2,4,6-tris(diphenylamino)-1,3,5-triazine | 18343-40-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,4,6-tris(diphenylamino)-1,3,5-triazine
• 英文别名: hexaphenylmelamine；hexa-N-phenyl-[1,3,5]triazine-2,4,6-triyltriamine；Hexa-N-phenyl-[1,3,5]triazin-2,4,6-triyltriamin；2-N,2-N,4-N,4-N,6-N,6-N-hexakis-phenyl-1,3,5-triazine-2,4,6-triamine
• CAS: 18343-40-3
• 化学式: C₃₉H₃₀N₆
• 分子量: 582.707
• InChiKey: YGXMMMPUTDCEAF-UHFFFAOYSA-N

物化性质

• 熔点：
  294-296 °C(Solv: chlorobenzene (108-90-7))
• 沸点：
  756.3±43.0 °C(Predicted)
• 密度：
  1.259±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  10.7
• 重原子数：
  45
• 可旋转键数：
  9
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  48.4
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2,4,6-tris(diphenylamino)-1,3,5-triazine 在 溴 作用下， 以 氯仿 为溶剂， 反应 23.0h， 以95%的产率得到2,4,6-tris(di-p-bromodiphenylamino)-1,3,5-triazine
  参考文献：
  名称：

  Triamino-s-triazine Triradical Trications. An Experimental Study of Triazine as a Magnetic Coupling Unit

  摘要：

  Triamino-s-triazine derivatives 3a, 4, and 5 have been prepared, and their cationic states have been analyzed electrochemically. At 298 K, 3a(+) has a limited lifetime in CH2CI2 solution, However, 4(+) and 5(+) are long lived under such conditions, and quartet states of 4(3+) and 5(3+) are observed by ESR spectroscopy, Variable temperature ESR analysis and NMR shift susceptibility measurements indicate that 5(3+) is a doublet ground state with a populated quartet state.

  DOI：

  10.1021/ol9912736
• 作为产物：
  描述：

  hexaphenylisomelamine 298.2 ℃ 、101.32 kPa 条件下， 生成 2,4,6-tris(diphenylamino)-1,3,5-triazine
  参考文献：
  名称：

  Lebedev, B. V.; Bykova, T. A.; Kiparisova, E. G., Journal of general chemistry of the USSR, 1984, vol. 54, # 2, p. 372 - 378

  摘要：

  DOI：

文献信息

• [EN] COMPOUNDS HAVING ELECTROLUMINESCENT OR ELECTRON TRANSPORT PROPERTIES<br/>[FR] COMPOSÉS PRÉSENTANT DES PROPRIÉTÉS ÉLECTROLUMINESCENTES OU DE TRANSPORT DES ÉLECTRONS
  申请人：MERCK PATENT GMBH

  公开号：WO2009112854A1

  公开（公告）日：2009-09-17

  A compound of the formula R1 (CR3 =CR4 ) nAr(CR4 =CR3 ) nR2 wherein: n is 0 or 1; Ar represents aryl or heteroaryl having 1-5 aromatic rings which may be chain or fused or a combination of chain and fused, which may be substituted withalkoxy, fluoro, fluoroalkyl or cyano and which in the case of a 5-memnered ring nitrogen heteroatom may be N-substituted with aryl or substituted aryl optionally further substituted with alkoxy, fluoro, fluoroalkyl or cyano; R1 and R2 independently represent aryl or nitrogen, oxygen or sulphur-containing heteroaryl having two to four fused aromatic rings one of which may be 5-membered and optionally substituted by aryl or heteroaryl having 1-5 chain or fused aromatic rings which may be further substituted withalkoxy, fluoro, fluoroalkyl or cyano; and R3 and R4 independently represent hydrogen, methyl, ethyl or benzyl. Alsoprovided is a method of making a compound having electroluminescent and/or electroconductive properties, which comprises condensing an aromatic dialdehyde with a methyl-substituted heteroaryl compound having two to four fused rings which maybe unsubstituted ormay be further substituted by aryl or heteroaryl having from one to fouraromatic rings, said aryl or heteroaryl substituent or substituents optionally being substituted with one or more fluoro, fluoroalkyl orcyano substituents.The condensation may be carried out in acetic anhydride under reflux. The compounds may be incorporatede.g. as an electron transport layer into an optical light emitting diode,where embodiments can provide high electron mobility, low turn-on voltage and good lifetime,or into an electrostatic imaging member. Acompositionis provided comprising a compound as above and a second host or electron transport material and/or at leastone dopant.

  一个化合物的结构式为R1（CR3=CR4）nAr（CR4=CR3）nR2，其中：n为0或1；Ar代表含有1-5个芳香环的芳基或杂芳基，可以是链状的、融合的或链状和融合的组合，可以被烷氧基、氟、氟烷基或氰基取代，在5-成员环氮杂原子的情况下，可能被芳基或取代芳基N-取代，可选择地进一步取代为烷氧基、氟、氟烷基或氰基；R1和R2独立地代表含有两到四个融合芳香环的芳基或氮、氧或硫杂杂芳基，其中一个可能是5-成员的，并且可选择地被芳基或含有1-5个链状或融合芳香环的杂芳基取代，这些芳基或杂芳基可能进一步被烷氧基、氟、氟烷基或氰基取代；R3和R4独立地代表氢、甲基、乙基或苄基。还提供了一种制备具有电致发光和/或电导性能的化合物的方法，包括将芳香二醛与一种具有两到四个融合环的甲基取代的杂芳基化合物缩合，该化合物可能未取代或可能进一步被含有一到四个芳香环的芳基或杂芳基取代，所述芳基或杂芳基取代物可选择地被一个或多个氟、氟烷基或氰基取代。缩合可以在乙酸酐中回流进行。这些化合物可以被用作电子传输层，例如用于光电发光二极管，其中实施例可以提供高电子迁移率、低开启电压和良好的寿命，或用于静电成像成员。提供了一种组合物，包括上述化合物和第二宿主或电子传输材料和/或至少一个掺杂剂。
• AMINO FLUORENE POLYMER AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME
  申请人：SAMSUNG ELECTRONICS CO., LTD.

  公开号：US20170062724A1

  公开（公告）日：2017-03-02

  An amino fluorene polymer including a first repeating unit represented by Formula 1: wherein, in Formula 1, A, F, F′, m1, n1, n2, R 1 , R 2 , R 3 , and R 4 are the same as described in the specification.

  一种氨基萘聚合物，包括由式1表示的第一重复单元：其中，在式1中，A、F、F′、m1、n1、n2、R1、R2、R3和R4与规范中描述的相同。
• LIGHT EMITTING DEVICE CONTAINING PHOSPHORESCENT COMPLEX
  申请人：Ren Xiaofan

  公开号：US20080020237A1

  公开（公告）日：2008-01-24

  An OLED device comprises a cathode, an anode, and has therebetween a light emitting layer comprising a phosphorescent emitter represented by Formula (I): L n M   (I) wherein each L is a cyclometallated ligand with at least one containing a coumarin group, M is Ir or Pt, and n is 3 when M is Ir and 2 when M is Pt. The invention also comprised the compound of formula (I).

  一种OLED器件包括阴极、阳极，并且在两者之间具有一个发光层，该发光层包括由式(I)表示的磷光发射体：LnM  (I)其中每个L是至少含有一个香豆素基团的环金属配体，M是Ir或Pt，当M为Ir时，n为3，当M为Pt时，n为2。该发明还包括式(I)的化合物。
• USE OF DIPHENYLAMINO-BIS(PHENOXY)- AND BIS(DIPHENYLAMINO)-PHENOXYTRIAZINE COMPOUNDS
  申请人：Fuchs Evelyn

  公开号：US20100258790A1

  公开（公告）日：2010-10-14

  The present invention relates to an organic light-emitting diode comprising at least one diphenylaminobis(phenoxy)triazine or at least one bis(diphenylamino)phenoxytriazine compound, to a light-emitting layer comprising at least one diphenylamino-bis(phenoxy)triazine or at least one bis(diphenylamino)phenoxytriazine compound, to the use of the aforementioned compounds as a matrix material, hole/exciton blocker material, electron/exciton blocker material, hole injection material, electron injection material, hole conductor material and/or electron conductor material, and to a device selected from the group consisting of stationary visual display units, mobile visual display units and illumination units comprising at least one inventive organic light-emitting diode.

  本发明涉及一种有机发光二极管，包括至少一种二苯胺基双(苯氧基)三嗪或至少一种双(二苯胺基)苯氧基三嗪化合物，以及包括至少一种二苯胺基双(苯氧基)三嗪或至少一种双(二苯胺基)苯氧基三嗪化合物的发光层，以及上述化合物作为基质材料、空穴/激子阻挡材料、电子/激子阻挡材料、空穴注入材料、电子注入材料、空穴导体材料和/或电子导体材料的用途，以及从固定式视觉显示单元、移动式视觉显示单元和至少包括一种创新的有机发光二极管的照明单元中选择的装置。
• [EN] COMPOUNDS HAVING ELECTRON TRANSPORT PROPERTIES, THEIR PREPARATION AND USE<br/>[FR] COMPOSÉS PRÉSENTANT DES PROPRIÉTÉS DE TRANSPORT D'ÉLECTRONS, LEUR PRÉPARATION ET LEUR UTILISATION
  申请人：MERCK PATENT GMBH

  公开号：WO2010020352A1

  公开（公告）日：2010-02-25

  The invention provides compounds having utility inter alia as electron transport materials in optical light emitting diodes (OLEDs) and of the formula (I), (Il) or (III). Embodiments of the compounds when incorporated as electron transport layers in OLEDs exhibit a greater current density for a given voltage than corresponding devices where the electron transport material is aluminium quinolate.

  该发明提供了作为光电发光二极管（OLEDs）中电子传输材料的化合物，具有公式（I）、（II）或（III）的用途。当这些化合物作为OLED中的电子传输层时，与电子传输材料为铝喹啉的相应器件相比，表现出给定电压下更大的电流密度。