2,3-dimethyl-4,5-diphenyl-1-phenylphosphole | 261720-40-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,3-dimethyl-4,5-diphenyl-1-phenylphosphole
• 英文别名: 2,3-Dimethyl-1,4,5-triphenylphosphole
• CAS: 261720-40-5
• 化学式: C₂₄H₂₁P
• 分子量: 340.404
• InChiKey: UUGBGYASLUBZLW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  25
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  2,3-dimethyl-4,5-diphenyl-1-phenylphosphole 在 sulfur 作用下， 以 二氯甲烷 为溶剂， 反应 4.0h， 生成 2,3-dimethyl-4,5-diphenyl-1-phenylphosphole-sulfide
  参考文献：
  名称：

  Convenient route for the preparation of unsymmetrical phospholes via zirconacyclopentadienes

  摘要：

  The unsymmetrical substituted zirconacyclopentadienes obtained by selective intramolecular cross-coupling of two different alkynes on zirconocene are used to prepare new unsymmetrical C-substituted phosphole compounds. The X-ray structures of a phosphole and its related sulfide are presented. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00635-x
• 作为产物：
  描述：

  2,3-dimethyl-4,5-diphenyl-1-phenylphosphole-sulfide 在 三(2-氰乙基)膦 作用下， 以 甲苯 为溶剂， 反应 4.0h， 生成 2,3-dimethyl-4,5-diphenyl-1-phenylphosphole
  参考文献：
  名称：

  Convenient route for the preparation of unsymmetrical phospholes via zirconacyclopentadienes

  摘要：

  The unsymmetrical substituted zirconacyclopentadienes obtained by selective intramolecular cross-coupling of two different alkynes on zirconocene are used to prepare new unsymmetrical C-substituted phosphole compounds. The X-ray structures of a phosphole and its related sulfide are presented. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00635-x

文献信息

• Convenient route for the preparation of unsymmetrical phospholes via zirconacyclopentadienes
  作者：Jérôme Hydrio、Maryse Gouygou、Fréderic Dallemer、Jean-Claude Daran、Gilbert G.A. Balavoine

  DOI：10.1016/s0022-328x(99)00635-x

  日期：2000.2

  The unsymmetrical substituted zirconacyclopentadienes obtained by selective intramolecular cross-coupling of two different alkynes on zirconocene are used to prepare new unsymmetrical C-substituted phosphole compounds. The X-ray structures of a phosphole and its related sulfide are presented. (C) 2000 Elsevier Science S.A. All rights reserved.