2-Hydroxy-4-[3-(4-methylbenzene-1-sulfonyl)propoxy]benzoic acid | 141887-22-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-Hydroxy-4-[3-(4-methylbenzene-1-sulfonyl)propoxy]benzoic acid
• 英文别名: 2-hydroxy-4-[3-(4-methylphenyl)sulfonylpropoxy]benzoic acid
• CAS: 141887-22-1
• 化学式: C₁₇H₁₈O₆S
• 分子量: 350.4
• InChiKey: BFVIXPJSXHGXJK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  24
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  109
• 氢给体数：
  2
• 氢受体数：
  6

文献信息

• A phtalide compound and a near infrared absorber and a recording material each comprising the same compound
  申请人：YAMAMOTO CHEMICALS, INC.

  公开号：EP0664292A1

  公开（公告）日：1995-07-26

  A phthalide compound of general formula (I) and a near infrared absorber and a recording material each utilizing the phthalide compound are disclosed. wherein ring A represents a substituent group of the following formula    where R₁ represents hydrogen, alkyl, alkoxy or halogen; n represents an integer of 1-3; ring B represents a defined aromatic ring; R₂ represents alkyl or aryl; R₃ represents alkyl; R₄ and R₅ independently represent alkyl or unsubstituted or substituted phenyl; R₆ represents hydrogen, alkyl or alkoxy. The near infrared absorber and the recorded image on the recording material absorb strongly the near infrared region with no appreciable absorption in the visible region of the spectrum. The near infrared absorber is colorless or pale in color and yet highly capable of absorbing near infrared radiation. The recorded image on the recording material can hardly be read with the eye but can be read with the OCR. Moreover, the effect on the developed shade of any concomitant color former in a recording material is minimal.

  本发明公开了通式（I）的邻苯二甲酸盐化合物以及利用该邻苯二甲酸盐化合物的近红外吸收剂和记录材料。 其中环 A 代表下式的取代基团 其中 R₁ 代表氢、烷基、烷氧基或卤素；n 代表 1-3 的整数；环 B 代表确定的芳环；R₂ 代表烷基或芳基；R₃ 代表烷基；R₄ 和 R₅ 独立地代表烷基或未取代或取代的苯基；R₆ 代表氢、烷基或烷氧基。 近红外吸收体和记录材料上记录的图像对近红外区域有强烈的吸收，而对光谱的可见光区域没有明显的吸收。近红外吸收体是无色或浅色的，但吸收近红外辐射的能力很强。记录材料上记录的图像几乎无法用肉眼读取，但可以用 OCR 读取。此外，记录材料中的任何伴色前者对显影色调的影响微乎其微。
• THERMAL RECORDING MATERIAL
  申请人：Nippon Paper Industries Co., Ltd.

  公开号：EP3312018A1

  公开（公告）日：2018-04-25

  The objective of the present invention is to provide a thermosensitive recording medium excellent in color developing property, especially excellent in bar code readability, under severe environment. Provided is a thermosensitive recording medium having a thermosensitive recording layer comprising a colorless or pale colored electron donating leuco dye and an electron accepting color developing agent on a substrate, wherein the thermosensitive recording layer contains a specific sulfone compound and a specific urea-urethane-based compound in a specific ratio.

  本发明的目的是提供一种在恶劣环境下显色性能优异，特别是条形码可读性优异的热敏记录介质。本发明提供了一种热敏记录介质，它具有一个热敏记录层，该热敏记录层由基底上的无色或浅色电子供体染料和电子受体显色剂组成，其中热敏记录层含有特定比例的特定砜基化合物和特定脲基化合物。
• THERMOSENSITIVE RECORDING MATERIAL AND LAMINATE
  申请人：Mitsubishi Chemical Corporation

  公开号：EP3666541A1

  公开（公告）日：2020-06-17

  An object is to provide a thermosensitive recording material and a laminate which are excellent in color development sensitivity and favorable in storage characteristics such as heat resistance, plasticizer resistance, moisture resistance, oil resistance, and grease resistance. A thermosensitive recording material in which a thermosensitive recording layer is provided on a support, wherein the thermosensitive recording layer contains a specific diphenylsulfone compound and an analog compound thereof at a specific ratio. A laminate in which a thermosensitive recording layer is provided on a support, wherein the thermosensitive recording layer contains a specific diphenylsulfone compound and an analog compound thereof at a specific ratio.

  目的是提供一种热敏记录材料和层压板，它们具有优异的显色灵敏度和良好的储存特性，如耐热性、耐增塑剂性、耐潮湿性、耐油性和耐油脂性。一种热敏记录材料，其热敏记录层设置在支持物上，其中热敏记录层按特定比例含有特定的二苯砜化合物及其类似化合物。一种层压材料，其热敏记录层设置在支架上，其中热敏记录层按特定比例含有特定的二苯砜化合物及其类似化合物。
• HEAT-SENSITIVE RECORDING BODY
  申请人：Nippon Paper Industries Co., Ltd.

  公开号：EP3763537A1

  公开（公告）日：2021-01-13

  Provided is a thermosensitive recording medium, which is excellent in color developing property, especially excellent in bar code readability, under severe environment, further, excellent in resistance to discoloration under severe environment. That is a thermosensitive recording medium having a thermosensitive recording layer comprising a colorless or pale colored electron donating leuco dye and an electron accepting color developing agent on a substrate, wherein the thermosensitive recording layer comprises, as the electron accepting color developing agent, a specific sulfone compound and a phenolic compound in a specific ratio, wherein the phenolic compound contains two or more hydroxyl groups and two or more diphenylsulfone backbone but contains neither urethane bond nor urea bond. The thermosensitive recording layer optionally may further comprise a specific urea-urethane-based compound.

  本发明提供了一种热敏记录介质，它在恶劣环境下具有优异的显色性，特别是条形码可读性，而且在恶劣环境下具有优异的抗变色性。这是一种热敏记录介质，其热敏记录层由无色或浅色的电子供体染料和电子受体显色剂组成，热敏记录层的基底上有一个热敏记录层，其中，作为电子受体显色剂，热敏记录层由特定比例的砜类化合物和酚类化合物组成，其中，酚类化合物含有两个或两个以上的羟基和两个或两个以上的二苯基砜骨架，但不含氨基甲酸酯键或脲键。热敏记录层可选择进一步包含特定的脲-脲基化合物。
• REVERSIBLE THERMOCHROMIC COMPOSITION, REVERSIBLE THERMOCHROMIC MICROCAPSULE PIGMENT COMPRISING SAME, AND WRITING INSTRUMENT USING SAME
  申请人：THE PILOT INK CO., LTD.

  公开号：EP3950068A1

  公开（公告）日：2022-02-09

  [Problems] Provided are a highly marketable reversibly thermochromic composition that provides a black color during color development by using a fluoran derivative having a specific structure as an electron-donating color-developing organic compound, turns colorless during decoloration, and is excellent in contrast between a colored state and a decolored state and a microcapsule pigment encapsulating the same. [Solution] Disclosed are a reversibly thermochromic composition including: (a) a fluoran derivative having a specific structure as an electron-donating color-developing organic compound; (b) an electron-accepting compound; and (c) a reaction medium which reversibly induces an electron transfer reaction between the component (a) and the component (b) in a specific temperature range, and a reversibly thermochromic microcapsule pigment encapsulating the same.

  [问题]提供了一种极具市场前景的可逆热致变色组合物，该组合物通过使用具有特定结构的芴衍生物作为电子捐赠显色有机化合物，在显色过程中提供黑色，在脱色过程中变成无色，并且在有色状态和脱色状态之间具有极佳的对比度，同时还提供了封装该组合物的微胶囊颜料。 [解决方案]本发明公开了一种可逆热变色组合物，包括：（a）具有特定结构的氟烷衍生物，作为电子捐赠显色有机化合物；（b）电子接受化合物；以及（c）反应介质，该介质可在特定温度范围内可逆地诱导组分（a）和组分（b）之间的电子转移反应，以及封装该组合物的可逆热变色微胶囊颜料。