3-[{2-[(Anthracene-2-carbonyl)-amino]-ethyl}-(2-methoxycarbonyl-ethyl)-amino]-propionic acid methyl ester | 594871-10-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 3-[{2-[(Anthracene-2-carbonyl)-amino]-ethyl}-(2-methoxycarbonyl-ethyl)-amino]-propionic acid methyl ester
• 英文别名: Methyl 3-[2-(anthracene-2-carbonylamino)ethyl-(3-methoxy-3-oxopropyl)amino]propanoate；methyl 3-[2-(anthracene-2-carbonylamino)ethyl-(3-methoxy-3-oxopropyl)amino]propanoate
• CAS: 594871-10-0
• 化学式: C₂₅H₂₈N₂O₅
• 分子量: 436.508
• InChiKey: RCBSPQHYMHGNAN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  32
• 可旋转键数：
  12
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  84.9
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  3-[{2-[(Anthracene-2-carbonyl)-amino]-ethyl}-(2-methoxycarbonyl-ethyl)-amino]-propionic acid methyl ester 以 甲醇 为溶剂， 生成 Methyl 3-[2-[3-[2-(anthracene-2-carbonylamino)ethyl-[3-[2-[bis(3-methoxy-3-oxopropyl)amino]ethylamino]-3-oxopropyl]amino]propanoylamino]ethyl-(3-methoxy-3-oxopropyl)amino]propanoate
  参考文献：
  名称：

  Facile and reversible synthesis of an acidic water-soluble poly(amidoamine) fullerodendrimer

  摘要：

  Water-soluble fullerodendrimer was obtained by the use of a Diels-Alder reaction of C-60 with a newly designed anthryl dendron under an extremely mild condition in 70% yield, which is more than five times as high as the yield described in our previous report. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(03)01425-4
• 作为产物：
  描述：

  甲基蒽-2-羧酸酯 以 甲醇 为溶剂， 生成 3-[{2-[(Anthracene-2-carbonyl)-amino]-ethyl}-(2-methoxycarbonyl-ethyl)-amino]-propionic acid methyl ester
  参考文献：
  名称：

  Facile and reversible synthesis of an acidic water-soluble poly(amidoamine) fullerodendrimer

  摘要：

  Water-soluble fullerodendrimer was obtained by the use of a Diels-Alder reaction of C-60 with a newly designed anthryl dendron under an extremely mild condition in 70% yield, which is more than five times as high as the yield described in our previous report. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(03)01425-4

文献信息

• A novel nanocomposite material prepared by intercalating photoresponsive dendrimers into a layered double hydroxide
  作者：Toshiyuki Tanaka、Shunsuke Nishimoto、Yoshikazu Kameshima、Junpei Matsukawa、Yasuhiko Fujita、Yutaka Takaguchi、Motohide Matsuda、Michihiro Miyake

  DOI：10.1016/j.jssc.2009.12.016

  日期：2010.2

  A novel combination for an inorganic-organic nanocomposite material was demonstrated. Anthryl dendron, i.e., poly(amidoamine) dendron with an anthracene chromophore group at the focal point, was incorporated in the interlayer space of ZnAl-NO3 type layered double hydroxide (LDH) through an anion-exchange reaction. The photoabsorption and fluorescence properties of the resulting material were different from those of the bare anthryl dendron molecule. It was suggested that the change in photochemical properties was due to the organization and pi-pi interaction of anthracene chromophores within the interlayer of the LDH. (C) 2010 Elsevier Inc. All rights reserved.
• Optically pure fullerodendron formed by diastereoselective Diels–Alder reaction
  作者：Nobuhiro Takahashi、Tomoyuki Tajima、Naoki Tsugawa、Yutaka Takaguchi

  DOI：10.1016/j.tet.2010.07.061

  日期：2010.9

  The Diels-Alder reaction between C(60) and anthryl glycodendron, which has D- or L-gluconamides at the terminals, gave a new fullerene glycodendron conjugate. Interestingly, the diastereoselective cycloaddition reaction proceeded upon the treatment of C60 with the anthryl dendron 3. Furthermore, optical pure fullerodendrons (-)-4L and (+)-4D, which were confirmed by (1)H and (13)C NMR spectroscopy, FT-IR, MALDI-TOF mass spectroscopic analysis, were isolated from the mixture of diastereomers. And their absolute configurations were predicted by the use of CD spectra. (C) 2010 Elsevier Ltd. All rights reserved.
• Facile and reversible synthesis of an acidic water-soluble poly(amidoamine) fullerodendrimer
  作者：Yutaka Takaguchi、Yuuki Sako、Yasushi Yanagimoto、Sadao Tsuboi、Jiro Motoyoshiya、Hiromu Aoyama、Takatsugu Wakahara、Takeshi Akasaka

  DOI：10.1016/s0040-4039(03)01425-4

  日期：2003.7

  Water-soluble fullerodendrimer was obtained by the use of a Diels-Alder reaction of C-60 with a newly designed anthryl dendron under an extremely mild condition in 70% yield, which is more than five times as high as the yield described in our previous report. (C) 2003 Elsevier Ltd. All rights reserved.