N,N-dibutylmethylamine hydrochloride | 67289-01-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N-dibutylmethylamine hydrochloride
• 英文别名: dibutyl-methyl-amine; hydrochloride；Dibutyl(methyl)azanium;chloride；dibutyl(methyl)azanium;chloride
• CAS: 67289-01-4
• 化学式: C₉H₂₁N*ClH
• 分子量: 179.733
• InChiKey: MWVMKRRNRAEZOI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.94
• 重原子数：
  11
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  甲醇 、 二正丁胺 在 Ag/TiO₂ 、 盐酸 作用下， 以 乙醚 为溶剂， 25.0 ℃ 、101.33 kPa 条件下， 反应 18.0h， 以96%的产率得到N,N-dibutylmethylamine hydrochloride
  参考文献：
  名称：

  N-Methylation of Amines with Methanol at Room Temperature

  摘要：

  N-Methylation of amines with methanol proceeds at room temperature in the presence of a silver-loaded titanium dioxide (Ag/TiO2) photocatalyst under UV-vis light irradiation. This method allows facile synthesis/isolation of N-methylamines bearing various functional groups including N-benzyl, N-allyl, N-Boc, hydroxyl, ether, acetal, carboxamide, formamide, and olefin groups.

  DOI：

  10.1021/acs.orglett.5b01063

文献信息

• IONIC COMPOUND, PROCESS FOR PRODUCING SAME, AND ION-CONDUCTIVE MATERIAL COMPRISING SAME
  申请人：Nippon Shokubai Co., Ltd.

  公开号：EP2327707A1

  公开（公告）日：2011-06-01

  The present invention provides a method of producing a tetracyanoborate-containing ionic compound in a milder condition more efficiently and less expensively than conventional methods, and a tetracyanoborate-containing ionic compound having a reduced content of impure components. An ionic compound of the present invention is represented by the following general formula (I), has a content of fluorine atom-containing impurities of 3 mol% or less per 100 mol% of the ionic compound, and a method for producing an ionic compound represented by the general formula (I) of the present invention comprises a step of reacting starting materials containing a cyanide and a boron compound. (In the formula, Ktm+ denotes an organic cation [Kt b]m+ or an inorganic cation [Kta]m+; and m denotes an integer of 1 to 3.)

  与传统方法相比，本发明提供了一种在更温和的条件下以更高效、更低成本生产含四氰基硼酸盐离子化合物的方法，以及一种降低了不纯组分含量的含四氰基硼酸盐离子化合物。本发明的离子化合物由以下通式(I)表示，每 100 摩尔离子化合物中含氟原子杂质的含量为 3 摩尔%或更少，生产本发明通式(I)表示的离子化合物的方法包括使含有氰化物和硼化合物的起始材料反应的步骤。 (式中，Ktm+表示有机阳离子[Kt b]m+ 或无机阳离子[Kta]m+；m 表示 1 至 3 的整数)。
• POLYMERIC SUPPORTED CATALYSTS FOR OLEFIN POLYMERIZATION
  申请人：ExxonMobil Chemical Patents, Inc.

  公开号：EP1066329B1

  公开（公告）日：2007-02-14
• IONIC COMPOUND, METHOD FOR PRODUCING THE SAME, AND ION-CONDUCTIVE MATERIAL COMPRISING THE SAME
  申请人：Hagiwara Yuji

  公开号：US20110150736A1

  公开（公告）日：2011-06-23

  The present invention provides a method of producing a tetracyanoborate-containing ionic compound in a milder condition more efficiently and less expensively than conventional methods, and a tetracyanoborate-containing ionic compound having a reduced content of impure components. An ionic compound of the present invention is represented by the following general formula (I), has a content of fluorine atom-containing impurities of 3 mol % or less per 100 mol % of the ionic compound, and a method for producing an ionic compound represented by the general formula (I) of the present invention comprises a step of reacting starting materials containing a cyanide and a boron compound. (In the formula, Kt m+ denotes an organic cation [Kt b ] m+ or an inorganic cation [Ke] m+ ; and m denotes an integer of 1 to 3.)
• POLYMERASE CHAIN REACTION COMPOSITION COMPRISING AMINES
  申请人：THERMO FISHER SCIENTIFIC BALTICS UAB

  公开号：US20200392562A1

  公开（公告）日：2020-12-17

  Compositions, methods, and kits comprising amines are described for use in nucleic acid synthesis. In some embodiments, amines improve nucleic acid synthesis product yield or tolerance to inhibitors of nucleic acid synthesis.
• US6426313B2
  申请人：——

  公开号：US6426313B2

  公开（公告）日：2002-07-30