C6H4-1-(CH2PPh2)-3-(CH(CH3)PPh2) | 1039307-83-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: C6H4-1-(CH2PPh2)-3-(CH(CH3)PPh2)
• 英文别名: [3-(1-Diphenylphosphanylethyl)phenyl]methyl-diphenylphosphane
• CAS: 1039307-83-9
• 化学式: C₃₃H₃₀P₂
• 分子量: 488.549
• InChiKey: GDPJMEMJMQZOMC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.6
• 重原子数：
  35
• 可旋转键数：
  8
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  dichloro(cycloocta-1,5-diene)palladium (II) 、 C6H4-1-(CH2PPh2)-3-(CH(CH3)PPh2) 以 甲苯 为溶剂， 以85%的产率得到[PdCl[C6H3-2-(CH2PPh2)-6-(CH(CH3)PPh2)]]
  参考文献：
  名称：

  Simple protocol for the synthesis of the asymmetric PCP pincer ligand [C6H4-1-(CH2PPh2)-3-(CH(CH3)PPh2)] and its Pd(II) derivative [PdCl{C6H3-2-(CH2PPh2)-6-(CH(CH3)PPh2)}]

  摘要：

  The asymmetric PCP pincer ligand [C6H4-1-(CH2PPh2)-3-(CH(CH3)PPh2)](4) has been synthesized in a facile manner in three simple steps in high yield. Metallation of PCP pincer ligand (4) with [Pd(COD)Cl-2] affords complex [PdCl{C6H3-2-(CH2PPh2)-6-(CH(CH3)PPh2)}] (7) in good yield. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.02.005

文献信息

• Simple protocol for the synthesis of the asymmetric PCP pincer ligand [C6H4-1-(CH2PPh2)-3-(CH(CH3)PPh2)] and its Pd(II) derivative [PdCl{C6H3-2-(CH2PPh2)-6-(CH(CH3)PPh2)}]
  作者：Ali Naghipour、Zahra Haji Ghasemi、David Morales-Morales、Juan M. Serrano-Becerra、Craig M. Jensen

  DOI：10.1016/j.poly.2008.02.005

  日期：2008.6

  The asymmetric PCP pincer ligand [C6H4-1-(CH2PPh2)-3-(CH(CH3)PPh2)](4) has been synthesized in a facile manner in three simple steps in high yield. Metallation of PCP pincer ligand (4) with [Pd(COD)Cl-2] affords complex [PdClC6H3-2-(CH2PPh2)-6-(CH(CH3)PPh2)}] (7) in good yield. (C) 2008 Elsevier Ltd. All rights reserved.