2,4-bis(pyridin-2-yl)-2-methyl-1,2-dihydro-1,10-phenanthroline | 1132769-79-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: 2,4-bis(pyridin-2-yl)-2-methyl-1,2-dihydro-1,10-phenanthroline
• 英文别名: 2-methyl-2,4-bis(pyridin-2-yl)-1,2-dihydro-1,10-phenanthroline；2-methyl-2,4-dipyridin-2-yl-1H-1,10-phenanthroline
• CAS: 1132769-79-9
• 化学式: C₂₃H₁₈N₄
• 分子量: 350.423
• InChiKey: OWMPXKVCFLQWNV-UHFFFAOYSA-N

物化性质

• 沸点：
  586.2±50.0 °C(predicted)
• 密度：
  1.233±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  27
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  50.7
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2,4-bis(pyridin-2-yl)-2-methyl-1,2-dihydro-1,10-phenanthroline 、 三氯化铁 在 n-C₄H₉Li 作用下， 以 四氢呋喃 为溶剂， 以95%的产率得到[FeCl2(2-methyl-2,4-bis(pyridin-2-yl)-1,2-dihydro-1,10-phenanthroline(-1H))]
  参考文献：
  名称：

  新型的乙烯低聚催化体系：具有阴离子N，N，N配体的铁（III）配合物

  摘要：

  我们报告了一种新型的基于铁（III）的催化体系，该体系通过向铁（III）的前体中添加阴离子的N，N，N配体而形成。该复合物已通过FT-IR，质谱和X射线衍射进行了表征。该预催化剂被证明形成了用于乙烯的选择性低聚的稳定的活性物质。获得高达66重量％的丁烯，在1-丁烯中的选择性为98％。

  DOI：

  10.1021/om200197s
• 作为产物：
  描述：

  2-乙酰基吡啶 、 8-氨基喹啉 在 甲酸 作用下， 以 甲醇 为溶剂， 反应 72.0h， 以30%的产率得到2,4-bis(pyridin-2-yl)-2-methyl-1,2-dihydro-1,10-phenanthroline
  参考文献：
  名称：

  Direct synthesis of a new class of N,N,N ligands based on 1,2-dihydro-1,10-phenanthroline backbone and their coordination to Pd complexes

  摘要：

  乙酰基吡啶衍生物与 8-氨基喹啉的反应提供了一种通用而简单的方法，可以获得一类意想不到的多功能 N,N,N 配体，为配位化学提供了有趣的前景。

  DOI：

  10.1039/b817726k

文献信息

• NOVEL NITROGEN-CONTAINING ORGANIC COMPOUNDS USABLE AS CATALYTIC COMPOSITION PRECURSORS
  申请人：Rangheard Claudine

  公开号：US20110009635A1

  公开（公告）日：2011-01-13

  The present invention describes novel nitrogen-containing organic compounds obtained by reacting a compound X of substituted pyridine type comprising at least one ketone function with a compound Y belonging to the aminoquinoleine family and derivatives thereof. Said organic compounds can be used as precursors in a catalytic composition.

  本发明描述了通过将至少具有一个酮功能的取代吡啶型化合物X与属于氨基喹啉家族及其衍生物的化合物Y反应而得到的新型含氮有机化合物。所述有机化合物可用作催化组合物中的前体。
• METHOD OF PREPARING A CATALYTIC COMPOSITION FOR DIMERIZATION, CO-DIMERIZATION AND OLIGOMERIZATION OF OLEFINS
  申请人：Rangheard Claudine

  公开号：US20110009581A1

  公开（公告）日：2011-01-13

  The present invention describes a method of preparing a catalytic composition used for oligomerization, co-dimerization or polymerization of olefins, wherein the compound obtained upon contacting at least one iron compound with at least one nitrogen-containing compound is subjected to an oxidation stage prior to being mixed with an activating agent and optionally with a solvent. The present invention also describes the catalytic composition obtained by means of said preparation method and the use thereof for oligomerization, co-dimerization or polymerization of olefins.
• PROCESS FOR THE PREPARATION OF A CATALYST COMPOSITION FOR DIMERIZATION, CODIMERIZATION AND OLIGOMERIZATION OF OLEFINS
  申请人：Rangheard Claudine

  公开号：US20110263804A1

  公开（公告）日：2011-10-27

  This invention describes a process for the preparation of a catalytic composition that can be used for oligomerization, codimerization, or polymerization of olefins. This invention also describes the catalytic composition that can be obtained by said process for the preparation and its use for oligomerization, codimerization, or polymerization of olefins.
• CATALYTIC COMPOSITION AND PROCESS FOR OLIGOMERIZATION OF OLEFINS USING SAID CATALYTIC COMPOSITION
  申请人：IFP ENERGIES NOUVELLES

  公开号：US20130211168A1

  公开（公告）日：2013-08-15

  The invention relates to a catalytic composition that comprises at least one precursor of iron or cobalt, at least one organic ligand, and an activating agent that consists of at least one derivative of aluminum and at least one organic compound having at least one alcohol group and/or at least one amine group, and in which the molar ratio between the aluminum and the alcohol and/or amine group number present in said organic compound of said activating agent is preferably greater than or equal to 1. The invention also relates to a process for oligomerization of olefins using said catalytic composition.
• US8101762B2
  申请人：——

  公开号：US8101762B2

  公开（公告）日：2012-01-24