Unsaturated polyaminopolymers, derivatives thereof, paper containing the polyaminopolymers processes for making all three
申请人:THE DOW CHEMICAL COMPANY
公开号:EP0471594A2
公开(公告)日:1992-02-19
Polyaminopolymers containing functionality are prepared by (a) contacting a polyfunctional amine with an unsaturated alkylating agent to form an amine/unsaturated alkylating agent adduct; (b) contacting the adduct with a polyfunctional compound to form a polyaminopolymer; (c) contacting the polyaminopolymer with a halogen, hypohalous acid or precursor thereof to form a polyaminopolymer having halohydrin or dihalo functionality; and (d) raising the pH of the polyaminopolymer having halohydrin or vicinal dihalo functionality to cause an increase in molecular weight. Optionally, the polyaminopolymer of step (b) or (c) is contacted with a crosslinking agent therefor having at least two functional groups reactive with amine groups to form a crosslinked polyaminopolymer. When such a crosslinked polyaminopolymer is formed, step (d) can be omitted. The polyaminopolymer of the invention are useful for preparing paper having improved wet strength.
含官能团的聚氨基聚合物的制备方法是:(a) 将多官能团胺与不饱和烷基化剂接触,形成胺/不饱和烷基化剂加合物;(b) 将加合物与多官能团化合物接触,形成聚氨基聚合物;(c) 将聚氨基聚合物与卤素、次卤酸或其前体接触,形成具有卤代卤素或二卤官能团的聚氨基聚合物;以及 (d) 提高具有卤代卤素或邻位二卤官能团的聚氨基聚合物的 pH 值,使分子量增加。可选择将步骤(b)或(c)中的聚氨基聚合物与具有至少两个与胺基团反应的官能团的交联剂接触,以形成交联聚氨基聚合物。当这种交联聚酰胺聚合物形成后,可省略步骤(d)。本发明的聚酰胺聚合物可用于制备具有更高湿强度的纸张。