tris(2-methoxyethyl)amine | 3235-51-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: tris(2-methoxyethyl)amine
• 英文别名: tris(3-oxabutyl)amine；tris-(3-oxabutyl)-amine；TDA-1；tris-(2-methoxy-ethyl)-amine；2.2'.2''-Trimethoxy-triaethylamin；Tris-(2-methoxy-aethyl)-amin；Triethylamine, 2,2'2''-trimethoxy-；2-methoxy-N,N-bis(2-methoxyethyl)ethanamine
• CAS: 3235-51-6
• 化学式: C₉H₂₁NO₃
• 分子量: 191.271
• InChiKey: QYOCMIVPWWBWGX-UHFFFAOYSA-N

物化性质

• 保留指数：
  1274

计算性质

• 辛醇/水分配系数(LogP)：
  -0.2
• 重原子数：
  13
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  30.9
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 海关编码：
  2922199090

反应信息

• 作为反应物：
  描述：

  tris(2-methoxyethyl)amine 、 2-碘乙基甲醚 以 乙腈 为溶剂， 生成 tetrakis(2-methoxyethyl)ammonium iodide
  参考文献：
  名称：

  Ionic liquid electrolytes based on multi-methoxyethyl substituted ammoniums and perfluorinated sulfonimides: Preparation, characterization, and properties

  摘要：

  New functionalized ionic liquids (ILs), comprised of multi-methoxyethyl substituted quaternary ammonium canons (i.e. [N(CH2CH2OCH3)(4-n)(R)(n)](+) : n=1, R=CH3OCH2CH2; n=1, R=CH3, CH2CH3: n=2, R=CH3CH2), and two representative perfluorinated sulfonimide anions (i.e. bis(fluorosulfonyl)imide (FSI-) and bis(trifluoromethanesulfonyl)imide (TFSI-)), were prepared. Their fundamental properties, including phase transition, thermal stability, viscosity, density, specific conductivity and electrochemical window, were extensively characterized. These multi-ether functionalized ionic liquids exhibit good capability of dissolving lithium salts. Their binary electrolytes containing high concentration of the corresponding lithium salt ([Li+] >1.6 mol kg(-1)) show Li+ ion transference number (t(Li+)) as high as 0.6-0.7. Their electrochemical stability allows Li deposition/stripping realized at room temperature. The desired properties of these multi-ether functionalized ionic liquids make them potential electrolytes for Li (or Li-ion) batteries. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.electacta.2010.06.063
• 作为产物：
  描述：

  2-氯乙基甲基醚 在 氨 作用下， 以 甲醇 为溶剂， 生成 tris(2-methoxyethyl)amine
  参考文献：
  名称：

  Remizov,A.L., Journal of general chemistry of the USSR, 1964, vol. 34, # 10, p. 3233 - 3237

  摘要：

  DOI：
• 作为试剂：
  描述：

  5-oxohexanal 、 2-<(Z)-3-(1-methoxy-1-methylethoxy)-2-propenyl>-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 在 高氯酸 、 tris(2-methoxyethyl)amine 作用下， 生成 (+)-(1R,7R)-exo-5-methyl-7-vinyl-6,8-dioxabicyclo<.3.2.1>octane 、 (1R,5S,7S)-5-methyl-7-vinyl-6,8-dioxabicyclo<3.2.1>octane
  参考文献：
  名称：

  Limited diastereoselectivity on addition of γ-alkoxy-z-allylboronates to aldehydes

  摘要：

  DOI：

  10.1016/s0040-4039(00)86964-6

文献信息

• Novel sulfonyldiazomethanes, photoacid generators, resist compositions, and patterning process
  申请人：——

  公开号：US20040167322A1

  公开（公告）日：2004-08-26

  A chemical amplification type resist composition comprising a specific benzenesulfonyldiazomethane containing a long-chain alkoxyl group at the 2-position on benzene ring has many advantages including improved resolution, improved focus latitude, minimized line width variation or shape degradation even on long-term PED, minimized debris left after coating, development and peeling, and improved pattern profile after development and is thus suited for microfabrication.

  一种化学放大型抗蚀组合物，包括在苯环上的2-位含有长链烷氧基基团的特定苯磺酰二氮甲烷，具有许多优点，包括提高分辨率，改善焦点宽度，即使在长期PED上也减少线宽变化或形状退化，涂层、显影和剥离后减少残留物，并在显影后改善图案轮廓，因此适用于微加工。
• [EN] BICYCLIC PEPTIDE LIGAND PRR-A CONJUGATES AND USES THEREOF<br/>[FR] CONJUGUÉS PEPTIDE BICYCLIQUE-LIGAND PPR-A ET LEURS UTILISATIONS
  申请人：BICYCLERD LTD

  公开号：WO2019034868A1

  公开（公告）日：2019-02-21

  The present invention provides compounds, compositions thereof, and methods of using the same.

  本发明提供了化合物、其组合物以及使用方法。
• [EN] BICYCLIC PEPTIDE LIGAND STING CONJUGATES AND USES THEREOF<br/>[FR] CONJUGUÉS PEPTIDE-LIGAND BICYCLIQUE ET LEURS UTILISATIONS
  申请人：BICYCLETX LTD

  公开号：WO2020165600A1

  公开（公告）日：2020-08-20

  The present invention provides compounds, compositions thereof, and methods of using the same.

  本发明提供了化合物、其组合物以及使用方法。
• Photoacid generators, chemically amplified resist compositions, and patterning process
  申请人：Ohsawa Youichi

  公开号：US20070292768A1

  公开（公告）日：2007-12-20

  A photoacid generator has formula (1). A chemically amplified resist composition comprising the photoacid generator has advantages including a high resolution, focus latitude, long-term PED dimensional stability, and a satisfactory pattern profile shape. When the photoacid generator is combined with a resin having acid labile groups other than those of the acetal type, resolution and top loss are improved. The composition is suited for deep UV lithography.

  一种光酸发生剂的化学式为（1）。包括该光酸发生剂的化学增感抗蚀组合物具有诸如高分辨率、焦点宽度、长期PED尺寸稳定性和令人满意的图案轮廓形状等优点。当该光酸发生剂与具有除了缩醛类型以外的酸敏感基团的树脂结合时，可以改善分辨率和顶部损失。该组合物适用于深紫外光刻。
• Method for producing biaryl compound
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20030158419A1

  公开（公告）日：2003-08-21

  There is disclosed a method for producing a biaryl compound of formula (I): 1 wherein R 1 is the same or different and independently denotes a substituted or unsubstituted hydrocarbon group or the like, A and B denote an aromatic hydrocarbon ring having from 6 to 14 carbon atoms or the like, k and m independently denote an integer of from 0 to 5, and 1 denotes an integer of 1 or 2, which method is characterized by reacting an aromatic compound of formula (II): 2 wherein R 1 , k and l denote the same as defined above, and X 1 denotes a leaving group, with a Grignard reagent of formula (III): 3 (R 2 ). 9MgX 2 (IIIg) wherein R 2 , B, and m denote the same as defined above and X 2 denotes chlorine or the like, in the presence of a cyclic ether, or an acyclic ether having two or more ether oxygens in the molecule and a nickel catalyst.

  揭示了一种制备式(I)的联苯化合物的方法：其中R1相同或不同且独立地表示取代或未取代的碳氢化合物基团或类似物，A和B表示具有6至14个碳原子或类似物的芳香碳氢环，k和m独立地表示0至5的整数，l表示1或2的整数，该方法的特征在于将式(II)的芳香化合物：其中R1、k和l的定义与上述相同，X1表示离去基团，与式(III)的格氏试剂反应：其中R2、B和m的定义与上述相同，X2表示氯或类似物，在环醚或分子中具有两个或更多个醚氧原子的无环醚和镍催化剂的存在下。