）日：2006-09-07

  A golf ball is disclosued, comprising: a core, the core having a diameter of 1.5 inches to 1.65 inches and a first coefficient of restitution of 0.8 or greater at 125 ft/s; an intermediate layer disposed about the core, the intermediate layer having a first Shore D hardness of 20 to 80 and comprising a blend of two or more ionomers; and an outer cover layer disposed about the intermediate layer; the outer cover layer having a thickness of 0.005 inches to 0.05 inches and a second Shore D hardness of 30 to 70, the outer cover layer being composed of a castable material formed from reactants comprising at least one fluorinated polyfunctional compound, wherein the golf ball has a second coefficient of restitution of 0.8 or greater at 125 ft/s and a compression of 50 to 120.
• Biomedical devices
  申请人：Schorzman Derek

  公开号：US20070004866A1

  公开（公告）日：2007-01-04

  Biomedical devices formed from a polymerization product of a monomeric mixture comprising one or more monomers comprising at least two trifluorovinyl groups are provided. Also provided are biomedical devices formed from a network of a polymer comprising one or more perfluorocyclobutane rings in the polymer backbone wherein the network is formed by crosslinks in the polymer.
• Perfluorocyclobutane copolymers
  申请人：Schorzman Derek

  公开号：US20070004867A1

  公开（公告）日：2007-01-04

  The present invention provides copolymer having repeating units based on polyoxyalkylene radicals, polysiloxane radicals and perfluorocyclobutane radicals. The copolymers are useful as biomedical devices such as contact lenses or intraocular lenses.