(4,4,5,5,6,6,7,7,7-nonafluorohept-1-enyl)benzene | 664326-37-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (4,4,5,5,6,6,7,7,7-nonafluorohept-1-enyl)benzene
• 英文别名: (4,4,5,5,6,6,7,7,7-Nonafluorohept-1-en-1-yl)benzene；4,4,5,5,6,6,7,7,7-nonafluorohept-1-enylbenzene
• CAS: 664326-37-8
• 化学式: C₁₃H₉F₉
• 分子量: 336.2
• InChiKey: CHTMEBZUIXBKMA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  22
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为反应物：
  描述：

  (4,4,5,5,6,6,7,7,7-nonafluorohept-1-enyl)benzene 在 2,2'-联吡啶 、 ruthenium trichloride 作用下， 以 二氯甲烷 、 水 为溶剂， 反应 48.0h， 以90%的产率得到2-(2,2,3,3,4,4,5,5,5-nonafluoropentyl)-3-phenyloxirane
  参考文献：
  名称：

  Synthesis of Fluorinated Epoxides Opening the Way to New Hybrid Fluorocarbon-Hydrocarbon Surfactants

  摘要：

  Two methods of epoxidation were investigated on a hybrid fluorocarbon-hydrocarbon olefin: RUCl3/bipyridine/NaIO4 and oxone/acetone. The best yield was obtained using the first method which was extended to the synthesis of new aromatic fluorinated epoxides with very good yields.

  DOI：

  10.1081/scc-120026862
• 作为产物：
  描述：

  1,1,2,2-四氢全氟己基碘 在 potassium carbonate 作用下， 以 1,4-二氧六环 、 水 为溶剂， 生成 (4,4,5,5,6,6,7,7,7-nonafluorohept-1-enyl)benzene
  参考文献：
  名称：

  Escoula, B.; Rico, I.; Laval, J. P., Synthetic Communications, 1985, vol. 15, p. 35 - 38

  摘要：

  DOI：

文献信息

• Base-Promoted C–C Bond Activation Enables Radical Allylation with Homoallylic Alcohols
  作者：Maximilian Lübbesmeyer、Emily G. Mackay、Mark A. R. Raycroft、Jonas Elfert、Derek A. Pratt、Armido Studer

  DOI：10.1021/jacs.9b12343

  日期：2020.2.5

  C-radical addition to the double bond of the title reagents and subsequent base-promoted homolytic Cα–Cβ cleavage leads to the formation of the corresponding allylated products along with ketyl radicals that act as single electron reductants to sustain the chain reactions. Substrate scope is documented and the role of base in the C–C bond activation is studied by computation.

  高烯丙醇中的 Cα-Cβ 键可以在碱性条件下被激活，使这些非应变无环系统成为自由基烯丙基化试剂。这种反应性通过光引发（用可见光和/或蓝色 LED）使全氟烷基和分别从全氟烷基碘化物和烷基吡啶鎓盐产生的烷基与高烯丙醇进行烯丙基化反应来举例说明。C-自由基加成到标题试剂的双键和随后的碱促进均裂 Cα-Cβ 裂解导致形成相应的烯丙基化产物以及作为单电子还原剂维持链反应的羰基自由基。记录了底物范围，并通过计算研究了碱在 C-C 键活化中的作用。
• Culture vessel
  申请人：Menicon Co., Ltd.

  公开号：EP0890636A1

  公开（公告）日：1999-01-13

  A culture vessel wherein at least a part of the vessel is made of a gas permeable plastic material. In accordance with the present invention, it is provided the culture vessel which can be constantly and sufficiently supplied with a gas such as oxygen necessary for metabolism of cells without an oxygenator, and the like, and which is not contamined with bacteria and is easily transported.

  一种培养容器，其中至少有一部分是由可渗透气体的塑料材料制成的。根据本发明，所提供的培养容器可持续、充分地供应细胞新陈代谢所需的氧气等气体，无需增氧机等设备，而且不会受到细菌污染，便于运输。
• PROCESS FOR PRODUCING CONTACT LENS WITH HYDROPHILIC SURFACE AND CONTACT LENS OBTAINED THEREBY
  申请人：MENICON CO., LTD.

  公开号：EP0892297A1

  公开（公告）日：1999-01-20

  A process for producing a contact lens having a hydrophilic surface comprising subjecting a contact lens material comprising a copolymer prepared by copolymerizing a monomer mixture containing a polymerizable monomer (A) which is at least one member selected from a sugar ketal-containing (meth)acrylate and a sugar glycerol ketal-containing (meth)acrylate, and a polymerizable monomer (B) which is copolymerizable with the polymerizable monomer (A) to acid treatment, wherein the polymerizable monomer (B) contains a hydrophobic monomer which is at least one member selected from a silicon-containing monomer, a fluorine-containing monomer and a silicon- and fluorine-containing monomer, and a contact lens which has high oxygen permeability and of which surface shows stably excellent hydrophilic property and which is excellent in deposit resistance at the same time.

  一种生产具有亲水性表面的隐形眼镜的工艺，包括将隐形眼镜材料进行酸处理，该隐形眼镜材料包含通过共聚单体混合物制备的共聚物，该单体混合物包含可聚合单体(A)和可聚合单体(B)，可聚合单体(A)是至少一种选自含糖酮基(甲基)丙烯酸酯和含糖甘油酮基(甲基)丙烯酸酯的成员，可聚合单体(B)可与可聚合单体(A)共聚、其中，可聚合单体（B）含有一种疏水性单体，该疏水性单体至少选自含硅、含氟和含硅、含氟单体中的一种。
• The reactions of copper-dibromodifluoromethane-amide systems with alcohols
  作者：James H. Clark、Martin A. McClinton、Robert J. Blade

  DOI：10.1016/s0022-1139(00)82418-5

  日期：1992.11

  1,1,1-Trifluoro-2-arylethanes can be prepared by the trifluoromethyldehydroxylation of benzYl alcohols using the copper-dibromodifluoromethane-amide reaction system, although the yields are low. The mechanism of the reaction may involve chelation of the substrate to copper so that alpha-substituted benzyl alcohols and most other alcohols are unreactive.
• Bigot, Y. Le; Hajjaji, N.; Rico, I., Synthetic Communications, 1985, vol. 15, # 6, p. 495 - 498
  作者：Bigot, Y. Le、Hajjaji, N.、Rico, I.、Lattes, A.、Delmas, M.、Gaset, A.

  DOI：——

  日期：——