N-(heptan-2-yl)-naphthalene-1,8-dicarboxyanhydride-4,5-dicarboxyimide | 866142-18-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异喹啉及其衍生物
• 英文名称: N-(heptan-2-yl)-naphthalene-1,8-dicarboxyanhydride-4,5-dicarboxyimide
• 英文别名: 13-Heptan-2-yl-6-oxa-13-azatetracyclo[6.6.2.04,16.011,15]hexadeca-1(15),2,4(16),8,10-pentaene-5,7,12,14-tetrone
• CAS: 866142-18-9
• 化学式: C₂₁H₁₉NO₅
• 分子量: 365.386
• InChiKey: KZPSJBUALQKJAF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  27
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  80.8
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  N-(heptan-2-yl)-naphthalene-1,8-dicarboxyanhydride-4,5-dicarboxyimide 在 肼 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 1.53h， 生成 6-Amino-13-heptan-2-yl-6,13-diazatetracyclo[6.6.2.04,16.011,15]hexadeca-1(15),2,4(16),8,10-pentaene-5,7,12,14-tetrone
  参考文献：
  名称：

  EP1736476

  摘要：

  公开号：
• 作为产物：
  描述：

  1,4,5,8-萘四甲酸酐 、 异庚胺 在 溶剂黄146 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 5.0h， 以28%的产率得到N-(heptan-2-yl)-naphthalene-1,8-dicarboxyanhydride-4,5-dicarboxyimide
  参考文献：
  名称：

  具有氧化还原活性萘二酰亚胺功能的前所未有的基于降冰片二烯的光开关的可逆光诱导转换

  摘要：

  合成了一系列基于功能性 NBD-NDI 混合结构的新型光电开关，并在两种异构状态之间可逆地切换。研究了由氧化还原活性 NDI 结构单元实现的光诱导转换与间隔基长度和浓度的关系。实验结果和提出的机制途径得到了 DFT 计算的支持。

  DOI：

  10.1002/chem.202201446

文献信息

• Efficient electron transfer through a triazole link in ruthenium(ii) polypyridine type complexes
  作者：Aurélie Baron、Christian Herrero、Annamaria Quaranta、Marie-France Charlot、Winfried Leibl、Boris Vauzeilles、Ally Aukauloo

  DOI：10.1039/c1cc13683f

  日期：——

  Spectroscopic, electrochemical and theoretical characterisations of photoactive systems readily assembled via click-chemistry show an efficient bi-directional charge shift through the triazole link.

  点击化学构建的光活性系统的光谱学、电化学和理论表征表明，通过三唑键实现了高效的电荷双向转移。
• Naphthalenetetracarboxylic acid diimide derivative and electrophotographic photoconductor having the same
  申请人：Ricoh Company, Ltd.

  公开号：EP2033961B1

  公开（公告）日：2011-03-23
• Novel Compound and Organic Electronic Device Using the Same
  申请人：Fujiyama Takahiro

  公开号：US20070219375A1

  公开（公告）日：2007-09-20

  Disclosed is a novel compound suitable as an electron transporting material for organic electronic devices. Also disclosed is an organic electronic device using such a compound which has higher sensitivity and longer life than conventional organic electronic devices. Specifically disclosed is a compound having a structure wherein structural units represented by the general formula (1) below are bonded to one another without a linking group, wherein, in the formula, X 1 to X 4 independently represent an oxygen atom, a sulfur atom or NR 0 (wherein R 0 represents a hydrogen atom, or a substituted or unsubstituted monovalent organic group); Z 0 represents a tetravalent organic group; and * represents a bonding position.
• NAPHTHALENETETRACARBOXYLIC ACID DIIMIDE DERIVATIVE AND ELECTROPHOTOGRAPHIC PHOTOCONDUCTOR HAVING THE SAME
  申请人：OHTA Masafumi

  公开号：US20090068577A1

  公开（公告）日：2009-03-12

  The present invention provides a naphthalenetetracarboxylic acid diimide derivative represented by the following general formula (1): wherein R 1 and R 2 , which are identical or different, each represent a substituted or non-substituted alkyl group or a substituted or non-substituted aromatic hydrocarbon group; R 3 represents an alkyl group having 1 to 8 carbon atoms or an aromatic hydrocarbon group; R 4 , R 5 , R 6 and R 7 , which are identical or different, each represent a hydrogen atom, a substituted or non-substituted alkyl group, or a substituted or non-substituted aromatic hydrocarbon group; and R 1 and R 2 may be linked to form a substituted or non-substituted heterocyclic group including a nitrogen atom; with compounds where all of R 1 , R 2 and R 3 are a methyl group, and compounds where both of R 1 and R 2 are a methyl group and R 3 is a 1-octyl group being excluded.
• US7763727B2
  申请人：——

  公开号：US7763727B2

  公开（公告）日：2010-07-27