N,N'-diphenyl-N-(1-naphtyl)-1,4-phenylenediamine | 354987-84-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N'-diphenyl-N-(1-naphtyl)-1,4-phenylenediamine
• 英文别名: 4-(N-phenyl-N-naphthylamino)phenyl-1-phenylamine；(4-(N-phenyl-N-naphthylamino)phenyl)(phenyl)amine；4-N-naphthalen-1-yl-1-N,4-N-diphenylbenzene-1,4-diamine
• CAS: 354987-84-1
• 化学式: C₂₈H₂₂N₂
• 分子量: 386.496
• InChiKey: FICKIWKNAGZXMH-UHFFFAOYSA-N

物化性质

• 沸点：
  584.2±33.0 °C(Predicted)
• 密度：
  1.204±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.1
• 重原子数：
  30
• 可旋转键数：
  5
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  15.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N,N'-diphenyl-N-(1-naphtyl)-1,4-phenylenediamine 、 8,8-bis(4-bromophenyl)-8H-indolo-[3,2,1-de]acridine 在 三叔丁基膦 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 2.0h， 以49%的产率得到4-N-naphthalen-1-yl-1-N-[4-[13-[4-(N-[4-(N-naphthalen-1-ylanilino)phenyl]anilino)phenyl]-1-azapentacyclo[10.7.1.02,7.08,20.014,19]icosa-2,4,6,8(20),9,11,14,16,18-nonaen-13-yl]phenyl]-1-N,4-N-diphenylbenzene-1,4-diamine
  参考文献：
  名称：

  WO2008/66358

  摘要：

  公开号：
• 作为产物：
  描述：

  N-苯基-1-萘胺 在 tris-(dibenzylideneacetone)dipalladium(0) 、 三叔丁基膦 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 4.0h， 生成 N,N'-diphenyl-N-(1-naphtyl)-1,4-phenylenediamine
  参考文献：
  名称：

  카바졸과 플루오렌이 결합하여 고리를 형성한 화합물 및 이를 이용한 유기전기소자, 그 단말

  摘要：

  本发明提供了由卡巴唑和氟烯组成的环形化合物以及利用该化合物制备的有机电子器件及其端子。

  公开号：

  KR101763838B1

文献信息

• Organic EL devices and production process thereof
  申请人：Kato Tetsuya

  公开号：US20070293704A1

  公开（公告）日：2007-12-20

  An organic electroluminescent device comprising a light-emitting layer between a pair of electrodes, the light-emitting layer comprising a mixture of a hole-transporting material consisting of a tertiary amine compound, an electron-transporting material and a light-emitting additive material, in which the tertiary amine compound has two or more oxidation potentials determined by a cyclic voltammetry wherein a potential difference between the first oxidation potential and the second oxidation potential in the oxidation potentials is 0.22V or more, and a glass transition temperature of at least 100° C., and the electron-transporting material has a glass transition temperature of at least 100° C.

  一种有机电致发光器件，包括位于一对电极之间的发光层，该发光层包括由三级胺化合物组成的传输空穴材料、电子传输材料和发光添加剂材料的混合物，其中三级胺化合物具有由循环伏安法确定的两个或更多氧化电位，氧化电位中第一个氧化电位和第二个氧化电位之间的电位差为0.22V或更大，且具有至少100°C的玻璃转变温度，电子传输材料具有至少100°C的玻璃转变温度。
• COMPOUNDS AND ORGANIC LIGHT EMITTING DIODE USING THE SAME
  申请人：Jeon Byung-Sun

  公开号：US20100065828A1

  公开（公告）日：2010-03-18

  Disclosed are new compounds and an organic light emitting diode using the same. The organic light emitting diode using the new compound according to the present invention exhibits excellent characteristics in terms of actuating voltage, light efficiency, and lifespan.

  揭示了新化合物以及使用这些化合物的有机发光二极管。根据本发明的新化合物制成的有机发光二极管在驱动电压、光效率和寿命方面表现出优异的特性。
• AROMATIC TRIAMINE COMPOUND AND ORGANIC ELECTTROLUMINESCENCE DEVICE USING THE SAME
  申请人：KAWAMURA Masahiro

  公开号：US20090115320A1

  公开（公告）日：2009-05-07

  Provided are an aromatic triamine compound of a specific structure having at least one terphenyl structure and an organic electroluminescence device in which an organic thin film layer comprising a single layer or plural layers having at least a luminescent layer is interposed between a cathode and an anode, wherein at least one layer of the above organic thin film layers contains the aromatic triamine compound described above in the form of a single component or a mixed component, and provided are the organic electroluminescence device having a high luminous efficiency and a long life and the novel aromatic triamine compound for materializing the same.

  提供了一种具有至少一个三苯基结构的特定结构的芳香性三胺化合物，以及一种有机电致发光装置，其中在阴极和阳极之间夹有包括至少一个发光层的单层或多层有机薄膜层，上述有机薄膜层中的至少一层以单一组分或混合组分的形式含有上述芳香性三胺化合物，提供了具有高发光效率和长寿命的有机电致发光装置和用于实现其的新型芳香性三胺化合物。
• ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP2224510A1

  公开（公告）日：2010-09-01

  An organic electroluminescence device including: an anode (10), a cathode (70), an emitting layer (40) including an organic compound, which is between the anode (10) and the cathode (70), two or more layers arranged in a hole injection and transport region which is between the anode (10) and the emitting layer (40), and one or more layers arranged in an electron injection and transport region which is between the emitting layer (40) and the cathode (70), wherein a layer in the hole injection and transport region, which is in contact with the emitting layer (40), includes an aromatic amine derivative having a carbazole skeleton, one of the layers other than the layer in contact with the emitting layer (40) in the hole injection and transport region includes one or more materials selected from the group consisting of thiophene derivatives, tricyclic or more cyclic fused aromatic derivatives, amine derivatives excluding the compound represented by the following formula (A), conductive polymers, CFx, CuPc, transition metal oxides, fullerenes and acceptor materials, and a layer in the electron injection and transport region includes a benzimidazole derivative.

  一种有机电致发光装置，包括阳极（10）、阴极（70）、位于阳极（10）和阴极（70）之间的包括有机化合物的发射层（40）、位于阳极（10）和发射层（40）之间的空穴注入和传输区域中的两个或多个层、在发射层（40）和阴极（70）之间的电子注入和传输区域中布置的一层或多层，其中在空穴注入和传输区域中与发射层（40）接触的一层包括具有咔唑骨架的芳香胺衍生物、在空穴注入和传输区域中，与发射层（40）接触的层以外的层之一包括一种或多种选自以下组别的材料：噻吩衍生物、三环或多环融合芳香衍生物、胺衍生物（不包括下式（A）代表的化合物）、导电聚合物、CFx、CuPc、过渡金属氧化物、富勒烯和受体材料；在电子注入和传输区域中的层包括苯并咪唑衍生物。
• Compound for organic electronic element, organic electronic element using same, and electronic device thereof
  申请人：DUK SAN NEOLUX CO., LTD.

  公开号：US11205755B2

  公开（公告）日：2021-12-21

  Provided are an organic electric element and an electronic device thereof, the element using a mixture of a compound, of the present invention, as a phosphorescent host material such that high light-emitting efficiency and a low driving voltage of the organic electronic element can be achieved, and the duration of the element can be greatly improved.

  本发明提供了一种有机电子元件及其电子装置，该元件使用本发明的一种化合物混合物作为磷光主材料，从而实现了有机电子元件的高发光效率和低驱动电压，并大大提高了元件的使用寿命。