methacryloylthiohexane | 158521-05-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 硫代羧酸及其衍生物
• 英文名称: methacryloylthiohexane
• 英文别名: S-hexyl 2-methylprop-2-enethioate
• CAS: 158521-05-2
• 化学式: C₁₀H₁₈OS
• 分子量: 186.318
• InChiKey: LVKXVKIKTAXDNC-UHFFFAOYSA-N

物化性质

• 沸点：
  272.1±7.0 °C(Predicted)
• 密度：
  0.933±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  12
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  42.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1-己硫醇 、 2,6-二叔丁基-4-甲基苯酚 以 sodium hydroxide 为溶剂， 以83%的产率得到methacryloylthiohexane
  参考文献：
  名称：

  Method of manufacturing a (meth)acryloylthio compound

  摘要：

  本发明涉及一种生产通式I的(甲基)丙烯酰硫醇酯的方法：##STR1## 其中，R代表氢或甲基，R1代表苯基、取代的苯基、C1-24烷基、取代的C1-24烷基或环状C3-24烷基；该方法包括将(甲基)丙烯酸酐（公式II）##STR2## 其中，R代表氢或甲基，与至少等量反应的硫醇或硫醇盐的公式III R1--S--M，(III) 其中，M代表氢或金属阳离子，R1的定义如上所述。

  公开号：

  US05424472A1

文献信息

• Fluoropolymer film structures and laminates produced therefrom
  申请人：——

  公开号：US20030203190A1

  公开（公告）日：2003-10-30

  Fluoropolymer films which combine the attributes of outdoor durability, chemical resistance and thermoformability with paint-like aesthetics are formed into film structures which have at least one surface coated with a primer of amine functional polymer and an overcoat of a thermoplastic adhesive of acid modified polyolefin. Fluoropolymer films so coated are securely bonded to a variety of thermoplastic substrates forming a laminated film structure which resists delamination when exposed to moisture and humidity.

  含氟聚合物薄膜兼具户外耐用性、耐化学性、热成型性和油漆美感等特性，可制成薄膜结构，其至少一个表面涂有胺功能聚合物底漆和酸改性聚烯烃热塑性粘合剂涂层。涂有这种涂层的含氟聚合物薄膜可牢固地粘合到各种热塑性基材上，形成一种层压薄膜结构，在受潮和潮湿时不会分层。
• Processes for preparing printable and printed articles
  申请人：Snow Glen Larry

  公开号：US20050129882A1

  公开（公告）日：2005-06-16

  Processes are disclosed for preparing a printable and printed articles by coating a substrate with a composition containing a crosslinkable amine functional polymer and a polyfunctional isocyanate blocked by a blocking agent. The coated substrate is heated to a sufficient temperature to deblock the blocked polyfunctional isocyanate and thereby produce a crosslinked hydrophobic, ink receptive polymer layer on the substrate. Printed articles are prepared by forming an image on the crosslinked hydrophobic, ink receptive layer. In a preferred embodiment, the crosslinked hydrophobic, ink receptive polymer composition is characterized by a solvent resistance fraction of at least 0.6 and a solvent absorbance capacity of at least 300. The substrate of the printed article is preferably polymer, metal, glass, or paper, more preferably polymer film. A process for preparing printable articles wherein the substrate is a fluoropolymer is especially preferred.

  本发明公开了一种制备可印刷和印刷品的工艺，方法是在基材上涂覆一种含有可交联胺官能团聚合物和被封端剂封端的多官能异氰酸酯的组合物。将涂层基材加热到足够的温度，使被封端的多官能异氰酸酯脱嵌，从而在基材上形成交联的疏水性油墨接受聚合物层。通过在交联疏水性油墨接受层上形成图像来制备印刷品。在一个优选的实施方案中，交联疏水性油墨接收聚合物组合物的特点是耐溶剂性至少为 0.6，溶剂吸收能力至少为 300。印刷品的基材最好是聚合物、金属、玻璃或纸，更优选聚合物薄膜。特别优选的是制备可印刷物品的工艺，其中基材是含氟聚合物。
• FLUOROPOLYMER FILM STRUCTURES AND LAMINATES PRODUCED THEREFROM
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP1131375B1

  公开（公告）日：2004-03-03
• PROCESSES FOR PREPARING PRINTABLE AND PRINTED ARTICLES
  申请人：E.I. du Pont de Nemours and Company

  公开号：EP1699843A1

  公开（公告）日：2006-09-13
• Processes for Preparing Printable and Printed Articles
  申请人：Snow Larry Glen

  公开号：US20090047449A1

  公开（公告）日：2009-02-19

  Processes are disclosed for preparing a printable and printed articles by coating a substrate with a composition containing a crosslinkable amine functional polymer and a polyfunctional isocyanate blocked by a blocking agent. The coated substrate is heated to a sufficient temperature to deblock the blocked polyfunctional isocyanate and thereby produce a crosslinked hydrophobic, ink receptive polymer layer on the substrate. Printed articles are prepared by forming an image on the crosslinked hydrophobic, ink receptive layer. In a preferred embodiment, the crosslinked hydrophobic, ink receptive polymer composition is characterized by a solvent resistance fraction of at least 0.6 and a solvent absorbance capacity of at least 300. The substrate of the printed article is preferably polymer, metal, glass, or paper, more preferably polymer film. A process for preparing printable articles wherein the substrate is a fluoropolymer is especially preferred.