Tetracyclohexyl-diphosphindisulfid | 3676-98-0

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机硫代磷化合物
• 英文名称: Tetracyclohexyl-diphosphindisulfid
• 英文别名: Tetracyclohexyl-biphosphin-disulfid；Dicyclohexyl-dicyclohexylphosphinothioyl-sulfanylidene-lambda5-phosphane；dicyclohexyl-dicyclohexylphosphinothioyl-sulfanylidene-λ5-phosphane
• CAS: 3676-98-0
• 化学式: C₂₄H₄₄P₂S₂
• 分子量: 458.693
• InChiKey: NUNKADNDHVNQDC-UHFFFAOYSA-N

物化性质

• 熔点：
  106-107 °C
• 沸点：
  560.9±33.0 °C(Predicted)
• 密度：
  1.10±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9.4
• 重原子数：
  28
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  64.2
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Tetracyclohexyl-diphosphindisulfid 在 sodium sulphide nonahydrate 、 sulfur 作用下， 以 1,4-二氧六环 为溶剂， 反应 24.0h， 以22.3 g的产率得到sodium dicyclohexyldithiophosphinate
  参考文献：
  名称：

  Convenient Synthesis of Dicyclohexyldithiophosphinic Acid

  摘要：

  Dicyclohexyldithiophosphinic acid was synthesized by a three-step strategy through the Grignard reaction of PSCl3 with cyclo-C6H11MgBr and the P-P bond-cleavage reaction of the intermediate. The 1H NMR data of ammonium dicyclohexyldithiophosphinate 4 and dicyclohexyldithiophosphinic acid 5 were characterized by 1H-1H correlation spectra.

  DOI：

  10.1080/00397910903029909
• 作为产物：
  描述：

  溴代环己烷 在 碘 、 magnesium 、 三氯硫磷 、 硫酸 作用下， 以 乙醚 、 水 为溶剂， 以80%的产率得到Tetracyclohexyl-diphosphindisulfid
  参考文献：
  名称：

  Convenient Synthesis of Dicyclohexyldithiophosphinic Acid

  摘要：

  Dicyclohexyldithiophosphinic acid was synthesized by a three-step strategy through the Grignard reaction of PSCl3 with cyclo-C6H11MgBr and the P-P bond-cleavage reaction of the intermediate. The 1H NMR data of ammonium dicyclohexyldithiophosphinate 4 and dicyclohexyldithiophosphinic acid 5 were characterized by 1H-1H correlation spectra.

  DOI：

  10.1080/00397910903029909

文献信息

• Niebergall,H.; Langenfeld,B., Chemische Berichte, 1962, vol. 95, p. 64 - 76
  作者：Niebergall,H.、Langenfeld,B.

  DOI：——

  日期：——
• Issleib; Seidel, Chemische Berichte, 1959, vol. 92, p. 2681,2691
  作者：Issleib、Seidel

  DOI：——

  日期：——
• Rhodium-catalyzed thiophosphinoylation reaction of 1,2-dienes with diphosphine disulfides
  作者：Mieko Arisawa、Masahiko Yamaguchi

  DOI：10.1016/j.tetlet.2008.10.075

  日期：2009.1

  In the presence of RhH(PPh3)(4), the reaction of 1,2-alkadienes, tetramethyldiphosphine disulfide, and camphorsulfonic acid gave (E)-2-dimethylthiophosphinoyl-2-alkenes. The reaction involved the P-P cleavage and the transfer of the thiophosphinoyl group to 1,2-alkadienes with concomitant formation of thiophosphinic anhydride. (C) 2008 Elsevier Ltd. All rights reserved.
• Convenient Synthesis of Dicyclohexyldithiophosphinic Acid
  作者：Cai Jia、Fengxian Yu、Fang Wang、Wangsuo Wu、Jing Chen

  DOI：10.1080/00397910903029909

  日期：2010.6.25

  Dicyclohexyldithiophosphinic acid was synthesized by a three-step strategy through the Grignard reaction of PSCl3 with cyclo-C6H11MgBr and the P-P bond-cleavage reaction of the intermediate. The 1H NMR data of ammonium dicyclohexyldithiophosphinate 4 and dicyclohexyldithiophosphinic acid 5 were characterized by 1H-1H correlation spectra.